Showing papers in "Rheologica Acta in 2013"

A unified approach to model elasto-viscoplastic thixotropic yield-stress materials and apparent yield-stress fluids

Abstract: A constitutive model for elasto-viscoplastic thixotropic materials is proposed. It consists of two differential equations, one for the stress and the other for the structure parameter, a scalar quantity that indicates the structuring level of the microstructure. In contrast to previous models of this kind, the structure parameter varies from zero to a positive and typically large number. The lower limit corresponds to a fully unstructured material, whereas the upper limit corresponds to a fully structured material. When the upper limit is finite, the model represents a highly shear-thinning, thixotropic, and viscoelastic liquid that possesses an apparent yield stress. When it tends to infinity, the behavior of a true yield-stress material is achieved. Predictions for rheometric flows such as constant shear rate tests, creep tests, SAOS, and large-amplitude oscillatory shear (LAOS) are presented, and it is shown that, in all cases, the trends observed experimentally are faithfully reproduced by the model. Within the framework of the model, simple explanations are given for the avalanche effect and the shear banding phenomenon. The LAOS results obtained are of particular importance because they provide a piece of information that so far is absent in the literature, namely a quantitative link between the Lissajous–Bowditch curve shapes and rheological effects such as elasticity, thixotropy, and yielding.

Influence of degree of sulfation on the rheology of cellulose nanocrystal suspensions

Abstract: The rheology and microstructure of two different cellulose nanocrystals (CNC) samples possessing different degrees of sulfation are studied over a broad concentration range of 1 to 15 wt%. CNC suspensions are isotropic at low concentration and experience two different transitions as concentration increases. First, they form chiral nematic liquid crystals above a first critical concentration where the samples exhibit a fingerprint texture and the viscosity profile shows a three-region behavior, typical of liquid crystals. By further increasing the concentration, CNC suspensions form gels above a second critical concentration, where the viscosity profile shows a single shear-thinning behavior over the whole range of shear rates investigated. It has been found that the degree of sulfation of CNC particles has a significant effect on the critical concentrations at which transitions from isotropic to liquid crystal and liquid crystal to gel occur. Rheological properties and microstructure of these suspensions have been studied using polarized optical microscopy combined with rheometry.

Low-dimensional intrinsic material functions for nonlinear viscoelasticity

Abstract: Rheological material functions are used to form our conceptual understanding of a material response. For a nonlinear rheological response, the possible deformation protocols and material measures span a high-dimensional space. Here, we use asymptotic expansions to outline low-dimensional measures for describing leading-order nonlinear responses in large amplitude oscillatory shear (LAOS). This amplitude-intrinsic regime is sometimes called medium amplitude oscillatory shear (MAOS). These intrinsic nonlinear material functions are only a function of oscillatory frequency, and not amplitude. Such measures have been suggested in the past, but here, we clarify what measures exist and give physically meaningful interpretations. Both shear strain control (LAOStrain) and shear stress control (LAOStress) protocols are considered, and nomenclature is introduced to encode the physical interpretations. We report the first experimental measurement of all four intrinsic shear nonlinearities of LAOStrain. For the polymeric hydrogel (polyvinyl alcohol - Borax) we observe typical integer power function asymptotics. The magnitudes and signs of the intrinsic nonlinear fingerprints are used to conceptually model the mechanical response and to infer molecular and microscale features of the material.

Microfluidic extensional rheometry using a hyperbolic contraction geometry

Abstract: Microfluidic devices are ideally suited for the study of complex fluids undergoing large deformation rates in the absence of inertial complications. In particular, a microfluidic contraction geometry can be utilized to characterize the material response of complex fluids in an extensionally-dominated flow, but the mixed nature of the flow kinematics makes quantitative measurements of material functions such as the true extensional viscosity challenging. In this paper, we introduce the ‘extensional viscometer-rheometer-on-a-chip’ (EVROC), which is a hyperbolically-shaped contraction-expansion geometry fabricated using microfluidic technology for characterizing the importance of viscoelastic effects in an extensionally-dominated flow at large extension rates (\(\lambda \dot \varepsilon _a \gg 1\), where \(\lambda \) is the characteristic relaxation time, or for many industrial processes \(\dot \varepsilon _a \gg 1\) s\(^{-1}\)). We combine measurements of the flow kinematics, the mechanical pressure drop across the contraction and spatially-resolved flow-induced birefringence to study a number of model rheological fluids, as well as several representative liquid consumer products, in order to assess the utility of EVROC as an extensional viscosity indexer.

Particle tracking in living cells: a review of the mean square displacement method and beyond

Abstract: The focus of many particle tracking experiments in the last decade has been active systems, such as living cells. In active systems, the particles undergo simultaneous active and thermally driven transport. In contrast to thermally driven transport, particle motion driven by active processes cannot directly be correlated to the rheology of the probed region. The rheology in particle tracking experiments is typically obtained through the mean square displacements (MSD) of the trajectories. Hence, the MSD and its functional form remain the only basic tools to evaluate and compare living cells or other active systems. However, the mechano-structural characteristics of the intracellular environment and the mechanisms driving particle transport cannot be revealed by the MSD alone. Hence, approaches for advanced analysis of particle trajectories have been introduced recently. Here, we present a broad review of the extensive intracellular particle tracking experiments that have been carried out on a wide variety of cell types. Those works utilize the MSD, revealing similarities and differences relating to cell type and experimental setup. We also highlight several advanced trajectory-and displacement-based analysis methods and illustrate their capabilities using particle tracking data obtained from two cancer cell lines. We show that combining these analysis methods with the MSD can reveal additional information on intracellular structure and the existence and nature of active processes driving particle motion in cells.

Morphological and rheological properties of PET/clay nanocomposites

Abstract: This work investigates the effects of clay chemistry and concentration on the morphology and rheology of polyethylene terephthalate (PET)/clay nanocomposites. The complex viscosity of the PET nanocomposites exhibited a more solid-like behavior, in contrast to the matrix that had a frequency-independent viscosity. In addition, at high frequencies where the behavior of the matrix should be dominant, a lower complex viscosity of the nanocomposites was observed due to PET degradation in the presence of the organoclays. The high-frequency data were used to estimate the matrix degradation using the Maron–Pierce equation. The apparent molecular weight of the PET matrix was found to decrease from 65 kg/mol for the neat PET to 30 kg/mol for a PET nanocomposite containing 8 wt% Cloisite®; 30B. The apparent yield stress in the nanocomposites was determined using the Herschel–Bulkley model. Yield stress increased with the level of exfoliation and clay concentration, from ∼0 to 166 Pa when the clay concentration increased from 2 to 8 wt%.

Study on the rheological properties of Portland cement pastes with polycarboxylate superplasticizers

Abstract: The coupling effects of temperature and time on the fluidity of fresh cement mixtures were investigated. Mini-cone tests on cement mortars and rheological tests on cement pastes under different temperatures (0 to 60 °C) were conducted to characterize the development of the fluidity of fresh cement mixtures over time. In addition, total organic carbon tests were performed to quantify the adsorption amount of superplasticizers on the cement surface. The amount of free water in cement pastes was determined via centrifugation. Isothermal calorimetry was employed to characterize the hydration kinetics of cement under different temperatures. Results show that the spread diameter of mortars decreases in a roughly linear fashion over elapsed time. Higher temperature facilitates a sharper decrease in fluidity with time, although the initial fluidity of fresh mortars is not significantly affected by temperature. Higher temperature results in a greater amount of adsorbed polycarboxylate ester/ether on the cement surface and a lower amount of free water in fresh cement pastes, which is believed to result from the higher hydration rate of cement. The evolution of rheological properties over time can be attributed to the development of hydration degree. Relative hydration degree is introduced to indicate the development of rheological properties with time. Two models to describe the evolution of yield stress and plastic viscosity for fresh cement pastes were developed.

Fractures in complex fluids: the case of transient networks

Abstract: We present a comprehensive review of the current state of fracture phenomena in transient networks, a wide class of viscoelastic fluids. We will first define what is a fracture in a complex fluid and recall the main structural and rheological properties of transient networks. Secondly, we review experimental reports on fractures of transient networks in several configurations: shear-induced fractures, fractures in Hele–Shaw cells, and fracture in extensional geometries (filament-stretching rheometry and pendant drop experiments), including fracture propagation. The tentative extension of the concepts of brittleness and ductility to the fracture mechanisms in transient networks is also discussed. Finally, the different and apparently contradictory theoretical approaches developed to interpret fracture nucleation will be addressed and confronted to experimental results. Rationalized criteria to discriminate the relevance of these different models will be proposed.

Tracking the interfacial dynamics of PNiPAM soft microgels particles adsorbed at the air–water interface and in thin liquid films

Abstract: We report the behavior of thermosensitive soft microgel particles adsorbed at the air–water interface. We study the effect of temperature on the adsorption, interfacial diffusion, and surface rheology of pure N-isopropylacrylamide (NiPAM) microgel particles at the air–water interface. We find that the surface tensions of the solutions are the same as those of polyNiPAM solution; hence, their adsorption properties are dominated by the surface activity of the NiPAM repeat units of the particles. Particle-tracking experiments show that the particles adsorb irreversibly at the interface and form stable clusters at very low concentrations, e.g., 5.10-3 wt%. We suggest that attractions between dangling arms or capillary interaction may be responsible for the formation of these clusters. For concentrations above 10-2 wt%, the interface is filled with particles, and their Brownian diffusivity is arrested. The compression elastic moduli—measured using the pendant drop method—are one or two orders of magnitude below those obtained for hard particles and NiPAM chains, and their value is probably dominated by the intrinsic compressibility of the particles. The thin liquid films made from microgels exhibit a symmetric drainage, consistent with a high surface viscosity, but their lifetime is surprisingly short, illustrating the fragility of the films. We observed the formation of a monolayer of microgels bridging the two interfaces of the film outside the dimple. This zone grows and thins over time to a point where the microgels are highly compressed and stretched, resulting in the rupture of the film.

Large Deborah number flows around confined microfluidic cylinders

Abstract: Viscoelastic flow around a confined cylinder at high Deborah numbers is studied using microfluidic channels. By varying fluid properties and flow rates, a systematic study of the roles of elasticity and inertia is accomplished. Two new elastic flow instabilities that occur at high Deborah numbers are identified. A downstream instability of disordered and temporally varying streamlines is observed at a Deborah number above 10. This instability is a precursor to an unsteady vortex that develops upstream of the cylinder at higher Deborah numbers. Both instabilities occur at moderate Reynolds numbers but are fundamentally elastic. The size and steadiness of the upstream vortex are primarily controlled by the Deborah and the elasticity number.

Compression behaviors of magnetorheological fluids under nonuniform magnetic field

Abstract: This work is concerned with an experimental and theoretical study on compression properties of magnetorheological fluids under the nonuniform field. Experimental tests of unidirectional monotonic compression were firstly carried out under constant area operation using a commercial plate–plate magneto-rheometer where the magnetic field radial distribution was nonuniform. Normal forces increased with decreasing of the gap distance, and two regions were found through the normal force versus gap distance curves: elastic deformation and plastic flow. High normal forces could be obtained in the case of high magnetic field, high compression velocity, low initial gap distance, high volume fraction, and high medium viscosity. In the plastic flow region, the normal force with the gap distance could be fitted with a power law relation $F_{\textrm {N}} \propto h^n$ , and the index n was around well in the range (−3, −2). Taking nonuniform magnetic field into account, the theoretical modeling in the plastic flow was then developed to calculate the normal force under compression based on the continuum media theory. Compared to the uniform field, there existed a magnetic field gradient-induced normal force under nonuniform field. Considering the sealing and squeeze strengthening effect, the gap distance-dependent shear yield stress was proposed, and a good correspondence between the theoretical and experimental results was obtained.

Rheological properties of suspensions of the green microalga Chlorella vulgaris at various volume fractions

Abstract: A systematic study of the rheological properties of solutions of non-motile microalgae (Chlorella vulgaris CCAP 211-19) in a wide range of volume fractions is presented. As the volume fraction is gradually increased, several rheological regimes are observed. At low volume fractions (but yet beyond the Einstein diluted limit), the sus- pensions display a Newtonian rheological behaviour and the volume fraction dependence of the viscosity can be well described by the Quemada model (Quemada, Eur Phys J Appl Phys 1:119-127, 1997). For intermediate values of the volume fraction, a shear thinning behaviour is observed and the volume fraction dependence of the viscosity can

Mixtures of foam and paste: suspensions of bubbles in yield stress fluids

Abstract: We study the rheological behavior of mixtures of foams and pastes, which can be described as suspensions of bubbles in yield stress fluids. Model systems are designed by mixing monodisperse aqueous foams and concentrated emulsions. The elastic modulus of the bubble suspensions is found to depend on the elastic capillary number $\textit{Ca}_{_G}$ , defined as the ratio of the paste elastic modulus to the bubble capillary pressure. For values of $\textit{Ca}_{_G}$ larger than $\simeq 0.5$ , the dimensionless elastic modulus of the aerated material decreases as the bubble volume fraction $\phi $ increases, suggesting that bubbles behave as soft elastic inclusions. Consistently, this decrease is all the sharper as $\textit{Ca}_{_G}$ is high, which accounts for the softening of the bubbles as compared to the paste. By contrast, we find that the yield stress of most studied materials is not modified by the presence of bubbles. This suggests that their plastic behavior is governed by the plastic capillary number $\textit{Ca}_{\tau_y}$ , defined as the ratio of the paste yield stress to the bubble capillary pressure. At low $\textit{Ca}_{\tau_y}$ values, bubbles behave as nondeformable inclusions, and we predict that the suspension dimensionless yield stress should remain close to unity, in agreement with our data up to $\textit{Ca}_{\tau_y}=0.2$ . When preparing systems with a larger target value of $\textit{Ca}_{\tau_y}$ , we observe bubble breakup during mixing, which means that they have been deformed by shear. It then seems that a critical value $\textit{Ca}_{\tau_y}\simeq 0.2$ is never exceeded in the final material. These observations might imply that, in bubble suspensions prepared by mixing a foam and a paste, the suspension yield stress is always close to that of the paste surrounding the bubbles. Finally, at the highest $\phi $ investigated, the yield stress is shown to increase abruptly with $\phi $ : this is interpreted as a “foamy yield stress fluid” regime, which takes place when the paste mesoscopic constitutive elements (here, the oil droplets) are strongly confined in the films between the bubbles.

Particles accelerate the detachment of viscous liquids

Abstract: During detachment of a viscous fluid extruded from a nozzle, a filament linking the droplet to the latter is formed. Under the effect of surface tension, the filament thins until pinch-off and final detachment of the droplet. In this paper, we study the effect of the presence of individual particles trapped in the filament on the detachment dynamics using granular suspensions of small volume fractions (ϕ < 6 %). We show that even a single particle strongly modifies the detachment dynamics. The particle perturbs the thinning of the thread, and a large droplet of fluid around the particle is formed. This perturbation leads to an acceleration of the detachment of the droplet compared to the detachment observed for a pure fluid. We quantify this acceleration for single particles of different sizes and link it to similar observations for suspensions of small volume fractions. Our study also gives more insight into particulate effects on detachment of denser suspensions and allows to explain the accelerated detachment close to final pinch-off observed previously (Bonnoit et al. Phys Fluids 24(4):043304, 2012).

Superposition rheometry of a wormlike micellar fluid

Abstract: Oscillatory measurements are often used to explore the nonlinear response of materials, with recently a strong focus on using large amplitude oscillatory experiments. However, the superposition of an oscillatory motion onto a steady-state shear flow is a method where the kinematic history experienced by the sample is simpler. Such a superposed oscillation can be applied either orthogonal or parallel to the main flow direction. Both superposed deformation modes can now be achieved on rotational rheometers equipped with a force-rebalanced transducer, the orthogonal mode requiring a minor modification to the control loop of the normal force. In the present work, the nonlinear properties of a wormlike micellar (WLM) solution are studied. The results are compared with the predictions of the Giesekus model, which is chosen both for its capability to describe the WLM response and for being one of the simplest continuum models that incorporate an anisotropic microstructure. From the fluid response in the homogeneous flow regime, a rate-dependent relaxation time and a rate-dependent plateau modulus can be derived. The latter provides insight into the structural anisotropy during flow at short length scales, which in this case is isotropic. Further analysis of the superposition moduli can be used to separate and quantify the effects of flow on the reptation and breaking of the chains. In the shear-banding regime, the orthogonal moduli show a weaker dependence on shear rate compared to the predictions of the Giesekus model, yet they remain sensitive to changes in the shear-banded state.

A new thixotropic model for waxy crude

Abstract: Waxy crude oil shows thixotropic behavior below the gelation temperature. The mostly used thixotropic model for waxy crude is the model proposed by Houska. One problem of Houska’s model is that after the stepwise change in shear rate, the predicted shear stress decreases to its equilibrium value more quickly than the measured data. To address this problem, a new viscoplastic thixotropic model is proposed. The evolution of structural parameter is described by a new kinetic equation. In the kinetic equation, a new pre-factor with shear strain as variable is introduced for the buildup and breakdown terms, and the breakdown term is assumed to be dependent on energy dissipation rate rather than on shear rate. The proposed model was validated by the stepwise shear rate test and hysteresis loop test. And the results showed that the new model’s fitting and predictive capability is satisfactory.

The use of rheology in the study of the composition effects on the fresh behaviour of hydraulic lime grouts for injection of masonry walls

Abstract: The injection of grouts inside multi-leaf stone masonries is a technique widely used for structural consolidation. To ensure an adequate flow of the grout inside the masonry, it is crucial to assure good fresh grout properties, such as good rheological behaviour. The scope of this paper is to provide preliminary indications and valuable data about the effects of specific hydraulic lime grout composition on their rheological behaviour with the purpose of a successful injection process. Through the use of rotational rheometer together with the Taguchi method, it was possible to study the influence of water/binder ratio, the type and dosage of superplasticizer and the partial replacement of hydraulic lime by silica fume, upon the grout rheological properties. The study leads to the conclusion that polycarboxylate-based superplasticizers present better performance from a rheological point of view than the naphthalene-based superplasticizer and that the water/binder ratio and superplasticizer dosage are the most determinant factors in the fresh grout rheological behaviour. On the other hand, silica fume dosage turned out to be the factor with the least contribution to improve the grout rheological behaviour compared to the other two factors reported in this study. The results summarised in this paper are part of a larger study and precede the analysis of the performance of those grouts when injected into different porous media that simulate old masonries.

Non-Newtonian deterministic lateral displacement separator: theory and simulations

Abstract: Deterministic lateral displacement devices have been proved to be an efficient way to perform continuous particle separation in microfluidic applications (Huang et al. Science 304:987–990, 2004). On the basis of their size, particles traveling through an array of obstacles follow different paths and can be separated in outflow. One limitation of such a technique is that each device works for a specific critical size to achieve particle separation, and a new device with different geometrical properties needs to be fabricated, as the dimensions of the particles to be separated change. In this work, we demonstrate the possibility to tune the critical particle size in a deterministic lateral displacement device by using non-Newtonian fluids as suspending liquid. The analysis is carried out by extending the theory developed for a Newtonian constitutive law (Inglis et al. Lab Chip 6:655–658, 2006) to account for fluid shear-thinning. 3-D finite element simulations are performed to compute the dynamics of a spherical particle flowing through the deterministic ratchet. The results show that fluid shear-thinning, by altering the flow field between the obstacles, contributes to decrease the critical particle diameter as compared to the Newtonian case. Numerical simulations demonstrate that tunability of the critical separation size can be achieved by using the flow rate as control parameter. A design formula, relating the separation diameter to the fluid rheology and the relevant geometrical parameters of the device, is derived. Such a formula, originally developed for a power-law model, is proved to work for non-Newtonian liquids with a general viscosity trend.

Generation of inkjet droplet of non-Newtonian fluid

Abstract: In this study, the generation of inkjet droplets of xanthan gum solutions in water–glycerin mixtures was investigated experimentally to understand the jetting and drop generation mechanisms of rheologically complex fluids using a drop-on-demand inkjet system based on a piezoelectric nozzle head. The ejected volume and velocity of droplet were measured while varying the wave form of bipolar shape to the piezoelectric inkjet head, and the effects of the rheological properties were examined. The shear properties of xanthan gum solutions were characterized for wide ranges of shear rate and frequency by using the diffusive wave spectroscopy microrheological method as well as the conventional rotational rheometry. The extensional properties were measured with the capillary breakup method. The result shows that drop generation process consists of two independent processes of ejection and detachment. The ejection process is found to be controlled primarily by high or infinite shear viscosity. Elasticity can affect the flow through the converging section of inkjet nozzle even though the effect may not be strong. The detachment process is controlled by extensional viscosity. Due to the strain hardening of polymers, the extensional viscosity becomes orders of magnitude larger than the Trouton viscosities based on the zero and infinite shear viscosities. The large extensional stress retards the extension of ligament, and hence the stress lowers the flight speed of the ligament head. The viscoelastic properties at the high-frequency regime do not appear to be directly related to the drop generation process even though it can affect the extensional properties.

Flow of concentrated solutions of starlike micelles under large-amplitude oscillatory shear

Abstract: The non-linear viscoelasticity of concentrated solutions and glasses of soft starlike micelles has been studied by large-amplitude oscillatory shear (LAOS). The non-linear response has been analysed using current schemes of Fourier transform (FT) rheology, and its character has been determined by the phase of the third harmonic contribution to the stress. The limitations of FT rheology and related analysis methods are discussed, and an alternative method is presented that takes into account all the higher harmonics. This method reveals a strain-hardening character of intracycle non-linearities at large strain amplitudes for all volume fractions. We also show that, although the relation of LAOS with steady shear measurements works qualitatively, due to inherent limitations of LAOS, steady shear data cannot be reproduced quantitatively.

A comparison of the magnetorheology of two ferrofluids with different magnetic field-dependent chaining behavior

Abstract: The effect of magnetic field-induced particle chaining on the magnetorheology of commercial iron oxide-based ferrofluids was investigated by comparison of a ferrofluid with particles that resist chaining and a ferrofluid with particles that interact when a field is applied, forming chain-like aggregates This difference between the two ferrofluids was confirmed by optical microscopy and dynamic light scattering in an applied magnetic field Both fluids had similar magnetic particle fraction, but showed different magnetorheological behavior Chaining resulted in a stronger magnetic field-dependent viscosity enhancement and the appearance of an elastic modulus The magnetorheology of these two fluids was described using the Mason number (Mn), resulting in two distinct Mn power law slopes at intermediate and small Mn values for the ferrofluid with magnetic field-induced aggregation The commonly used magnetic coupling parameter failed to distinguish the behavior of the two ferrofluids

Viscoelastic melt rheology and time-temperature superposition of polycarbonate – multi-walled carbon nanotube nanocomposites

Abstract: This work investigates the linear and non-linear viscoelastic melt rheology of four grades of polycarbonate melt compounded with 3 wt% Nanocyl NC7000 multi-walled carbon nanotubes and of the matching matrix polymers. Amplitude sweeps reveal an earlier onset of non-linearity and a strain overshoot in the nanocomposites. Mastercurves are constructed from isothermal frequency sweeps using vertical and horizontal shifting. Although all nanocomposites exhibit a second plateau at ∼105 Pa, the relaxation times estimated from the peak in loss tangent are not statistically different from those of pure melts estimated from cross-over frequencies: all relaxation timescales scale with molar mass in the same way, evidence that the relaxation of the polymer network is the dominant mechanism in both filled and unfilled materials. Non-linear rheology is also measured in large amplitude oscillatory shear. A comparison of the responses from frequency and amplitude sweep experiments reveals the importance of strain and temperature history on the response of such nanocomposites.

Interfacial localization of nanoclay particles in oil-in-water emulsions and its reflection in interfacial moduli

Abstract: The localization of nanoclay particles dispersed in the oil phase of a model oil-in-water emulsion depends on the wetting property of layered nanoparticles. Investigation at a single droplet interface shows that nanoclay is located at different interfacial regions depending on the hydrophilic property of the nanoclay surface. Hydrophobic nanoclays do not present Pickering phenomena at the interface and hardly form an interfacial layer. Hydrophilic nanoclay particles quickly move to the interface and form a Pickering interface with a high interfacial shear modulus. With surfactant, poor hydrophilic nanoclays can be located at the interface due to improvement of the wetting behavior caused by the surfactants dissolved in the aqueous continuous phase. With ionic molecules changing the wetting behavior of particles, the interfacial localization of nanoclays can be controlled and improve the mechanical property of emulsion.

Time-dependent non-linear dynamics of polymer solutions in microfluidic contraction flow—a numerical study on the role of elongational viscosity

Abstract: A generalised form of the finitely extensible non-linear elastic (FENE) model for modelling non-linear flow of semi-dilute polymer solutions is proposed. It accounts for conformation-dependent polymer elasticity and predicts shear-thinning shear viscosity, non-linear elongational viscosity and first and second normal stress differences. The rheometric material functions predicted by the model are critically compared with the results of the linear Phan–Thien–Tanner model. The predictabilities of these constitutive models under benchmark flow problems are evaluated by time-dependent simulations, using finite volume method based on a CFD simulation toolbox. The effects of the model parameters, the inertia and the contraction ratio are numerically studied. The modified FENE model qualitatively captures the non-linear flow phenomena of polymer solution in the high elasticity number (\(\mathrm {El}\)) flow regime observed in experiments. The results show that an accurate growth function of the elongational viscosity is the key to the prediction of the time-dependent highly asymmetric flow patterns.

Beneficial use of a cell coupling rheometry, conductimetry, and calorimetry to investigate the early age hydration of calcium sulfoaluminate cement

Abstract: A specific cell was designed to monitor simultaneously the evolution of the viscoelastic properties, electrical conductivity, and temperature of a cement paste with ongoing hydration. Hydration of calcium sulfoaluminate cement by demineralised water or by a borated solution was then investigated as an example. Borate anions acted as set retarders but to a smaller extent than with ordinary Portland cement. The delay in cement hydration resulted from the precipitation of an amorphous or poorly crystallized calcium borate, which also caused a rapid stiffening (and thus a loss of workability) of the paste after mixing. The gypsum content of the CSA cement was shown to play a key role in the control of the cement reactivity.

Shear thickening and shear-induced agglomeration of chemical mechanical polishing slurries using electrolytes

Abstract: Chemical mechanical polishing is a fundamental technology used in the semiconductor manufacturing industry to polish and planarize a wide range of materials for the fabrication of microelectronic devices. During the high-shear (∼1,000,000 s−1) polishing process, it is hypothesized that individual slurry particles are driven together to form large agglomerates (≥0.5 µm). These agglomerates are believed to trigger a shear-induced thickening effect and cause defects during polishing. We examined how the addition of various monovalent salts (CsCl, KCl, LiCl, and NaCl) and electrostatic stabilizing bases (KOH, NaOH, or CsOH) influenced the slurry’s thickening behavior. Overall, as the added salt concentration was increased from 0.02 to 0.15 M, the shear rate at which the slurry thickened (i.e., the critical shear rate) decreased. Slurries with added CsCl, NaCl, and LiCl thickened at comparable shear rates (∼20,000–70,000 s−1) and, in general, followed ion hydration theory (poorly hydrated ions caused the slurry to thicken at lower shear rates). However, slurries with added KCl portrayed thickening behavior at higher critical shear rates (∼35,000–100,000 s−1) than other chloride salts. Also, slurries stabilized with CsOH thickened at higher shear rates (∼90,000–140,000 s−1), regardless of the added salt cation or concentration, than the slurries with KOH or NaOH. The NaOH-stabilized slurries displayed thickening at the lowest shear rates (∼20,000 s−1). The thickening dependence on slurry base cation indicates the existence of additional close-range structure forces that are not predicted by the Derjaguin–Landau–Verwey–Overbeek colloidal stability theory.

Aging, rejuvenation, and thixotropy in yielding magnetorheological fluids

Abstract: The yielding behavior of dilute magnetorheological (MR) fluids has been investigated using creep–recovery tests. At very low stress levels, MR fluids behave in the linear viscoelastic regime as demonstrated by the fact that the instantaneous strain equals the instantaneous (elastic) recovery. In this region, gap-spanning field-induced structures support the stress levels applied. Upon increasing the stress value, the MR fluid evolves towards a nonlinear viscoelastic response. Here, the retarded elastic and viscous strain decrease, and the plastic contribution to the instantaneous strain grows probably due to the appearance of unattached field-induced structures. A larger stress value results in a viscoplastic solid behavior with negligible retarded and viscous strain and a fully plastic instantaneous strain. Finally, a plastic fluid behavior is found when the stress value is larger than the so-called yield stress. MR fluids exhibit an intermediate behavior between non-thixotropic (simple) and highly thixotropic model yield stress fluids.

Comparison of stress-controlled and strain-controlled rheometers for large amplitude oscillatory shear

Abstract: In linear viscoelastic region, it is well known that dynamic modulus and dynamic compliance can be converted to each other. However, it is questionable whether there exists an interconversion between large amplitude oscillatory shear (LAOS) data measured from different types of rheometers—stress-controlled and strain-controlled rheometers. Hence, we tried to prove the existence by use of polyethylene oxide (PEO) aqueous solutions with well-developed entanglements. From this experiment, we can conclude that a stress-controlled rheometer can simulate LAOS behavior measured from a strain-controlled rheometer under the conditions where inertia effect is not significant. Furthermore, it is investigated whether the LAOS data of the stress-controlled rheometer obey stress–frequency superposition as the strain–frequency superposition found by Cho et al. (J Rheol 54:27–63, 2010) from LAOS data measured by the strain-controlled rheometer. This scaling relation shows that the dimensionless stress amplitude is a function of zeta which is the product of the stress amplitude and linear viscoelastic function J′(ω). The plot shows that all of the data are superposed in a single curve without regard to frequency, molecular weight, and concentration of PEO aqueous solutions.

A simple shear cell for the direct visualization of step-stress deformation in soft materials

Abstract: We introduce a custom-built stress-controlled shear cell coupled to a confocal microscope for direct visualization of constant-stress shear deformation in soft materials. The torque generator is a cylindrical Taylor–Couette system with a Newtonian fluid between a rotating inner bob and a free-to-move outer cup. A spindle/cone assembly is coaxially coupled to the cup and transfers the torque exerted by the fluid to the sample of interest in a cone-and-plate geometry. We demonstrate the performance of our device in both steady-state and transient experiments with different viscoelastic materials. Our apparatus can conduct unidirectional constant-stress experiments as accurately as most commercial rheometers, with the capability to directly visualize the flow field using tracer particles. Further, our step-stress experiments on viscoelastic materials are devoid of creep ringing, which is an advantageous aspect of our torque generation mechanism. We believe that the device presented here could serve as a powerful and cost-effective tool to investigate the microstructural determinants of nonlinear rheology in complex fluids.

Rheological and electrical properties of EVA copolymer filled with bamboo charcoal

Abstract: The electrical and rheological properties of an ethylene vinyl acetate (EVA) copolymer filled with bamboo charcoal were investigated. The composites were prepared by melt process in an internal batch mixer. Size distribution analysis showed that d(50) and d(90) values of the bamboo charcoal particles are 12.7 and 40 μm, respectively, with a mean diameter of 22 μm. Scanning electron microscopy proved that the particles of bamboo charcoal present a rectangular shape. The electrical percolation threshold was observed at 0.18 volume fraction (35 wt%) of bamboo. Beyond the percolation threshold, a considerable increase in electrical properties was observed up to a limit value of 10-2 S/m. The rheological percolation was studied from different rheological models. As a result, the rheological percolation threshold was observed at 0.3 volume fraction (50 wt%) of bamboo charcoal contents. So, the electrical percolation occurs before the rheological percolation. This is principally due to the filler’s characteristics such as the specific surface area, the aspect ratio, and the surface properties. Finally, the bamboo charcoal confers high electrical properties to the EVA composite without inducing strong changes in its viscoelastic properties.