Journal•ISSN: 0936-5214
Synlett
Thieme Medical Publishers (Germany)
About: Synlett is an academic journal published by Thieme Medical Publishers (Germany). The journal publishes majorly in the area(s): Catalysis & Enantioselective synthesis. It has an ISSN identifier of 0936-5214. Over the lifetime, 16582 publications have been published receiving 232058 citations. The journal is also known as: Synlett (Stuttgart. Print).
Topics: Catalysis, Enantioselective synthesis, Aryl, Chemistry, Palladium
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TL;DR: A wide range of aryl reagents have been explored in the past five years as mentioned in this paper, of which the aryls halides are among the most promising procedures, covering the litera- ture published through May 2003.
Abstract: Copper-catalyzed C-N-, C-O- and C-S-coupling reac- tions are powerful tools in organic synthesis and have been exten- sively reinvestigated in the past five years. The understanding of solubilizing and accelerating effects exhibited by substrates and ligands initiated novel developments originally on N-arylation of amines, amides, and nitrogen heterocycles. Nevertheless practical methods for the syntheses of aryl ethers and aryl thioethers have been established as well. A wide range of arylating reagents was ex- plored, of which the aryl halides will be presented in this overview. Among a growing set of ligands and optimized reaction protocols, the most promising procedures are highlighted, covering the litera- ture published through May 2003.
671 citations
637 citations
590 citations
TL;DR: This "combinatorial reaction finding" provides also a powerful tool to the understanding of the rules of organic chemistry, especially structure-reactivity relationships.
Abstract: The discovery of novel chemical reactions or reaction se- quences that are able to generate useful chemical products may be regarded as the heart of organic chemistry. We present here con- cepts and methods on how to find and explore new multi component reactions, especially with automated combinatorial methods. This "combinatorial reaction finding" provides also a powerful tool to the understanding of the rules of organic chemistry, especially structure-reactivity relationships.
491 citations
TL;DR: In this paper, the half-peak potentials for over 180 organic substrates obtained via cyclic voltammetry were reported and used in assessing the thermodynamics of an electron-transfer process.
Abstract: Herein, we report half-peak potentials for over 180 organic substrates obtained via cyclic voltammetry. These values are of great use in assessing the thermodynamics of an electron-transfer process. In addition, we disclose a simple computational method to determine redox potentials of organic substrates.
466 citations