Journal•ISSN: 0040-6031
Thermochimica Acta
Elsevier BV
About: Thermochimica Acta is an academic journal published by Elsevier BV. The journal publishes majorly in the area(s): Thermal decomposition & Differential scanning calorimetry. It has an ISSN identifier of 0040-6031. Over the lifetime, 19176 publications have been published receiving 362692 citations. The journal is also known as: TA.
Topics: Thermal decomposition, Differential scanning calorimetry, Thermal analysis, Enthalpy, Thermogravimetry
Papers published on a yearly basis
Papers
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TL;DR: In this article, the authors have developed recommendations for reliable evaluation of kinetic parameters (the activation energy, the preexponential factor, and the reaction model) from the data obtained by means of thermal analysis methods such as TGA, differential scanning calorimetry (DSC), and differential thermal analysis (DTA).
4,112 citations
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TL;DR: In this article, a classification of model-free isoconversion methods for the calculation of activation energies of thermally activated reactions is proposed, by deriving expressions for the main sources of error which includes the inaccuracy in reaction rate measurement, approximations for the temperature integral and inaccuracies in determination of temperature for equivalent fraction transformed.
1,393 citations
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TL;DR: In this paper, the importance of the correct selection for the assessment of the progress of the reaction and the acquisition of representative experimental data, as well as the effect of non-isothermal conditions and possible change of the equilibrium on the kinetic equation are stressed.
1,249 citations
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TL;DR: In this paper, the model-free and model-fitting approaches have been applied to data for nonisothermal and isothermal thermal decompositions of HMX and ammonium dinitramide.
1,168 citations
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TL;DR: In this paper, the thermal properties of several imidazolium salts were investigated using DSC and TGA/SDTA data, and it was observed that aluminium catalyzes the decomposition of the salts containing the inorganic fluoride anions.
963 citations