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1,2,3‐Triazoles and 1,2,3‐Triazolium Ions as Catalysts

Kohsuke Ohmatsu, +1 more
- pp 221-247
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The article was published on 2022-02-14 and is currently open access. It has received 1 citations till now.

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Enantioselective dearomatization reactions of heteroarenes by anion-binding organocatalysis

TL;DR: An overview of the different methodologies and advances in anion-binding catalyzed dearomatization reactions of different heteroarenes can be found in this paper , where a chiral contact ion pair formation by activation of the electrophilic reaction partner is discussed.
References
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The growing impact of click chemistry on drug discovery.

TL;DR: The copper-(I)-catalyzed 1,2,3-triazole formation from azides and terminal acetylenes is a particularly powerful linking reaction, due to its high degree of dependability, complete specificity, and the bio-compatibility of the reactants.
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1,3-Dipolar Cycloadditions. Past and Future†

TL;DR: In contrast to the very large number of special methods applicable to syntheses in the heterocyclic series, relatively few general methods are available as discussed by the authors, and the 1,3-dipolar addition offers a remarkably wide range of utility in the synthesis of five-membered heterocycles.
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Light-driven monodirectional molecular rotor

TL;DR: In this article, the authors report repetitive, monodirectional rotation around a central carbon-carbon double bond in a chiral, helical alkene, with each 360° rotation involving four discrete isomerization steps activated by ultraviolet light or a change in the temperature of the system.
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‘Click’ Chemistry in Polymer and Materials Science

TL;DR: The metal catalyzed azide/alkyne "click" reaction (a variation of the Huisgen 1,3-dipolar cycloaddition reaction between terminal acetylenes and azides) represents an important contribution towards this endeavor.
Journal ArticleDOI

Applications of Orthogonal “Click” Chemistries in the Synthesis of Functional Soft Materials

TL;DR: This paper aims to demonstrate the efforts towards in-situ applicability of EMMARM, which aims to provide real-time information about the physical properties of EMTs and their applications in the treatment of cancer.