Citations
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Coordination chemistry of schiff base complexes of molybdenum
A. Syamal,Mannar R. Maurya +1 more
TL;DR: Recapitulatif de travaux concernant la preparation and the caracterisation spectrometrique de complexes du molybdene avec une serie de bases de Schiff.
Journal ArticleDOI
Photochemical and catalytic properties of dimeric species of molybdenum(V)
TL;DR: In this paper, the authors present an update of data obtained from studies performed on these systems and the contribution of our laboratory to the understanding of the photochemical and catalytic properties of the di μ-oxo-dimers of molybdenum(V).
Journal ArticleDOI
Synthesis, spectroscopic characterization and structural studies of chloro dioxotriphenylphosphine oxide (O, O-dialkyl/diphenyl(alkylene)dithiophosphate) molybdenum(VI) complexes: crystal structure of MoO2Cl2(OSMe2)2
Neeta Manwani,Mukesh Chand Gupta,Raju Ratnani,John E. Drake,Michael B. Hursthouse,Mark E. Light +5 more
TL;DR: MoO2Cl2(OSMe2)(2) was determined by single-crystal X-ray diffraction and crystallizes as orthorhombic in the space group Pbca.
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Dioxomolybdenum(VI) complexes of new binucleating schiff bases derived from methylene- or dithio-bis(salicyclaldehyde) and various amines☆
TL;DR: In this article, the synthesis of binuclear dioxomolybdenum(VI) complexes of the type [(MoO2)2L), where L is a flexibly-bridged hexadentate tetraanionic Schiff base derived from the condensation of methylene- or dithio-bis(salicylaldehyde) with o-aminophenol, 2-aminoethanol, 2amino-2-methyl propanol or 1-amide-2propanol, are reported.
References
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Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand
TL;DR: In this article, the first isolable transition-metal complexes containing a coordinated dihydrogen molecule was reported, characterized by a variety of spectroscopic and structural methods to possess n/sup 2/bonded hydrogen.
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Vibrational investigations of polyoxometalates. 3. Isomerism in molybdenum(VI) and tungsten(VI) compounds related to the Keggin structure
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A heteropolyanion with fivefold molecular symmetry that contains a nonlabile encapsulated sodium ion. The structure and chemistry of [NaP5W30O110]14-
TL;DR: In this paper, the assemblage cyclique de 5 unites PW 6 O 22, l'ion Na etant situe a l'interieur du polyanion sur un axe d'ordre 5.
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Reactions of Metal-Metal Multiple Bonds. 10. Reactions of Mo2(OR)6 (M Triple Bond M) and (M(OR)4)x Compounds with Molecular Oxygen. Preparation and Characterization of Oxo-Alkoxides of Formula MoO2(OR)2, MoO2(OR)2(bpy), MoO(OR)4, Mo3O(OR)10, Mo4O8(OR)4(py)4 and Mo6O10(OR)12.
TL;DR: In this paper, it has been shown that the Mo=Mo bond in M02(OR)6 compounds is labile toward a number of oxidative-addition reactions, including those involving molecular oxygen.