Q1. What are the contributions in this paper?
In this paper, Mahmood et al. reported the crystal structures of new 2D polymeric cadmium ( II ) complexes containing 1,3imidazolidine-2-thione ( Imt ) ligand.
2D polymeric cadmium(II) complexes containing 1,3-imidazolidine-2-thione (Imt) ligand, [Cd(Imt)(H2O)2(SO4)]n and [Cd(Imt)2(N3)2]n
Rashid Mahmood,Saeed Ahmad,Mohammed Fettouhi,Thierry Roisnel,Mazhar Amjad Gilani,Kashif Mehmood,Ghulam Murtaza,Anvarhusein A. Isab +7 more
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TLDR
In this paper, the structural investigation of two polymeric cadmium(II) complexes of imidazolidine-2-thione (Imt) based on sulfate or azide ions was carried out.About:
This article is published in Journal of Molecular Structure.The article was published on 2018-03-15 and is currently open access. It has received 9 citations till now. The article focuses on the topics: Octahedral molecular geometry & Coordination sphere.read more
Figures
Table 1. Crystal data and details of the structure refinement for compounds 1 and 2. 
Figure 6. View of the packing of the 2D networks in compound 2 in the form of a 3D network 
Table 2. Selected bond distances (Å) and bond angles (˚) for compounds 1 and 2 
Figure 4. ORTEP diagram of the molecular structure of compound 2 showing the atomic labeling scheme. Thermal ellipsoids have been drawn t 50% probability level. Symmetry codes: i = x, 1+y, z ; ii = -x+1/2, -y+3/2, 1-z ; iii = 1-x, y, -z+3/2 
Table 3 Hydrogen bond parameters in complexes 1 and 2 (Å, deg)a _______________________________________________________________________ D-H...A d(D-H) d(H...A) d(D...A) ∠(D-H-A) _______________________________________________________________________ (1)
Citations
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Heterocyclic-2-thione derivatives of group 10–12 metals: Coordination versatility, activation of CS (thione) bonds and biochemical potential
TL;DR: A survey of relatively recent coordination compounds of these metals is described with selective heterocyclic thiones, namely, pyridine-2-thione, pyrimidine-two-thiones and purine-6thione as discussed by the authors.
Journal ArticleDOI
Synthesis, S-alkylation, and fungicidal activity of 4-(benzylideneamino)thioglycolurils
Galina A. Gazieva,T. V. Nechaeva,N. N. Kostikova,Natalya V. Sigay,S. A. Serkov,Sergey V. Popkov +5 more
TL;DR: In this article, a series of 1,3-disubstituted 4-benzylideneamino-5thioxohexahydroimidazo[4,5-d]imidazol-2(1H)-ones (thioglycolurils) was synthesized via the reaction of 5,7-disubsubstitized 3-thioxoperhydroIMidazo [4, 5-e]-1,2,4-triazin-6-ones with hydroxy-, alkoxy-, and
Journal ArticleDOI
Synthesis, crystalline structures and photophysical properties of new cadmium iodide complexes with thiocarbamoyl-pyrazoline ligands
Persiely P. Rosa,Guilherme B Laranjeira,Lis R.V. Favarin,Lucas Pizzuti,Amilcar Machulek Junior,Leandro M. C. Pinto,Claudia C. Gatto,Anderson R.L. Caires,Carolina G. Oliveira,Victor M. Deflon,Gleison A. Casagrande +10 more
TL;DR: In this article, new mononuclear cadmium (II) complexes based on thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized.
Journal ArticleDOI
Synthesis, characterization, DFT calculations and antimicrobial studies of cadmium(II) sulfate complexes of thioureas and 2-mercaptopyridine; X-ray structures of polymeric diaqua(N,N′-dimethylthiourea) sulfatocadmium(II) and bis(2-mercaptopyridine)sulfatocadmium(II)
Saeed Ahmad,Muhammad Saleem,Ivelina Georgieva,Tobias Rüffer,Dieter Schaarschmidt,Heinrich Lang,Ghulam Murtaza,Irshad Hussain,Habib-ur-Rehman,Anvarhusein A. Isab,Muhammad Riaz Malik,Saqib Ali +11 more
TL;DR: In this article, the properties of the Cadmium(II) complexes of thioureas, [Cd(Tu)(SO4)(H2O)2]n (1), [Ccd(Dmtu)2(SO4), H2O 2, H2 O 2 ]n (2) and Mpy 2(Mpy) 2(SO 4 )n (3) were characterized by IR and NMR spectroscopy, and thermal analysis.
Journal ArticleDOI
Synthesis, characterization and in vitro cytotoxicity of Au(I) carbene complexes
Sughra Gulzar,Zeeshan Abid,Raja Shahid Ashraf,Muhammad Sher,Anvarhusein A. Isab,Muhammad Altaf +5 more
TL;DR: In this paper , the authors synthesized four new Au(I)-NHC complexes (1-4) by reacting (1,3-bis(2,6-di-isopropylphenyl)imidazol-2-ylidenegold(I)chloride) (Au(Ipr)Cl) with four different thiones, namely N-(i-propyl)IMidazolidine- 2-thione (i-PrImt), N-(dipropyl)-imidrazolidine (2-THione), 1, 3-Diazinane-2,Diaz, and 1,3 -Diazipane- 2 -thione(Diap), which showed moderate anticancer activities against selected cancer cell lines.
References
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Crystal structure refinement with SHELXL
TL;DR: New features added to the refinement program SHELXL since 2008 are described and explained.
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ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI)
TL;DR: L Lists of software presented and~or reviewed in the Journal of Applied Crystallography are available on the World Wide Web at the above address, together with information about the availability of the software where this is known.
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SHELXT - Integrated space-group and crystal- structure determination
TL;DR: This work automates routine small-molecule structure determination starting from single-crystal reflection data, the Laue group and a reasonable guess as to which elements might be present.
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Mercury CSD 2.0 – new features for the visualization and investigation of crystal structures
Clare F. Macrae,Ian J. Bruno,James A. Chisholm,Paul R. Edgington,Patrick McCabe,Elna Pidcock,Lucia Rodriguez-Monge,Robin Taylor,Jacco van de Streek,Peter A. Wood +9 more
TL;DR: Mercury as discussed by the authors is a crystal structure visualization tool that allows highly customizable searching of structural databases for intermolecular interaction motifs and packing patterns, as well as the ability to perform packing similarity calculations between structures containing the same compound.
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Ligand scrambling reactions of cyano(thione)gold(I) complexes and determination of their equilibrium constants
TL;DR: In this article, a series of thiones in DMSO using 13 C and 15 N NMR spectroscopy were investigated and the equilibrium constants (Keq) were determined for scrambling of all the complexes by integrating the CN resonances in the 13 C NMR recorded at 298 K.