Q1. What are the contributions in this paper?
In this paper, Mahmood et al. reported the crystal structures of new 2D polymeric cadmium ( II ) complexes containing 1,3imidazolidine-2-thione ( Imt ) ligand.
2D polymeric cadmium(II) complexes containing 1,3-imidazolidine-2-thione (Imt) ligand, [Cd(Imt)(H2O)2(SO4)]n and [Cd(Imt)2(N3)2]n
Rashid Mahmood,Saeed Ahmad,Mohammed Fettouhi,Thierry Roisnel,Mazhar Amjad Gilani,Kashif Mehmood,Ghulam Murtaza,Anvarhusein A. Isab +7 more
Reads0
Chats0
TLDR
In this paper, the structural investigation of two polymeric cadmium(II) complexes of imidazolidine-2-thione (Imt) based on sulfate or azide ions was carried out.About:
This article is published in Journal of Molecular Structure.The article was published on 2018-03-15 and is currently open access. It has received 9 citations till now. The article focuses on the topics: Octahedral molecular geometry & Coordination sphere.read more
Figures
Table 1. Crystal data and details of the structure refinement for compounds 1 and 2. 
Figure 6. View of the packing of the 2D networks in compound 2 in the form of a 3D network 
Table 2. Selected bond distances (Å) and bond angles (˚) for compounds 1 and 2 
Figure 4. ORTEP diagram of the molecular structure of compound 2 showing the atomic labeling scheme. Thermal ellipsoids have been drawn t 50% probability level. Symmetry codes: i = x, 1+y, z ; ii = -x+1/2, -y+3/2, 1-z ; iii = 1-x, y, -z+3/2 
Table 3 Hydrogen bond parameters in complexes 1 and 2 (Å, deg)a _______________________________________________________________________ D-H...A d(D-H) d(H...A) d(D...A) ∠(D-H-A) _______________________________________________________________________ (1)
Citations
More filters
Journal ArticleDOI
Heterocyclic-2-thione derivatives of group 10–12 metals: Coordination versatility, activation of CS (thione) bonds and biochemical potential
TL;DR: A survey of relatively recent coordination compounds of these metals is described with selective heterocyclic thiones, namely, pyridine-2-thione, pyrimidine-two-thiones and purine-6thione as discussed by the authors.
Journal ArticleDOI
Synthesis, S-alkylation, and fungicidal activity of 4-(benzylideneamino)thioglycolurils
Galina A. Gazieva,T. V. Nechaeva,N. N. Kostikova,Natalya V. Sigay,S. A. Serkov,Sergey V. Popkov +5 more
TL;DR: In this article, a series of 1,3-disubstituted 4-benzylideneamino-5thioxohexahydroimidazo[4,5-d]imidazol-2(1H)-ones (thioglycolurils) was synthesized via the reaction of 5,7-disubsubstitized 3-thioxoperhydroIMidazo [4, 5-e]-1,2,4-triazin-6-ones with hydroxy-, alkoxy-, and
Journal ArticleDOI
Synthesis, crystalline structures and photophysical properties of new cadmium iodide complexes with thiocarbamoyl-pyrazoline ligands
Persiely P. Rosa,Guilherme B Laranjeira,Lis R.V. Favarin,Lucas Pizzuti,Amilcar Machulek Junior,Leandro M. C. Pinto,Claudia C. Gatto,Anderson R.L. Caires,Carolina G. Oliveira,Victor M. Deflon,Gleison A. Casagrande +10 more
TL;DR: In this article, new mononuclear cadmium (II) complexes based on thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized.
Journal ArticleDOI
Synthesis, characterization, DFT calculations and antimicrobial studies of cadmium(II) sulfate complexes of thioureas and 2-mercaptopyridine; X-ray structures of polymeric diaqua(N,N′-dimethylthiourea) sulfatocadmium(II) and bis(2-mercaptopyridine)sulfatocadmium(II)
Saeed Ahmad,Muhammad Saleem,Ivelina Georgieva,Tobias Rüffer,Dieter Schaarschmidt,Heinrich Lang,Ghulam Murtaza,Irshad Hussain,Habib-ur-Rehman,Anvarhusein A. Isab,Muhammad Riaz Malik,Saqib Ali +11 more
TL;DR: In this article, the properties of the Cadmium(II) complexes of thioureas, [Cd(Tu)(SO4)(H2O)2]n (1), [Ccd(Dmtu)2(SO4), H2O 2, H2 O 2 ]n (2) and Mpy 2(Mpy) 2(SO 4 )n (3) were characterized by IR and NMR spectroscopy, and thermal analysis.
Journal ArticleDOI
Synthesis, characterization and in vitro cytotoxicity of Au(I) carbene complexes
Sughra Gulzar,Zeeshan Abid,Raja Shahid Ashraf,Muhammad Sher,Anvarhusein A. Isab,Muhammad Altaf +5 more
TL;DR: In this paper , the authors synthesized four new Au(I)-NHC complexes (1-4) by reacting (1,3-bis(2,6-di-isopropylphenyl)imidazol-2-ylidenegold(I)chloride) (Au(Ipr)Cl) with four different thiones, namely N-(i-propyl)IMidazolidine- 2-thione (i-PrImt), N-(dipropyl)-imidrazolidine (2-THione), 1, 3-Diazinane-2,Diaz, and 1,3 -Diazipane- 2 -thione(Diap), which showed moderate anticancer activities against selected cancer cell lines.
References
More filters
Journal ArticleDOI
Synthesis and structures of dichlorotetrakis-(phenylthiourea) cadmium(ii) and catena-bis(thiocyanate) bis(phenylthiourea)cadmium(ii)
TL;DR: In this article, two new cadmium-II complexes with phenylthiourea (PTU) have been prepared and characterized structurally by X-ray diffaction, which can serve as either a monodentate ligand or a μ2-bridging ligand upon coordination to a metal atom.
Journal ArticleDOI
The crystal structure of monothiourea‐cadmium sulphate dihydrate
Journal ArticleDOI
Synthesis and spectroscopic characterization of cadmium(II) complexes of thiones and thiocyanate
TL;DR: In this paper, the upfield shift in the >C=S resonance of thiones in the 13C NMR and downfield shift of N−H resonance in 1H NMR are consistent with sulfur coordination to cadmium(II).
Journal ArticleDOI
A novel polymeric Cd[SSe2N2] central core five-coordinate complex: Synthesis, X-ray structure and 113Cd, 77Se CP MAS NMR characterization of catena(bis(μ2-selenocyanato-N,Se)-(N,N′-dimethylimidazolidine- 2-thione-S)-cadmium(II))
TL;DR: In this paper, the 77Se CP MAS NMR data are consistent with two different selenium sites and the shielding tensor parameters of 113Cd point to a near axial symmetry for the cadmium environment.
Journal ArticleDOI
Synthesis and Structural Characterization of Dibromidobis(N,N′-dimethylthiourea-κS)cadmium(II) and Diiodidobis(N,N′-dimethylthiourea-κS)cadmium(II)
Saeed Ahmad,Muhammad Altaf,Helen Stoeckli-Evans,Anvarhusein A. Isab,Muhammam Riaz Malik,Saqib Ali,Shaukat Shuja +6 more
TL;DR: Cadmium(II) complexes were also characterized by IR and NMR spectroscopy and the data are consistent with the structures of the compounds as mentioned in this paper. But they have no crystallographic symmetry.