Q1. What are the contributions in this paper?
In this paper, Mahmood et al. reported the crystal structures of new 2D polymeric cadmium ( II ) complexes containing 1,3imidazolidine-2-thione ( Imt ) ligand.
2D polymeric cadmium(II) complexes containing 1,3-imidazolidine-2-thione (Imt) ligand, [Cd(Imt)(H2O)2(SO4)]n and [Cd(Imt)2(N3)2]n
Rashid Mahmood,Saeed Ahmad,Mohammed Fettouhi,Thierry Roisnel,Mazhar Amjad Gilani,Kashif Mehmood,Ghulam Murtaza,Anvarhusein A. Isab +7 more
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TLDR
In this paper, the structural investigation of two polymeric cadmium(II) complexes of imidazolidine-2-thione (Imt) based on sulfate or azide ions was carried out.About:
This article is published in Journal of Molecular Structure.The article was published on 2018-03-15 and is currently open access. It has received 9 citations till now. The article focuses on the topics: Octahedral molecular geometry & Coordination sphere.read more
Figures
Table 1. Crystal data and details of the structure refinement for compounds 1 and 2. 
Figure 6. View of the packing of the 2D networks in compound 2 in the form of a 3D network 
Table 2. Selected bond distances (Å) and bond angles (˚) for compounds 1 and 2 
Figure 4. ORTEP diagram of the molecular structure of compound 2 showing the atomic labeling scheme. Thermal ellipsoids have been drawn t 50% probability level. Symmetry codes: i = x, 1+y, z ; ii = -x+1/2, -y+3/2, 1-z ; iii = 1-x, y, -z+3/2 
Table 3 Hydrogen bond parameters in complexes 1 and 2 (Å, deg)a _______________________________________________________________________ D-H...A d(D-H) d(H...A) d(D...A) ∠(D-H-A) _______________________________________________________________________ (1)
Citations
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Heterocyclic-2-thione derivatives of group 10–12 metals: Coordination versatility, activation of CS (thione) bonds and biochemical potential
TL;DR: A survey of relatively recent coordination compounds of these metals is described with selective heterocyclic thiones, namely, pyridine-2-thione, pyrimidine-two-thiones and purine-6thione as discussed by the authors.
Journal ArticleDOI
Synthesis, S-alkylation, and fungicidal activity of 4-(benzylideneamino)thioglycolurils
Galina A. Gazieva,T. V. Nechaeva,N. N. Kostikova,Natalya V. Sigay,S. A. Serkov,Sergey V. Popkov +5 more
TL;DR: In this article, a series of 1,3-disubstituted 4-benzylideneamino-5thioxohexahydroimidazo[4,5-d]imidazol-2(1H)-ones (thioglycolurils) was synthesized via the reaction of 5,7-disubsubstitized 3-thioxoperhydroIMidazo [4, 5-e]-1,2,4-triazin-6-ones with hydroxy-, alkoxy-, and
Journal ArticleDOI
Synthesis, crystalline structures and photophysical properties of new cadmium iodide complexes with thiocarbamoyl-pyrazoline ligands
Persiely P. Rosa,Guilherme B Laranjeira,Lis R.V. Favarin,Lucas Pizzuti,Amilcar Machulek Junior,Leandro M. C. Pinto,Claudia C. Gatto,Anderson R.L. Caires,Carolina G. Oliveira,Victor M. Deflon,Gleison A. Casagrande +10 more
TL;DR: In this article, new mononuclear cadmium (II) complexes based on thiocarbamoyl-pyrazoline ligands were synthesized and structurally characterized.
Journal ArticleDOI
Synthesis, characterization, DFT calculations and antimicrobial studies of cadmium(II) sulfate complexes of thioureas and 2-mercaptopyridine; X-ray structures of polymeric diaqua(N,N′-dimethylthiourea) sulfatocadmium(II) and bis(2-mercaptopyridine)sulfatocadmium(II)
Saeed Ahmad,Muhammad Saleem,Ivelina Georgieva,Tobias Rüffer,Dieter Schaarschmidt,Heinrich Lang,Ghulam Murtaza,Irshad Hussain,Habib-ur-Rehman,Anvarhusein A. Isab,Muhammad Riaz Malik,Saqib Ali +11 more
TL;DR: In this article, the properties of the Cadmium(II) complexes of thioureas, [Cd(Tu)(SO4)(H2O)2]n (1), [Ccd(Dmtu)2(SO4), H2O 2, H2 O 2 ]n (2) and Mpy 2(Mpy) 2(SO 4 )n (3) were characterized by IR and NMR spectroscopy, and thermal analysis.
Journal ArticleDOI
Synthesis, characterization and in vitro cytotoxicity of Au(I) carbene complexes
Sughra Gulzar,Zeeshan Abid,Raja Shahid Ashraf,Muhammad Sher,Anvarhusein A. Isab,Muhammad Altaf +5 more
TL;DR: In this paper , the authors synthesized four new Au(I)-NHC complexes (1-4) by reacting (1,3-bis(2,6-di-isopropylphenyl)imidazol-2-ylidenegold(I)chloride) (Au(Ipr)Cl) with four different thiones, namely N-(i-propyl)IMidazolidine- 2-thione (i-PrImt), N-(dipropyl)-imidrazolidine (2-THione), 1, 3-Diazinane-2,Diaz, and 1,3 -Diazipane- 2 -thione(Diap), which showed moderate anticancer activities against selected cancer cell lines.
References
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Cadmium cyanide complexes with heterocyclic thiones: Solid state and solution NMR studies
TL;DR: Cadmium(II)cyanide complexes of various thiones have been prepared and characterized by elemental analysis, IR and solid as well as solution NMR spectroscopy and the presence of different coordination numbers in some complexes is shown.
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Dibromidobis(N,N,N',N'-tetra-methyl-thio-urea-κS)cadmium(II).
TL;DR: In the title compound, [CdBr2(C5H12N2S)2], the CdII atom lies on a twofold rotation axis and exhibits a distorted tetrahedral coordination environment defined by two S atoms of two tetramethylthiourea (tmtu) ligands and two bromide ions.
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Diiodidobis(N,N,N',N'-tetra-methyl-thio-urea-κS)cadmium(II).
TL;DR: In the title compound, [CdI2(C5H12N2S)2], the CdII ion is located on a twofold rotation axis and is coordinated in a distorted tetrahedral mode by two iodide ions and by two tetramethylthiourea (tmtu) ligands through their S atoms.
Journal ArticleDOI
catena-Poly[[bis(thiocyanato-κN)cadmium(II)]-di-μ-thiourea-κ4S:S]
TL;DR: The CdII ion in the title complex, [Cd(SCN)2{SC(NH2)2]∞, is situated at a centre of symmetry, and is bound to two N atoms belonging to thiocyanate groups and to four S atoms of bridging thio-urea ligands as mentioned in this paper.
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Dicyanidobis(thiourea-κS)cadmium(II) monohydrate
TL;DR: In the title compound, [Cd(CN)2(CH4N2S)2]·H2O, the Cd atom lies on a twofold rotation axis and is bonded to two S atoms of thiourea and two C atoms of the cyanide anions in a distorted tetrahedral environment.