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A cascade strategy towards the direct synthesis of green polyesters with versatile functional groups

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TLDR
In this paper, a cascade polycondensation-coupling ring-opening polymerization (PROP) was proposed for the direct preparation of green copolyesters with versatile functionalities.
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This article is published in Polymer Chemistry.The article was published on 2021-10-26. It has received 4 citations till now. The article focuses on the topics: Polyester & Polymerization.

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Rapid synthesis of sustainable poly(ethylene 2,5-furandicarboxylate)-block-poly(tetramethylene oxide) multiblock copolymers with tailor-made properties via a cascade polymerization route

TL;DR: In this article, a cascade polycondensation-coupling ring-opening polymerization (PROP) strategy was proposed for the rapid synthesis of poly(ethylene 2,5-furandicarboxylate)-block-poly(tetramethylene oxide) multiblock copolymers (mBCPs), via the vacuum melt polymerization of cyclic oligo(methylene 2.5-fricarboxylic acid)s (COEFs) with PTMO diols.
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Effect of oligo(ethylene glycol) length on properties of poly(oligoethylene glycol terephthalate)s and their cyclic oligomers

TL;DR: In this paper , the effect of OEG segmental length on properties of cyclic oligo(ethylene glycol) (OEG) segments has been investigated in a cascade polycondensation-coupling ring-opening polymerization method to obtain high molecular weight POEGTs.
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An efficient cyclodepolymerization route for chemical recycling of poly(ethylene adipate)

TL;DR: CyCyclodepolymerization is a special chemical recycling (upcycling) method for polyesters based on the ring-chain equilibria in solution, yet it is usually carried out in halogenated solvents at temperatures around 200 as discussed by the authors .
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Helical Crystals in Aliphatic Copolyesters: From Chiral Amplification to Mechanical Property Enhancement.

TL;DR: In this article , a bottom-up strategy for achieving helical crystals via chiral amplification in copolyesters by incorporating a small amount of (d)-isosorbide into semicrystalline polyester, poly(ethylene brassylate) (PEB).
References
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Book

Principles of polymerization

TL;DR: In this paper, the authors present an overview of the properties of polymers and their applications in the literature, including the following: 1.1 Types of Polymers and Polymerization. 2.3 Linear, Branched, and Crosslinked Polymers.
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Biodegradable polymers as biomaterials

TL;DR: This review summarizes the main advances published over the last 15 years, outlining the synthesis, biodegradability and biomedical applications ofBiodegradable synthetic and natural polymers.
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Atom Economy—A Challenge for Organic Synthesis: Homogeneous Catalysis Leads the Way

TL;DR: The ability of transition metal complexes to preorganize π-electron systems serves as the basis both of simple additions usually accompanied by subsequent hydrogen shifts and of cycloadditions as mentioned in this paper.
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The E Factor: fifteen years on

TL;DR: In this article, the effect of the E Factor concept has had over the last fifteen years on developments in the chemical industry and pharmaceutical industry with regard to waste minimisation and to assess its current status in the broader context of green chemistry and sustainability.
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Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable

TL;DR: Inspired by the tremendous utility of petroleum-derived styrenic triblock copolymers, syntheses and understand the structure-property profiles of sustainable alternatives are developed, focusing on all renewable and all readily degradable aliphatic polyester triblocks as targets.
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