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Journal ArticleDOI

A Collective Description of-Electron Interactions: III. Coulomb Interactions in a Degenerate Electron Gas

David Pines
- 01 Nov 1953 - 
- Vol. 92, Iss: 3, pp 609-625
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TLDR
In this article, the behavior of the electrons in a dense electron gas is analyzed quantum-mechanically by a series of canonical transformations, and the results are related to the classical density fluctuation approach and Tomonaga's one-dimensional treatment of the degenerate Fermi gas.
Abstract
The behavior of the electrons in a dense electron gas is analyzed quantum-mechanically by a series of canonical transformations. The usual Hamiltonian corresponding to a system of individual electrons with Coulomb interactions is first re-expressed in such a way that the long-range part of the Coulomb interactions between the electrons is described in terms of collective fields, representing organized "plasma" oscillation of the system as a whole. The Hamiltonian then describes these collective fields plus a set of individual electrons which interact with the collective fields and with one another via short-range screened Coulomb interactions. There is, in addition, a set of subsidiary conditions on the system wave function which relate the field and particle variables. The field-particle interaction is eliminated to a high degree of approximation by a further canonical transformation to a new representation in which the Hamiltonian describes independent collective fields, with ${n}^{\ensuremath{'}}$ degrees of freedom, plus the system of electrons interacting via screened Coulomb forces with a range of the order of the inter electronic distance. The new subsidiary conditions act only on the electronic wave functions; they strongly inhibit long wavelength electronic density fluctuations and act to reduce the number of individual electronic degrees of freedom by ${n}^{\ensuremath{'}}$. The general properties of this system are discussed, and the methods and results obtained are related to the classical density fluctuation approach and Tomonaga's one-dimensional treatment of the degenerate Fermi gas.

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Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems

Andrea C. Ferrari, +68 more
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Electronic structure calculations with dynamical mean-field theory

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