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Journal ArticleDOI

A comparative review on foam-based versus lightweight aggregate-based alkali-activated materials and geopolymer

01 Dec 2021-Innovative Infrastructure Solutions (Springer International Publishing)-Vol. 6, Iss: 4, pp 1-20
TL;DR: In this paper, the authors provide an updated information on recent advances while stressing the sustainability of lightweight geopolymer materials over ordinary Portland cement products that are vastly in use, including perlite, pumice, shale, ceramsite, and slate sand.
Abstract: Alkali-activated materials and geopolymer are major sustainable alternative binding materials to ordinary Portland cement products with higher thermal resistance and often better durability properties. In lightweight form, they have an unmatched lowered thermal conductivity and insulating properties making them a perfect fit for optimized structural components with highest strength to density ratio and major energy savings in green buildings. For them to produce lightweight materials, generally either certain foaming agent or some types of lightweight aggregates in virgin, expanded, or recycled form are utilized that reduce the overall density through higher overall porosity. In accordance, this review provides an updated information on recent advances while stressing the sustainability of lightweight geopolymer materials over ordinary Portland cement products that are vastly in use. In the end, recent mechanical and durability properties developed and documented are reviewed and provided for future applications. Based on the result of this review, the most common lightweight aggregates used in literature are perlite, pumice, shale, ceramsite, and slate sand, in expanded and porous form, along with recycled thermosetting (e.g., rubber), or thermoplastic (e.g., polyethylene) materials. In foam form, chemical and mechanical foaming are the most commonly used foaming techniques to increase porosity of final materials. The pore mechanism of foam-based geopolymer is found to be different from that of lightweight aggregate-based geopolymer. This variation results in different physico-mechanical and durability properties such as better insulation properties (and lower thermal conductivity) for foam-based versus better mechanical properties for lightweight aggregate-based geopolymer.
Citations
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Journal ArticleDOI
TL;DR: In this article , a state-of-the-art review of the technical and production properties of the recent advances and perspectives of ultra-highperformance geopolymer concrete (UHP-GPC) is provided.

56 citations

Journal ArticleDOI
TL;DR: In this paper , the use of basalt fibers with silica fume to increase the structural integrity of foam concrete has been investigated and the results show that the effect of the inclusion of silica fiber can significantly influence the pore network and enhance fiber-paste matrix.

52 citations

Journal ArticleDOI
TL;DR: In this article , expanded perlite and fine-sized waste glass sand were used as the main aggregates in concrete mixes to reduce the pore network connectivity and increase the insulation properties of foam concrete.

52 citations

Journal ArticleDOI
TL;DR: In this article , the effects of nano-SiO2 on the properties of fly ash-based geopolymers including compressive strength, microstructure, hardening properties, shear bond strength, durability, and practical applications have been summarized.
Abstract: Abstract Nano-SiO2 is a non-toxic, tasteless, and pollution-free material with hydroxyl groups that facilitate the adsorption of water on its surface. Nano-SiO2 is characterized by small particle size, high purity, low density, large surface area, and good dispersion properties. In addition, nano-SiO2 has excellent stability, reinforcement, thixotropy, and optical and mechanical properties. The additive of nano-SiO2 can enhance the mechanical properties and microstructure of concrete. Therefore, nano-SiO2 is widely used as an additive in the field of building materials. Geopolymers have excellent mechanical properties, acid–alkali resistance, fire resistance, and high-temperature resistance. In addition, mineral waste and construction waste can be used as raw materials for geopolymers. Therefore, geopolymers have the potential to substitute ordinary Portland cement and have good prospects for application as construction materials. The application of nanomaterials in geopolymer products has shown that nano-SiO2 is effective in increasing the rate of geopolymerization reaction and reducing the setting time of geopolymers in a controlled quantity. Related results indicate that an appropriate quantity of nano-SiO2 can make the microstructure of fly ash-based geopolymers denser and produce higher mechanical strength. In this study, based on the mechanism of geopolymerization, the effects of nano-SiO2 on the properties of fly ash-based geopolymers including compressive strength, microstructure, hardening properties, shear bond strength, durability, and practical applications have been summarized. This study can provide a basis for understanding the effects of nano-SiO2 on the mechanical properties and durability of fly ash-based geopolymers.

42 citations

Journal ArticleDOI
TL;DR: In this paper , a critical literature review of current updates related to the fire performance of RF-reinforced GPC subjected to elevated temperatures and during fires is urgently necessary, conducting critical reviews on the type of RFs, spalling mechanism, physical inspection and properties of the RF-RGPCs.

38 citations

References
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Journal ArticleDOI
TL;DR: In this article, the authors present the results of comprehensive carbon footprint estimates for both geopolymer and OPC concrete, including energy expending activities associated with mining and transport of raw materials, manufacturing and concrete construction.

1,274 citations

Journal ArticleDOI
TL;DR: In this paper, a brief discussion of the class of cementing materials known as "alkali-activated binders" is provided, which are identified to have potential for utilization as a key component of a sustainable future global construction materials industry.

1,052 citations

Book
02 Apr 2003
TL;DR: Alkali-Activated Cement and Concrete as discussed by the authors is a type of Cementitious Systems that uses Alkaline Activators to activate slag cements and lime-pozzolan cements.
Abstract: Introduction 1. Alkaline Activators 2. Cementing Components 3. Hydration and Microstructure of Alkali-Activated Slag Cement 4. Properties of Alkali-Activated Slag Cement Pastes and Mortars (Under Both Atmospheric Pressure and Autoclave Conditions) 5. Properties of Alkali-Activated Slag Cement Concrete 6. Durability of Alkali-Activated Slag Cement and Concrete 7. Mix Design of Alkali-Activated Slag Cement Concrete 8. Alkali-Activated Portland Cement Based Blended Cement 9. Alkali-Activated Lime-Pozzolan Cement 10. Other Alkali-Activated Cementitious Systems 11. Applications of Alkali-Activated Cement And Concrete 12. Standards and Specifications

1,008 citations

Journal ArticleDOI
TL;DR: In this article, the compatibility relationship between C-A-S-H and N-Aluminum-modified calcium silicate hydrate (C-A,S,H) gels is assessed.

776 citations

Book
01 Jan 2009
TL;DR: In this article, the authors describe the synthesis and characterization of fly ash glass chemistry and inorganic polymer cements for geopolymers and their application in nuclear waste immobilization and toxic waste removal.
Abstract: Introduction to geopolymers Part 1 Geopolymer synthesis and characterisation: Fly ash glass chemistry and inorganic polymer cements Geopolymer precursor design Activating solution chemistry for geopolymers Nanostructure/microstructure of metakaolin geopolymers Nanostructure/microstructure of fly ash geopolymers Geopolymer synthesis kinetics Part 2 Manufacture and properties of geopolymers: Accelerated ageing of geopolymers Chemical durability of geopolymers Life-cycle analysis of geopolymers Engineering properties of geopolymer concrete Producing fire and heat-resistant geopolymers Utilisation of mining wastes to produce geopolymer binders Utilisation of non-thermally activated clays in the production of geopolymers Thermal properties of geopolymers Utilisation of low-calcium slags to improve the strength and durability of geopolymers Part 3 Applications of geopolymers: Commercialisation of geopolymers for construction: Opportunities and obstacles Geopolymers for nuclear waste immobilization Immobilization of toxic waste in geopolymers

585 citations