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Journal ArticleDOI

A comparison of grain nucleation and grain growth during crystallization of HWCVD and PECVD a-Si:H films

15 Jan 2008-Thin Solid Films (Elsevier)-Vol. 516, Iss: 5, pp 529-532
TL;DR: In this article, the authors compare the crystallization kinetics of HWCVD and PECVD a-Si:H films, containing different initial film hydrogen contents (CH), by annealing at 600 °C.
About: This article is published in Thin Solid Films.The article was published on 2008-01-15 and is currently open access. It has received 25 citations till now. The article focuses on the topics: Crystallization & Nucleation.

Summary (2 min read)

1. Introduction

  • The crystallization of as deposited a-Si:H thin films is becoming increasingly important because of its potential use to produce higher mobility polycrystalline materials for use in solar cells and high performance thin film transistors.
  • This process is believed, at relatively low anneal temperatures (b 1000 °C), to follow a classical model of nucleation and grain growth [1], where an amorphous incubation time, a steady state nucleation rate, grain growth of these nuclei, and a characteristic time of crystallization can be identified.
  • Further, recent results have shown that the crystallization time, for a given film CH, can depend upon the a-Si:H deposition method [4].

2. Experimental

  • H films were deposited by HWCVD and PECVD, using deposition conditions described previously [6,7], also known as A-Si.
  • Regarding the latter, the width of the XRD diffraction peaks may result from a combination of grain size, defect density, or strain effects.
  • This thickness was chosen because no sample thinning was required.
  • TEM analysis was performed on a CM200 Scanning TEM using a Phillips single-slit holder and a Gatan Model 652 double-slit heating holder for in-situ annealing.

3. Results and discussion

  • Fig. 1 shows TEM images of partially crystallized HWCVD and PECVD a-Si:H films annealed at 600 °C, with the annealing times indicated in the figures.
  • From this figure, clear differences are seen not only in the anneal time, but also in the grain density and grain morphology between the different films.
  • These differences become even more pronounced when a low CH HWCVD film is included in the comparison compared to the PECVD film seen in Fig. 1(b) [8,9]; in these comparisons, the PECVD film showed much lower grain densities and larger grains overall.
  • In Table 3 the authors first present a review of the NMR data, from which the densities of the isolated and clustered hydrogen distributions can be obtained.
  • H calculation, the authors use an averaged value of the clustered/isolated hydrogen ratio, obtained for ‘standard’ (low deposition rate) films deposited using 100% silane and a moderate (∼ 200–250 C) substrate temperature, also known as For the PECVD a-Si.

4. Summary and conclusions

  • The authors have presented the crystallization kinetics when HWCVD films of different film CH and ‘standard’ PECVD aSi:H films have been annealed at a temperature of 600 °C to induce film crystallization.
  • The authors find that the low CH HWCVD film nucleates first, and that the incubation time increases with increasing film CH.
  • Not surprisingly, the films which nucleate the fastest contain the smallest grains when crystallization is complete.
  • The increase in short range disorder upon film hydrogen evolution does not seem to play a primary role in the crystallization process.
  • A tentative model relating the crystallization kinetics to the initial hydrogen spatial distribution in the film is presented.

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Citations
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Book ChapterDOI
19 Sep 2012
TL;DR: In this paper, a variety of methods for lowering the crystallization temperature of polycrystalline silicon thin films have been developed, which can render larger grains compared to the conventional poly Si film deposition.
Abstract: Polycrystalline silicon thin films have attracted the attention of semiconductor industries in the past few decades due to their wide applications in thin film transistors, solar cells, display units and sensors (Schropp & Zeman, 1998; Choi et al., 2005; Mahan et al., 2008). Polycrystalline Si thin films are generally fabricated by crystallizing amorphous Si (a-Si) thin films, because these can render larger grains compared to the conventional poly Si film deposition. As a consequence, a variety of methods for lowering the crystallization temperature of a-Si have been developed. Excimer laser annealing is one of the promising ways to achieve large grain size poly Si films at lower substrate temperatures. Its high costs and nonuniform grain size, however, are significant obstacles that prevent its wide use (Parr et al., 2002). The other promising technique is the solid phase crystallization method. But this technique is essentially a high-temperature process and many substrates, including most forms of glass, cannot withstand the thermal processing. In order to achieve lower costs and have a wider range of application, inexpensive materials such as glass and special polymers have to substitute quartz or PyrexTM substrates. In the case of glass substrates, all of the processing steps need to be limited to temperatures below 550 °C. The other known technique is rapid thermal annealing (RTA). In RTA infrared radiation is used as a heating source, and has the advantage of the high heating speed (up to 60 oC/s) that reduces the crystallization time. In RTA radiation is applied in pulses to heat the sample without heating the glass substrate (which is transparent to the infrared radiation). However, the grain size obtained in the crystallization of a-Si is also in the range of a few micrometers.

16 citations

Journal ArticleDOI
TL;DR: In this paper, the metal-induced crystallization of amorphous Si (a-Si) films is investigated using transmission electron microscopy using Ni-Si nanocomposite.
Abstract: Nickel induced crystallization of amorphous Si (a-Si) films is investigated using transmission electron microscopy. Metal-induced crystallization was achieved on layered films deposited onto thermally oxidized Si(3 1 1) substrates by electron beam evaporation of a-Si (400 nm) over Ni (50 nm). The multi-layer stack was subjected to post-deposition annealing at 200 and 600 °C for 1 h after the deposition. Microstructural studies reveal the formation of nanosized grains separated by dendritic channels of 5 nm width and 400 nm length. Electron diffraction on selected points within these nanostructured regions shows the presence of face centered cubic NiSi 2 and diamond cubic structured Si. Z -contrast scanning transmission electron microscopy images reveal that the crystallization of Si occurs at the interface between the grains of NiSi 2 and a-Si. X-ray absorption fine structure spectroscopy analysis has been carried out to understand the nature of Ni in the Ni–Si nanocomposite film. The results of the present study indicate that the metal induced crystallization is due to the diffusion of Ni into the a-Si matrix, which then reacts to form nickel silicide at temperatures of the order of 600 °C leading to crystallization of a-Si at the silicide–silicon interface.

12 citations

Journal ArticleDOI
TL;DR: In this article, the authors report on the deposition of amorphous silicon (a-Si:H) films at ultra-high growth rate (11-60nm/s) by means of the expanding thermal plasma technique, followed by solid phase crystallization (SPC).
Abstract: In this paper, we report on the deposition of amorphous silicon (a-Si:H) films at ultra-high growth rate (11–60 nm/s) by means of the expanding thermal plasma technique, followed by solid-phase crystallization (SPC). Large-grain (∼1.5 μm) polycrystalline silicon was obtained after SPC of high growth rate (∼25 nm/s) deposited a-Si:H films. The obtained results are discussed by taking into account the impact of the a-Si:H microstructure parameter R* as well as of its morphology, on the final grain size development.

11 citations

Journal ArticleDOI
TL;DR: In this article, the impact of the amorphous silicon properties on the crystallization process is highlighted and discussed and the development of large grains extending through the thickness of the poly-Si layer is found to be promoted by an increase in the microstructure parameter, R* and the medium range order (MRO).
Abstract: The impact of the amorphous silicon properties, i.e., the microstructure parameter R* and the medium range order (MRO), on the crystallization process is highlighted and discussed. In agreement with literature, the development of large grains extending through the thickness of the poly-Si layer is found to be promoted by an increase in the amorphous silicon microstructure parameter, R*. Furthermore, while the role of the MRO in controlling the incubation time and, therefore, the onset in crystallization is generally acknowledged, it is also concluded that the presence of nano-sized voids plays an essential role in the crystallization kinetics.

10 citations

Journal ArticleDOI
TL;DR: In this article, the authors demonstrate the use of laser processing to affect the nucleation of crystallites in thermally annealed hydrogenated amorphous silicon (a-Si:H) thin films.
Abstract: We demonstrate the use of laser processing to affect the nucleation of crystallites in thermally annealed hydrogenated amorphous silicon (a-Si:H) thin films. The influence of film H content and subcrystallization threshold laser fluence are investigated by x-ray diffraction measurements during in situ thermal annealing at 600 °C. All laser-treated films show a reduced incubation time for crystallization compared to as-grown films, with the largest differences exhibited for samples with higher film H and higher laser fluences. These results are consistent with multivacancy annihilation by laser processing, based upon a recently developed model for a nucleation center in a-Si:H.

9 citations

References
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Journal ArticleDOI
TL;DR: In this paper, it was shown that hydrogenated amorphous silicon containing as little as 1/10 the bonded H observed in device-quality glow discharge films have been deposited by thermal decomposition of silane on a heated filament.
Abstract: Device‐quality hydrogenated amorphous silicon containing as little as 1/10 the bonded H observed in device‐quality glow discharge films have been deposited by thermal decomposition of silane on a heated filament. These low H content films show an Urbach edge width of 50 mV and a spin density of ∼1/100 as large as that of glow discharge films containing comparable amounts of H. High substrate temperatures, deposition in a high flux of atomic H, and lack of energetic particle bombardment are suggested as reasons for this behavior.

464 citations

Journal ArticleDOI
TL;DR: It is shown that the width of the ``optic peak'' increases roughly linearly with the rms bond-angle distortion of the network, consistent with model-building experience which shows that it is impossible to construct fully bonded amorphous networks with \ensuremath{\Delta}${\ensureMath{\theta}}_{b}$.
Abstract: The Raman scattering from various model structures for amorphous silicon is computed. It is shown that the width of the ``optic peak'' increases roughly linearly with the rms bond-angle distortion \ensuremath{\Delta}${\ensuremath{\theta}}_{b}$ of the network. The experimentally observed linewidths lead to 7.7\ifmmode^\circ\else\textdegree\fi{}\ensuremath{\le}\ensuremath{\Delta}${\ensuremath{\theta}}_{b}$\ensuremath{\le}10.5\ifmmode^\circ\else\textdegree\fi{}. The smaller linewidths (and hence angles) correspond to networks that have been annealed at higher temperatures. These results are consistent with model-building experience which shows that it is impossible to construct fully bonded amorphous networks with \ensuremath{\Delta}${\ensuremath{\theta}}_{b}$\ensuremath{\le}6.6\ifmmode^\circ\else\textdegree\fi{}.

392 citations

Journal ArticleDOI
TL;DR: In this paper, the morphological evolution of the amorphous towards the polycrystalline phase is investigated by transmission electron microscopy and it is interpreted in terms of a physical model containing few free parameters related to the thermodynamical properties of ammorphous silicon and to the kinetical mechanisms of crystal grain growth.
Abstract: The solid phase crystallization of chemical vapor deposited amorphous silicon films onto oxidized silicon wafers, induced either by thermal annealing or by ion beam irradiation at high substrate temperatures, has been extensively developed and it is reviewed here. We report and discuss a large variety of processing conditions. The structural and thermodynamical properties of the starting phase are emphasized. The morphological evolution of the amorphous towards the polycrystalline phase is investigated by transmission electron microscopy and it is interpreted in terms of a physical model containing few free parameters related to the thermodynamical properties of amorphous silicon and to the kinetical mechanisms of crystal grain growth. A direct extension of this model explains also the data concerning the ion-assisted crystal grain nucleation.

332 citations

Journal ArticleDOI
TL;DR: In this paper, a theoretical and experimental study of the recrystallization behavior of polycrystalline silicon films amorphized by self-implantation was carried out and the crystallization behavior was found to be similar to the crystallisation behavior of films deposited in the amorphous state, however, a transient time was observed, during which negligible crystallization occurs.
Abstract: This paper presents a theoretical and experimental study of the recrystallization behavior of polycrystalline silicon films amorphized by self‐implantation. The crystallization behavior was found to be similar to the crystallization behavior of films deposited in the amorphous state, as reported in the literature; however, a transient time was observed, during which negligible crystallization occurs. The films were prepared by low‐pressure chemical vapor deposition onto thermally oxidized silicon wafers and amorphized by implantation of silicon ions. The transient time, nucleation rate, and characteristic crystallization time were determined from the crystalline fraction and density of grains in partially recrystallized samples for anneal temperatures from 580 to 640 °C. The growth velocity was calculated from the nucleation rate and crystallization time and is lower than values in the literature for films deposited in the amorphous state. The final grain size, as calculated from the crystallization param...

329 citations

Journal ArticleDOI
TL;DR: Using the fact that multiple-quantum excitation is limited by the size of the dipolar-coupled spin system, it is shown that the predominant bonding environment for hydrogen is a cluster of four to seven atoms.
Abstract: Multiple-quantum nuclear-magnetic-resonance techniques are used to study the distribution of hydrogen in hydrogenated amorphous silicon. Using the fact that multiple-quantum excitation is limited by the size of the dipolar-coupled spin system, we show that the predominant bonding environment for hydrogen is a cluster of four to seven atoms. For device quality films, the concentration of these cluster defects increases with increasing hydrogen content. At very high hydrogen content, the clusters are replaced with a continuous network of silicon-hydrogen bonds.

174 citations

Frequently Asked Questions (1)
Q1. What contributions have the authors mentioned in the paper "A comparison of grain nucleation and grain growth during crystallization of hwcvd and pecvd a-si:h films" ?

Even though the bonded hydrogen evolves very early from the film during annealing, the authors suggest that the initial spatial distribution of hydrogen plays a critical role in the crystallization kinetics, and they propose a preliminary model to describe this process.