A field study of the exposure-annoyance relationship of military shooting noise.
Summary (4 min read)
Introduction
- Here the authors present a similar study to analyze the combined rotational and translation states of hydrogen molecules confined in a one-dimensional potential.
- In the present paper, the authors focus their attention on the general formalism and discuss only the case where a single H2 is confined inside a single nanotube.
- In Sec. VI the authors discuss the experimental observation of various transitions via inelastic neutron scattering measurements.
- The authors conclusions are summarized in Sec. VII.
II. POTENTIAL MODEL
- By this the authors mean that the potential produced by the nanotube has cylindrical symmetry and is invariant with respect to translations along its axis of symmetry.
- It is instructive to look at various potentials for an orientationally averaged hydrogen molecule ~i.e., parahydrogen with J50) when H2 is inside and outside a single nanotube.
- The solid and dashed lines in Fig. 2 show the results with and without the smooth tube approximation, respectively.
III. FORMULATION
- The hydrogen molecule is unique in that its moment of inertia is small enough that the rotational kinetic energy often dominates the orientational potential in which the molecule is placed.
- This function may be evaluated by integrating the potential at a fixed center-of-mass position over all orientations vL M~r !5eiMfrE dVY LM~u ,f!*V~r,V!. ~6!.
- It is important to keep in mind that vL M(r) vanishes for odd M.
- As a consequence, in the (2J11)-component wave function there is no mixing between even and odd values of M.
1. Harmonic potential
- Here the authors discuss the eigenvalues and eigenfunctions of the two-dimensional isotropic harmonic oscillator, to emphasize the relation between the above formulation in terms of cylindrical coordinates and that in terms of Cartesian coordinates.
- This degeneracy reflects the U2 symmetry corresponding to the invariance of the Hamiltonian with respect to a transformation of the form S ~ax†!8~ay†!8D 5@U#S ~ax†!~ay†!D , ~14!.
- This transformation is essentially the same as a four-dimensional rotational symmetry in the space of the momenta px , py , and coordinates x and y.
- Here the family of solutions for a given value of m are labeled a50,1,2, . . . , in order of increasing energy and for the isotropic and harmonic potential the authors have Em a5~m1112a!\v .
- A consequence of this symmetry is that for a harmonic potential the total energy depends only on the total number of phonon excitations.
2. Anharmonic potential
- The U2 symmetry is broken by anharmonic terms which then take us into the generic case of a particle in a circularly symmetric potential which is not harmonic.
- Accordingly, the authors now consider the effect of adding an anharmonic perturbation of the form gr4 to the harmonic potential.
- The authors results are characteristic of the generic case, for which different values of m give rise to distinct eigenvalues.
- The n-fold degenerate manifold which has energy n\v for the harmonic potential is split into doublets ~corresponding to the degeneracy between 1m and 2m) and, if n is odd, a singlet from m50.
- The authors explicit results are given in Table I.
B. Toy model of translation-rotation coupling
- In this section the authors explore the consequences of allowing coupling between rotations and translations.
- For larger tubes, the minimal potential energy occurs for a nonzero value of r and the molecule is dominantly off center.
C. Results of the toy model
- The authors now discuss the results of the toy model assuming that the number of phonons is a good quantum number.
- The authors note that all the energy expressions given below are with respect to BJ(J11) with J51.
1. Zero phonon manifold
- The authors first consider the manifold of the states having J51 with zero phonons.
- One has the singlet Jz50 state lower than the doublet Jz561 states by an energy separation of 3a .
- One may visualize this as the energy difference between a state for which the molecule is in the phonon ground state and is oriented parallel to the axis and the two states when the molecule is in the phonon ground state and is oriented transversely to the axis.
- For later use the authors tabulate these wave functions in Table II.
2. One-phonon manifold without rotation-translation coupling
- If the authors set b50 in the toy model of Eq. ~19!, then essentially they have independent oscillation of molecules which have fixed orientation.
- So that the lowest energy state ~if a.0) is doubly degenerate and the excited state is fourfold degenerate, as is shown in Fig.
3. One-phonon manifold with rotation-translation coupling
- The unphysical aspect of the energy level scheme the authors just found for the one-phonon manifold is that it does not take into account that the molecular orientation ought to be correlated with the translational motion.
- This means that the orientation of the molecule has to be correlated with the translational motion.
- In terms of number operators nx and ny which are the number of phonon excitations in the x and y directions, respectively, and ax † and ay † which are creation operators for aWe tabulate the energy relative to \v .the authors.
- This argument predicts that the six states form three doubly degenerate energy lev- els.
- In Fig. 4 the authors show the energy levels when no dynamical mixing between rotations and translations is allowed, i.e., for b50.
4. Two-Phonon manifold with rotation-translation coupling
- Actually, because the dependence on r of the matrix elements in Eq. ~19! was taken to be either constant or proportional to r2, the representation of Eq. ~22!.
- The removal of the degeneracy in the energy level scheme of the two-phonon ~i.e., nx1ny52) and (J51) manifold according to the Hamiltonian of Eq. ~22!.
- Is shown in Fig. using the WS77 potential are given in the last column of Table V.18.
- In this simple model the authors also include the anharmonic term gr4 which they treat within first order perturbation theory.
- The authors determine the best parameters for the toy model by making a least squares fit of the numerically determined energy levels to those of the toy model and these parameters as well as the results of this fit are given in Table.
5. Summary
- The authors can summarize the systematics of the rotationtranslation spectrum of the toy model they have introduced.
- The authors first consider the harmonic g50 case and then discuss the effect of introducing anharmonicity.
- Harmonic phonon states which transform as (x 1iy)N22k will uniquely combine with Jz50 states to form states for which P5(N22k) and which have energy (N 11)\v22a .
- Since the rotation translation coupling interaction proportional to xy(J1 2 2J2 2 ) has matrix elements between these two states, the eigenstates f16f2 will be split by an amount proportional to bs2 and this splitting will be modified by anharmonicity.
V. MEXICAN HAT POTENTIAL
- Here the authors discuss the case when the minimum of the potential V0(r) occurs for nonzero r as happens for H2 molecules inside 10310 tubes or for H2 molecule in a bound state outside any tube.
- It is possible to understand the quadratic behavior of energy levels versus the quantum number P based on a simple idealized model.
- The authors expect the radial wave functions to be Gaussians centered about r5r0.
OF THE ENERGY SPECTRUM
- Here the authors make some remarks concerning the observation of these modes via inelastic neutron scattering.
- Also the cJ ,P (a) (k ,m)’s are the set of coefficients ~for fixed J, P, and a) which are obtained by the numerical solution of the (2J11)-component radial eigenvalue problem on a set of mesh points $rk%.
A. Para to ortho conversion
- At low temperature the initial state ~whose energy is denoted Ei) will be the ground state for J50 and for a small value of P ~which the authors denote Pi).
- The authors now discuss the qualitative meaning of this result.
B. Ortho Cross Section
- Here the authors discuss the scattering from an ortho H2 molecule.
- The resolution at energies below around 10 meV could be about 0.5 meV ~which is used in Fig. 8! and therefore it may be possible to observe these transitions.
- Finally the authors note that the tangential phonon transitions below 10 meV show a maximum near 3.6 to 4 meV.
- The phase change when the neutron passes through a diamater of the Maxican hat is 2kr0, where r0 is the radius at which the Maxican hat potential is minimal.
VII. CONCLUSION
- The authors list the major conclusion from their study of H2 molecules bound to nanotubes which they treat as smooth cylinders.
- This formulation leads to classifying translation-rotation wave functions according to their properties under a global rotation of the molecule about the cylindrical axis.
- The quantum wave functions are easy to understand qualitatively.
- This simplification is a result of the mirror plane perpendicular to axis of the cylinder.
- The authors also suggest that neutron time-of-flight spectra could provide useful confirmation of their results.
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Citations
291 citations
Cites methods from "A field study of the exposure-annoy..."
...[45], however, showed closer associations between noise levels and annoyance expressed by means of the verbal 5-point scale, as compared to the numeric 11-point scale....
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Cites background from "A field study of the exposure-annoy..."
...This phenomenon for example has been previously observed in Switzerland with respect to shooting noise, where only a low correlation with actual exposure values was observed [3]....
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..., from a survey on aircraft noise annoyance (n = 2269) in Frankfurt [13] and from a study on military shooting noise annoyance (n = 1002) around training grounds of the Swiss army [14]....
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34 citations
Cites background from "A field study of the exposure-annoy..."
...In field studies, noise exposure has been found to account for between 4% and 20% of the variance in annoyance on the individual level (Brink and Wunderli, 2010; Fields, 1993; Job, 1988)....
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References
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...To roughly assess the degree of explained variance in the model building process, the pseudo-R2 statistic according to McKelvey and Zavoina 1975 was calculated....
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...In this case, the cutoff lies at 72.7% see Schultz, 1978 ....
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...Schultz 1978 already observed that the largest uncertainties in deriving his influential dose-effect curve were associated with the judgment as to which respondents are counted as highly annoyed....
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...There have been successful attempts to attain congruent curves in other studies e.g., Schreckenberg and Meis, 2006 by statistically raising the cutoff point of the five-point scale to 72% by weighting the response category “very” on the five-point scale as proposed by Miedema and Vos 1998 ....
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...The data also demonstrate that statistically aligning the cutoff points of both scales using the weighting method described by Miedema and Vos 1998 might not necessarily be a sound basis for comparing the two scales....
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...Within each household, one person over 16 years of age was selected using a modified Troldahl– Carter method Troldahl and Carter, 1964 ....
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Frequently Asked Questions (3)
Q2. What is the reason for the inclusion of this second predictor?
The inclusion of this second predictor is based on the idea that for large weapons with considerable low frequency content, the A-weighted level alone does not sufficiently account for the variation in annoyance.
Q3. What was the main block of questions used?
This main block of questions included the German version of the 11-point annoyance scale from 0 to 10 recommended by the International Commission on Biological Effects of Noise ICBEN that were published by Fields et al.