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Journal ArticleDOI

A mass spectrometer observation of NO in an auroral arc

01 Nov 1970-Journal of Geophysical Research (John Wiley & Sons, Ltd)-Vol. 75, Iss: 31, pp 6371-6376
About: This article is published in Journal of Geophysical Research.The article was published on 1970-11-01 and is currently open access. It has received 89 citations till now.

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SPACE RESEARCH COORDINATION CENTER
A MASS SPECTROMETER OBSERVATION
OF
NO
IN
AN AURORAL ARC
BY
E.
C.
ZIPF,
W.
L.
BORST AND T.
M.
DONAHUE
DEPARTMENT
OF
PHYSICS
SRCC REPORT NO.
133
UNIVERSITY
OF
PITTSBURGH
PITTSBURGH. PENNSYLVANIA
27
JULY 1970


A
MASS
SPECTROM%TER
OBSERYATIOM
OF
NO
IN
Al!I
AURORAL
ARC
E.
C.
Zipf,
W.
Lo
Boret and
T.
M.
Donshue
Department
of
Physics
University
of
Pittsburgh, Pittsburgh, Pennsylvanis
15213
July
1970

On
25
March 1970 an Aerobee rocket r4.309
DA]
was
launched
+
into
a
bright
IBC
I1
The instrumentation on board included
a
quadrupole
mass
spectrometer
that
measured
the
local ion &neutral composition in the auroral
form,
separate primary and seconda,ry electron energy analyzers covering
the
nominal energy ranges
1
to
30
keV and
1
to
1000
eV respectively,
auroral arc above Fort
Churchill, Manitoba.
a
cylindrical electron probe and
a
planar total positive ion probe.
These particle experiments
were
complemented by
a
l/h-rneter
Bert
monochromator
that
scanned the
VW
auroral spectrum from
1150A
to
1500A
and four
filtered
photometers
that
measured the overhead intensity
of
the
(0,O)
first
negative band
of
B2
,
the
(1,O)
first
negative band
of
O2
,
the
(5,2)
first
positive band of
B
line
[IS
+
'D;
XSS77A1.
Fastie, 1969)
was
included to obtain information on the temporal and
structural characteristics
of
the
aurora.
+
+
and
the
auroral oxygen green
2
In addition,
an
up-down photometer (Dick and
In this paper we discuss the neutral and ion
data
obtained by
our
programmable
mass
spectrometer.
The
most important results are the
following:
of
NO
and
NO
within
the
auroral form. The molecular ions
O2
and
B2
were
conspicuously absent and comparatively large densities
of
0
were detected.
concentration exceeded the
ambient
0
concentration.
The
mass
spectrometer observed remarkably
large
concentrations
9
+
+
+
ions
In the altitude range
110
km
to
130
km
the neutral
NO
2
In previous years we have
flown
similar comprehensively instrumented
rockets into
IBC
I
and
I1
post breakup
aurpra
(Donahue et
ale,
1968;

Parkfnson
et
al,,
1970a;
Donahue et
ale,
1970; Parkinson et
al.,
1970b).
In
these displays the primary ionization and luminosity often
was
observed over
a
relatively wide altitude region
(100
-
135
km),
the prfmary electron spectrum
was
comparatively soft
(.
10
keV
electrons),
and the maximum electron density observe4 in the aurora
was
modest
(-
2
x
lo5
e/cm3). The aurora encountered on Aerobee flight
4.309
UA
was
by coqtrast
a
stable arc characterized by large fluxes of
20
-
30
.keV
primary electrons (Doering, 1970), by large local electron densities
(-
lo6
e/cm3)
and by an energy deposition confined for
the
most part
to
a
relatively narrow altitude region
(95
-
115
km).
in
Ffgure
1
where
we
show the intensity
of
the
(O,O)
first
negative band
of
N2
measured
on
the
upleg
of
the flight;
similar
results
were
obtained
for the
cl,O)
first nagative band
of
0
measurements
of
the excitation cross sections for these bands (Borst
and Zipf 1970a, 1970b), the total ionization cross sections for
N2,
O2
and
0
(Kieffer and
Dum,
1966),
and our in situ opticalmeasurements,
we
estimate that the
maximum
ionization
rate
in this arc
was
approximately
2
x
105
ion pairs/cm3sec
at
102
kmo
This
is
illustrated
f
+
Using
recent laboratory
2O
In an earlier auroral experiment
(4,217
UA;
Donahue
et
ale,
1970)
++
we
observed an unusually large
NO
/O
spectrometer.
(1968)
breakup aurora,
we
supposed that
NO
ratio
with
a
single mode ion
mass
2
Similar results have been obtained by Swider
et
al.,
In
order to explain this observation, which
was
made in
a
post-
+
ions were produced by rapid charge
transfer
2

Citations
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Journal ArticleDOI
TL;DR: In this paper, the coupled momentum and continuity equations for NO(+), O2(+) and O(+) ions in the E- and F-regions of the ionosphere were solved.

249 citations

Journal ArticleDOI
TL;DR: In this paper, a two-dimensional photochemical model which treated the troposphere and stratosphere has been extended to include the mesosphere and lower thermosphere, and particular emphasis is placed on the transport and chemistry of nitric oxide.
Abstract: A two-dimensional photochemical model which treated the troposphere and stratosphere has been extended to include the mesosphere and lower thermosphere. The model is described, and particular emphasis is placed on the transport and chemistry of nitric oxide. Large amounts of NO are produced in the lower thermosphere both by solar radiation during quiet times and through auroral ionization. Using reasonable descriptions of dynamical processes in the two-dimensional model, substantial amounts of NO produced in the thermosphere can reach the stratosphere, particularly at high latitudes during polar winter. This process provides a coupling between the upper and lower atmosphere which may play a significant role in the photochemistry of odd nitrogen and odd oxygen in the stratosphere.

239 citations

Journal ArticleDOI
TL;DR: In this article, the impact of particle precipitation on the chemical composition of the atmosphere has been studied, and there are a number of observations as well as model studies concerning especially the auroral impact and large solar particle events.
Abstract: Precipitation of energetic particles into the atmosphere greatly disturbs the chemical composition from the upper stratosphere to the lower thermosphere. Most important are changes to the budget of atmospheric nitric oxides (NOx = N, NO, NO2) and to atmospheric reactive hydrogen oxides (HOx = H, OH, HO2), which both contribute to ozone loss in the stratosphere and mesosphere. The impact of energetic particle precipitation on the chemical composition of the atmosphere has been studied since the 1960s, and there are a number of observations as well as model studies concerning especially the auroral impact and large solar particle events. Changes to the NOx budget due to energetic particle precipitation can be quite long-lived during polar winter and can then be transported down into the lower mesosphere and stratosphere, where NOx is one of the main participants in catalytic ozone destruction. Energetic particle precipitation can also affect temperatures and dynamics of the atmosphere from the source region down to the stratosphere and possibly even down to the surface, due to a coupling of chemical composition changes affecting atmospheric heating and cooling rates, the mean circulation, and wave propagation and breaking. Thus, energetic particle precipitation impacts have been implemented in chemistry-climate models reaching from the surface up to the mesosphere or lower thermosphere. However, there are still a number of open questions in the theoretical description of the energetic particle precipitation impact; the most important are uncertainties in the formation rate of different NOx species due to energetic particle precipitation, and the complex coupling between chemical changes, atmospheric heating and cooling rates, and atmospheric dynamics.

213 citations


Cites background from "A mass spectrometer observation of ..."

  • ...High values of NO have been observed directly within the aurora (Zipf et al. 1970) or during or shortly after high geomagnetic activity or particle precipitation events at high latitudes (Gerard and Barth 1977; Iwagami and Ogawa 1980; Grossmann et al. 1985; Crowley et al. 1998), and a correlation…...

    [...]

Journal ArticleDOI
TL;DR: In this article, a self-consistent, time-dependent numerical model of the aurora and high-latitude ionosphere has been developed to study the response of ionospheric and atmospheric properties in regions subjected to electron bombardment.

163 citations

References
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TL;DR: In this article, a compilation and critical evaluation of absolute cross-sections for ionization of atoms and diatomic molecules by electron impact is presented, along with a brief discussion of relative cross-section data near threshold.
Abstract: This review includes a compilation and critical evaluation of absolute cross sections for ionization of atoms and diatomic molecules by electron impact. Experimental techniques used for ionization are surveyed. Selected relative cross sections for production of multiply charged ions and a brief discussion of relative cross-section data near threshold are presented. Absolute limits are not set on the size of probable systematic errors in the various experiments.

576 citations

Journal ArticleDOI
TL;DR: In this paper, the first negative band of nitrogen ion from threshold to 3 keV was measured using photon counting techniques. But the authors did not consider the negative band in this work.
Abstract: Electron impact excitation cross section of /0,0/ first negative band of nitrogen ion from threshold to 3 keV, using photon counting techniques

187 citations

Journal ArticleDOI
TL;DR: Lower thermosphere composition over New Mexico, discussing rocket flight mass spectrometer measurements during summer 1967 as mentioned in this paper, discussing the performance of the first rocket flight in the United States.
Abstract: Lower thermosphere composition over New Mexico, discussing rocket flight mass spectrometer measurements during summer 1967

82 citations

Journal ArticleDOI
TL;DR: Auroral ion composition and chemistry from rocket-borne mass spectrometer measurements, investigating oxygen density and green line excitation was described in this paper. But the results were limited to a single image.

79 citations

Journal ArticleDOI
TL;DR: In this article, the authors considered the relationship between electron impact excitation cross sections of oxygen ion first negative bands, considering relationship to oxygen ionization cross section, and showed that the cross section of the first negative band is positively associated with the second negative band.
Abstract: Electron impact excitation cross sections of oxygen ion first negative bands, considering relationship to oxygen ionization cross section

12 citations