Journal ArticleDOI
A Microporous Hydrogen-Bonded Organic Framework: Exceptional Stability and Highly Selective Adsorption of Gas and Liquid
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TLDR
An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated and exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorptive at ambient temperature.Abstract:
An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temperature.read more
Citations
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Journal ArticleDOI
Multifunctional porous hydrogen-bonded organic framework materials.
TL;DR: The bright potential of HOF materials as multifunctional materials is highlighted in some of the most important applications for gas storage and separation, molecular recognition, electric and optical materials, chemical sensing, catalysis, and biomedicine.
Journal ArticleDOI
Porous organic cages: soluble, modular and molecular pores
Tom Hasell,Andrew I. Cooper +1 more
TL;DR: Porosity is a rare property for molecular materials but, surprisingly, porous solids built from discrete organic cage molecules have emerged as a versatile functional-materials platform as mentioned in this paper, and the surface areas of molecular organic cage solids now rival those of metal-organic frameworks.
Modular and predictable assembly of porous organic molecular crystals
Andrew I. Cooper,Graeme M. Day,Jta Jones,Xiao-Feng Wu,Tom Hasell,John Bacsa,Kim E. Jelfs,M Scmidtmann,Sy Chong,Abbie Trewin,F Schiffman,Furio Corà,Ben Slater,Alexander Steiner +13 more
TL;DR: In this article, the authors show that highly porous crystalline solids can be produced by mixing different organic cage modules that self-assemble by means of chiral recognition, and the structures of the resulting materials can be predicted computationally, allowing in silico materials design strategies.
Journal ArticleDOI
Designing Hydrogen‐Bonded Organic Frameworks (HOFs) with Permanent Porosity
TL;DR: H-bonding patterns and molecular structures that have been used to achieve thermal and chemical durability, a large surface area, and functions, such as selective gas sorption and separation, can provide design principles for constructing HOFs with permanent porosity.
Journal ArticleDOI
A Flexible Microporous Hydrogen-Bonded Organic Framework for Gas Sorption and Separation
TL;DR: Powder neutron diffraction studies and theoretical calculations reveal that suitable pore sizes, curvatures, and functional sites collectively enable HOF-5a to encapsulate a high density of carbon dioxide molecules packed in a pseudo-one-dimensional array along the pore channel.
References
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Journal ArticleDOI
Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores
Dongyuan Zhao,Jianglin Feng,Qisheng Huo,Nicholas A. Melosh,Glenn H. Fredrickson,Bradley F. Chmelka,Galen D. Stucky +6 more
TL;DR: Use of amphiphilic triblock copolymers to direct the organization of polymerizing silica species has resulted in the preparation of well-ordered hexagonal mesoporous silica structures (SBA-15) with uniform pore sizes up to approximately 300 angstroms.
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Metal–Organic Framework Materials as Chemical Sensors
Lauren E. Kreno,Kirsty Leong,Omar K. Farha,Mark D. Allendorf,Richard P. Van Duyne,Joseph T. Hupp +5 more
TL;DR: The potential to computationally predict, with good accuracy, affinities of guests for host frameworks points to the prospect of routinely predesigning frameworks to deliver desired properties.
Journal ArticleDOI
Introduction to Metal–Organic Frameworks
Journal ArticleDOI
Metal–Organic Frameworks for Separations
Journal ArticleDOI
Carbon Dioxide Capture in Metal–Organic Frameworks
Kenji Sumida,David L. Rogow,Jarad A. Mason,Thomas M. McDonald,Eric D. Bloch,Zoey R. Herm,Tae-Hyun Bae,Jeffrey R. Long +7 more
TL;DR: Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long
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