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Journal ArticleDOI

A nanofiltration-coagulation integrated system for separation and stabilization of arsenic from groundwater.

TL;DR: A membrane-integrated hybrid treatment system has been developed for continuous removal of arsenic from contaminated groundwater with simultaneous stabilization of arsenic rejects for safe disposal, resulting in a total and sustainable solution to the problem of arsenic contamination of groundwater.
About: This article is published in Science of The Total Environment.The article was published on 2014-04-01. It has received 76 citations till now. The article focuses on the topics: Arsenic contamination of groundwater & Arsenic.
Citations
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Journal ArticleDOI
TL;DR: Nanofiltration (NF) membranes have come a long way since it was first introduced during the late 80's as mentioned in this paper, and significant development has taken place in terms of the fundamental understanding of the transport mechanism in NF membranes, which has been translated into predictive modeling based on the modified extended Nernst-Planck equation.

1,374 citations

Journal ArticleDOI
TL;DR: An overview of As and Sb chemistry, distribution and toxicity, which are relevant aspects to understand and develop remediation techniques are presented, and several alternative sorbents have been presenting promising results.

492 citations


Cites background from "A nanofiltration-coagulation integr..."

  • ...A new nanofiltrationecoagulation integrated system was recently proposed for arsenic removal from groundwater (Pal et al., 2014)....

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Journal ArticleDOI
TL;DR: In this paper, a review of the performance of chemical coagulation process in removing heavy metal from water is presented. And the main mechanisms of the removal of heavy metals are adsorption, complexation, and coprecipitation.
Abstract: Heavy metal pollution has become one of the most urgent environmental issues, which also poses a potential threat to the human health. This article is suggested to review the advance on the performance of chemical coagulation process in removing heavy metal from water. Chemical coagulation process is considered to be a valid method which is determined by the hydrolyzed species of the inorganic coagulants under different raw water and coagulation conditions. And the main mechanisms of the removal of heavy metals are adsorption, complexation, and coprecipitation. Compared with the aluminum-based coagulants, the iron-based coagulants have better performance due to the use of wide pH range and large surface area of the resulting flocs. During the chemical coagulation process, the valence state of arsenic and antimony could affect the removal efficiency. Thus, the oxidants and reductants are often combined with inorganic coagulants used in this process. It is found that pH is an important factor greatl...

155 citations

Journal ArticleDOI
TL;DR: This review presents an overview of nanoparticles and nanobased adsorbents and its efficiencies in arsenic removal from water and highlights the application of nanomaterials and their properties, mechanisms, and advantages over conventional adsorbent for arsenic Removal from contaminated water.
Abstract: Contamination of natural waters with arsenic, which is both toxic and carcinogenic, is widespread. Among various technologies that have been employed for arsenic removal from water, such as coagulation, filtration, membrane separation, ion exchange, etc., adsorption offers many advantages including simple and stable operation, easy handling of waste, absence of added reagents, compact facilities, and generally lower operation cost, but the need for technological innovation for water purification is gaining attention worldwide. Nanotechnology is considered to play a crucial role in providing clean and affordable water to meet human demands. This review presents an overview of nanoparticles and nanobased adsorbents and its efficiencies in arsenic removal from water. The paper highlights the application of nanomaterials and their properties, mechanisms, and advantages over conventional adsorbents for arsenic removal from contaminated water.

145 citations


Cites background from "A nanofiltration-coagulation integr..."

  • ...2013), membrane separation (Ning 2002; Shih 2005; Pal et al. 2014), ion exchange (Flicklin 1983; Katsoyiannis and Zouboulis 2002; Tresintsi et al....

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  • ...…(Khan et al. 2002; Wickramasinghe et al. 2004; Bilici Baskan and Pala 2010; Mólgora et al. 2013), membrane separation (Ning 2002; Shih 2005; Pal et al. 2014), ion exchange (Flicklin 1983; Katsoyiannis and Zouboulis 2002; Tresintsi et al. 2014), and adsorption (Lin and Wu 2001; Zeng 2003;…...

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Journal ArticleDOI
TL;DR: The work shows clearly that many EIs can be eliminated or minimized by incorporating specific design criteria and process improvements, and shows that the feedwater source has shown to have a great effect on EIs.

108 citations

References
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Journal ArticleDOI
TL;DR: The agreement among the models and experimental data indicated that the adsorption and diffusion of arsenate and arsenite can be simulated by the proposed model.

534 citations


"A nanofiltration-coagulation integr..." refers background or methods in this paper

  • ...A variety of treatment options have been documented by the researchers world-wide for removal of arsenic from the contaminated groundwater and these include chemical coagulation–precipitation, adsorption, ion exchange, membrane filtration, membrane distillation, photo-catalytic oxidation and ultrafiltration (Lin and Wu, 2001; Zouboulis and Katsoyiannis, 2002; Gholami et al., 2006; Pal et al., 2007; Hsieh et al., 2008; Nguyen et al., 2008; Pal and Manna, 2010)....

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  • ...…coagulation–precipitation, adsorption, ion exchange, membrane filtration, membrane distillation, photo-catalytic oxidation and ultrafiltration (Lin and Wu, 2001; Zouboulis and Katsoyiannis, 2002; Gholami et al., 2006; Pal et al., 2007; Hsieh et al., 2008; Nguyen et al., 2008; Pal and Manna,…...

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Journal ArticleDOI
TL;DR: Application of Fe(II) instead of the usually applied Fe(III) is shown to be advantageous, as oxidation of Fe (II) by dissolved oxygen causes partial oxidation of As (III) and iron( III) (hydr)oxides formed from Fe( II) have higher sorption capacities.
Abstract: Arsenic removal by passive treatment, in which naturally present Fe(II) is oxidized by aeration and the forming iron(III) (hydr)oxides precipitate with adsorbed arsenic, is the simplest conceivable water treatment option. However, competing anions and low iron concentrations often require additional iron. Application of Fe(II) instead of the usually applied Fe(III) is shown to be advantageous, as oxidation of Fe(II) by dissolved oxygen causes partial oxidation of As(III) and iron(III) (hydr)oxides formed from Fe(II) have higher sorption capacities. In simulated groundwater (8.2 mM HCO3-, 2.5 mM Ca2+, 1.6 mM Mg2+, 30 mg/L Si, 3 mg/L P, 500 ppb As(III), or As(V), pH 7.0 ± 0.1), addition of Fe(II) clearly leads to better As removal than Fe(III). Multiple additions of Fe(II) further improved the removal of As(III). A competitive coprecipitation model that considers As(III) oxidation explains the observed results and allows the estimation of arsenic removal under different conditions. Lowering 500 μg/L As(III)...

480 citations


"A nanofiltration-coagulation integr..." refers background in this paper

  • ...Quite a few studies on such coagulation–precipitation involving salts of iron, aluminum and calcium have been reported in the literature (Camacho et al., 2000; Roberts et al., 2004; Song et al., 2006; Baskan and Pala, 2009, 2010; Sullivan and Tyrer, 2010;Wang et al., 2011; Randall, 2012)....

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Journal ArticleDOI
TL;DR: In this paper, a double pass module design with recirculation of the concentrate in the second module to the feed of the first module was used to remove four pesticides (atrazine, simazine, diuron and isoproturon), hardness and nitrates with the membranes NF70, NF45, UTC-20 and UTC-60.

259 citations

Journal ArticleDOI
TL;DR: It has been found that the mechanism by which coarse calcite enhanced the coagulation of high-arsenic water might be due to attractive electrical double layer interaction between small arsenic-borne coagulates and calcite particles, which leads to non-existence of a potential energy barrier between the heterogeneous particles.

251 citations


"A nanofiltration-coagulation integr..." refers background in this paper

  • ...Arsenic ions precipitate with the ferric ions on the coagulants and thus increase the concentration of the coagulates (Song et al., 2006) as described below:...

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  • ...Quite a few studies on such coagulation–precipitation involving salts of iron, aluminum and calcium have been reported in the literature (Camacho et al., 2000; Roberts et al., 2004; Song et al., 2006; Baskan and Pala, 2009, 2010; Sullivan and Tyrer, 2010;Wang et al., 2011; Randall, 2012)....

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  • ...Arsenic ions precipitate with the ferric ions on the coagulants and thus increase the concentration of the coagulates (Song et al., 2006) as described below: Fe3+ + H3AsO4 → FeAsO4 (solid precipitate)....

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Journal ArticleDOI
TL;DR: The results of the bench-scale experiments conducted indicate that coagulation with ferric ions followed by filtration is effective in reducing arsenic concentration in the water tested.

224 citations