Journal ArticleDOI
A new type of pyridine-2-thionato bridge: X-ray crystal structure of the complex [Re2(MepyS)2(CO)6] where MepyS is the 6-methylpyridine-2-thionato ligand
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TLDR
In this article, the dinuclear cluster [Re2(pyS)2(CO)6] contains three fused four-membered rings, which can be easily cleaved by ligand addition and in redistribution reactions with Re2(MepyS) 2(CO), the 6-methyl-substituted derivative for which the X-ray structure is reported.About:
This article is published in Polyhedron.The article was published on 1988-01-01. It has received 61 citations till now.read more
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Complexes of heterocyclic thionates Part 2: complexes of bridging ligands
TL;DR: The bridging behavior of deprotonated heterocyclic thiones is described in this paper, where anions are effective bridging ligands among binuclear, trinuclear, tetranuclear hexanuclear and polynuclear metallic species.
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Copper complexes of heterocyclic thioamides and related ligands
TL;DR: In this paper, a detailed discussion of the structural aspects of these species based upon X-ray data is presented. But emphasis is placed on detailed discussion on the structural properties of the species.
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Common and less-common coordination modes of the typical chelating and heteroaromatic ligands
TL;DR: In this article, different modes of bonding the metals to the most widely spread chelating [β-diketones, o-oxyazomethines, o -oxy(mercapto) derivatives of azoles and azines] and heteroaromatic ligands are generalized and systematized.
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The X-ray crystal structures of the cadmium complexes of pyridine-1-thiol and mercaptobenzothiazole, [cd(C5H4NS)2]n And [Cd(C7H4N2S2)2]n: Two unusual volatile polymeric complexes
TL;DR: In this paper, the 2:1 complexes formed by pyridine-1-thiol and mercaptobenzothiazole with cadmium(II) are polymeric but both sublime at reduced pressure and decompose cleanly to CdS in air.
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Competitive coordination : ambident ligands in the modern chemistry of metal complexes
Alexander D. Garnovskii,Dimitri A. Garnovskii,Igor S. Vasilchenko,Anatolii S. Burlov,Alexander P. Sadimenko,Igor D. Sadekov +5 more
TL;DR: In this paper, the competitive binding of metals in complexes of bi-and poly-dentate ligand systems was surveyed and treated systematically, focusing on nontraditional ways in which typical ligand system are coordinated and on regioselective synthesis as a method for the specific synthesis of metal complexes with a specified location of the coordinate bond.