Journal ArticleDOI
A novel two-dimensional nickel phthalocyanine-based metal–organic framework for highly efficient water oxidation catalysis
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TLDR
In this article, a noble metal-free nickel phthalocyanine-based 2D MOF (NiPc-MOF) was synthesized for water oxidation.Abstract:
Large π-conjugated conductive two-dimensional (2D) metal–organic frameworks (MOFs) via the bottom-up approach have recently emerged as novel and interesting 2D materials. For the first time, herein we demonstrate the design and successful bottom-up fabrication of a novel noble-metal-free nickel phthalocyanine-based 2D MOF (NiPc–MOF) for highly efficient water oxidation catalysis. This NiPc–MOF can be easily grown on various substrates. The thin film deposited on FTO showed high catalytic oxygen evolution reaction (OER) activity with a very low onset potential (<1.48 V, overpotential < 0.25 V), high mass activity (883.3 A g−1), and excellent catalytic durability. To the best of our knowledge, this present 2D MOF film catalyst represents the best OER catalytic activity among molecular catalyst-based materials reported so far. This work represents the first synthesis of a nickel phthalocyanine-based 2D MOF material and application of the π-conjugated 2D MOF for water oxidation.read more
Citations
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Metal–Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives
TL;DR: In this review, the recent advances in the application of MOFs in heterogeneous catalysis are discussed and the personal view on future research directions is wrapped up.
Journal ArticleDOI
Electrically Conductive Metal-Organic Frameworks.
TL;DR: This Review discusses the efforts undertaken so far to achieve efficient charge transport in MOFs and focuses on four common strategies that have been harnessed toward high conductivities.
Journal ArticleDOI
Metal-organic frameworks for direct electrochemical applications
TL;DR: In this article, the morphological and electrochemical properties of these promising metal-organic framework materials for their future development are discussed, and based on the reported literature, they propose the future direction of metalorganic frameworks and metalorganic framework composites in the field of electrochemistry.
Journal ArticleDOI
Conductive two-dimensional metal-organic frameworks as multifunctional materials.
TL;DR: The progress in the development of 2D conductive MOFs with emphasis on synthetic modularity, device integration strategies, and multifunctional properties is summarized.
Journal ArticleDOI
Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications.
TL;DR: In this article, the authors provide an overview of different aspects of 2D MOF layered architectures such as topology, interpenetration, structural transformations, properties, and applications.
References
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The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
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TL;DR: Graphene has high mobility and optical transparency, in addition to flexibility, robustness and environmental stability as discussed by the authors, and its true potential lies in photonics and optoelectronics, where the combination of its unique optical and electronic properties can be fully exploited, even in the absence of a bandgap, and the linear dispersion of the Dirac electrons enables ultrawideband tunability.
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