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A review of biochar as a low-cost adsorbent for aqueous heavy metal removal

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TLDR
In this article, a review incorporating existing literature to understand the overall sorption behavior of heavy metals on biochar adsorbents is presented, and mathematical models are used to evaluate the efficiency of biochar at removing heavy metals.
Abstract
As a low-cost adsorbent, biochar can be used as a low-cost adsorbent for wastewater treatment, particularly with respect to treating heavy metals in wastewater. A number of studies have demonstrated effective removal of heavy metals from aqueous solutions by biochar and, in some cases, proven the superiority of biochars to activated carbons. Among several factors affecting the sorption ability of biochars, feedstock materials play a significant role. This review incorporates existing literature to understand the overall sorption behavior of heavy metals on biochar adsorbents. Depending on the biochar type, heavy metal can be removed by different mechanisms such as complexation, physical sorption, precipitation and electrostatic interactions. Mathematical sorption models can be used to understand the efficiency of biochar at removing heavy metals, and promote the application of biochar technology in water treatment.

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Journal ArticleDOI

Pharmaceuticals of Emerging Concern in Aquatic Systems: Chemistry, Occurrence, Effects, and Removal Methods.

TL;DR: Adsorption technologies are a low-cost alternative, easily used in developing countries where there is a dearth of advanced technologies, skilled personnel, and available capital, and adsorption appears to be the most broadly feasible pharmaceutical removal method.
Journal ArticleDOI

Mechanisms of metal sorption by biochars: Biochar characteristics and modifications

TL;DR: This review summarizes the characteristics of biochar (e.g., surface area, porosity, pH, surface charge, functional groups, and mineral components) and main mechanisms governing sorption of As, Cr, Cd, Pb, and Hg by biochar and includes competitive sorption mechanisms of co-existing metals.
Journal ArticleDOI

Preparation, modification and environmental application of biochar: A review

TL;DR: In this paper, a review of the preparation, characterization, modification, and especially environmental application of biochar, based on more than 200 papers published in recent 10 year, to provide an overview of Biochar with a particular on its environmental application.
Journal ArticleDOI

Catalytic removal of aqueous contaminants on N-doped graphitic biochars: inherent roles of adsorption and nonradical mechanisms.

TL;DR: This study not only provides robust and cheap carbonaceous materials for environmental remediation but also enables the first insight into the graphitic biochar-based nonradical catalysis.
Journal ArticleDOI

Surface functional groups of carbon-based adsorbents and their roles in the removal of heavy metals from aqueous solutions: A critical review.

TL;DR: This work provides a comprehensive review of recent research on various carbon adsorbents in terms of their surface functional groups and the associated removal behaviors and performances to heavy metals in aqueous solutions.
References
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Journal ArticleDOI

Insights into the modeling of adsorption isotherm systems

TL;DR: In this paper, the authors present a review of the state-of-the-art in isotherm modeling, its fundamental characteristics and mathematical derivations, as well as the key advance of the error functions, its utilization principles together with the comparisons of linearized and nonlinearized isotherms models have been highlighted and discussed.
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Review of second-order models for adsorption systems.

TL;DR: An overview of second-order kinetic expressions is described in this paper based on the solid adsorption capacity, which shows that a pseudo-second-order rate expression has been widely applied to the Adsorption of pollutants from aqueous solutions onto adsorbents.
Journal ArticleDOI

Arsenic removal from water/wastewater using adsorbents—A critical review

TL;DR: Strong acids and bases seem to be the best desorbing agents to produce arsenic concentrates, and some commercial adsorbents which include resins, gels, silica, treated silica tested for arsenic removal come out to be superior.
Journal ArticleDOI

A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents

TL;DR: In this paper, a comparison of kinetic models describing the sorption of pollutants has been reviewed, and the rate models evaluated include the Elovich equation, the pseudo-first order equation and the pseudo second order equation.
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