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A review of surfactants as corrosion inhibitors and associated modeling

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TLDR
A review of surfactants as corrosion inhibitors is designed to provide systemic evaluation of various physical and chemical properties, surfactant behaviors in corrosive environments, and their influence in corrosion inhibition.
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This article is published in Progress in Materials Science.The article was published on 2017-10-01. It has received 232 citations till now. The article focuses on the topics: Corrosion.

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Anticatalytic Strategies to Suppress Water Electrolysis in Aqueous Batteries.

TL;DR: In this article, the authors provide an in-depth review on the mechanisms of water electrolysis on electrodes, where they summarize the critical influencing factors applicable for a broad spectrum of aqueous battery systems.
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Synergistic effect of mixing cationic and nonionic surfactants on corrosion inhibition of mild steel in HCl: Experimental and theoretical investigations.

TL;DR: It was found that the mixtures adsorb on the steel by an endothermic spontaneous process, and the adsorption model follows Langmuir isotherm, so the synergistic inhibition effect of organic inhibitors and their energetic position of molecular frontier orbitals was discussed.
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Novel surfactants as green corrosion inhibitors for mild steel in 15% HCl: Experimental and theoretical studies

TL;DR: In this paper, two novel surfactants were synthesized and investigated as green corrosion inhibitor for mild steel in 15% HCl solution in various ways including weight loss, electrochemical measurements, scanning kelvin probe (SKP), scanning electron microscope (SEM) and theoretical calculations.
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Rational design of metallic anti-corrosion coatings based on zinc gluconate@ZIF-8

TL;DR: In this paper, a strategy based on encapsulating corrosion inhibitors into metal-organic frameworks (MOFs) matrix has been developed, and their corrosion process and mechanism have been fully studied. But the studies regarding loading inhibitors into MOFs for metallic anti-corrosion applications are scarcely reported.
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Some alginates polymeric cationic surfactants; surface study and their evaluation as biocide and corrosion inhibitors

TL;DR: In this article, three cationic polymeric surfactants were synthesized by alkylation of prepared alginate ester to obtain on three polymers with different alkyl chain (octyl, dodecyl and hexadecyl), and they are labeled (ALGOB, ALGDB and ALGHB), respectively.
References
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Book

Intermolecular and surface forces

TL;DR: The forces between atoms and molecules are discussed in detail in this article, including the van der Waals forces between surfaces, and the forces between particles and surfaces, as well as their interactions with other forces.
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Universal solvation model based on solute electron density and on a continuum model of the solvent defined by the bulk dielectric constant and atomic surface tensions.

TL;DR: The SMD model may be employed with other algorithms for solving the nonhomogeneous Poisson equation for continuum solvation calculations in which the solute is represented by its electron density in real space, including, for example, the conductor-like screening algorithm.
Book

Physical chemistry of surfaces

TL;DR: In this paper, the authors discuss the nature and properties of liquid interfaces, including the formation of a new phase, nucleation and crystal growth, and the contact angle of surfaces of solids.
Journal ArticleDOI

Formation and Structure of Self-Assembled Monolayers.

Abraham Ulman
- 20 Jun 1996 - 
TL;DR: Monolayers of alkanethiolates on gold are probably the most studied SAMs to date and offer the needed design flexibility, both at the individual molecular and at the material levels, and offer a vehicle for investigation of specific interactions at interfaces, and of the effect of increasing molecular complexity on the structure and stability of two-dimensional assemblies.
Book

Surfactants and Interfacial Phenomena

TL;DR: In this paper, the Gibbs equation is used to calculate the area per Molecule at the interface by using the Gibbs Equation (GEE) of the Gibbs equilibrium. But the Gibbs equations are not applicable to surface-active agents.
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