Journal ArticleDOI
A Stereospecific Approach to cis-anti-cis Triquinanes
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TLDR
A methodology for the synthesis of compounds containing the cis-anti-cis fused triquinane system has been developed starting from tricyclo[5.2.1]deca-4,8-dien-3-(exo)ol 6 involving Ireland ester Claisen rearrangement and intramolecular diazo ketone cyclopropanation reactions as key steps as mentioned in this paper.About:
This article is published in Synthetic Communications.The article was published on 2003-01-05. It has received 3 citations till now. The article focuses on the topics: Claisen rearrangement & Ireland–Claisen rearrangement.read more
Citations
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Journal ArticleDOI
Michael addition of malonic esters to endo-tricyclo[5.2.1.02,6]deca-4,8-dien-4-bromo-3-one: a novel entry to highly functionalized cis–anti–cis fused triquinane framework/skeleton
Tarur Konikkaledom Dinesh,Tarur Konikkaledom Dinesh,Namasivayam Palani,Sengottuvelan Balasubramanian +3 more
TL;DR: In this paper, a stereo controlled synthesis of cis-anti-cis fused triquinane is reported from readily accessible starting material, endo-tricyclo[5.2.1]deca-4,8-dien-4-bromo-3.
Journal ArticleDOI
Design and Synthesis of Linearly Fused Triquinanes via Tandem‐Metathesis: Access to Basic Core of Cucumin, Capnellene, Chondrosterin, and Xeromphalinone
TL;DR: In this article , a short synthetic approach to linearly fused tricyclic enone 1 and cis-anti-cis type hydroxy-triquinane 2 has been described in an efficient manner by employing tandem-metathesis as a key step.
Journal ArticleDOI
A Stereospecific Approach to cis‐anti‐cis Triquinanes.
TL;DR: A methodology for the synthesis of compounds containing the cis-anti-cis fused triquinane system has been developed starting from tricyclo[5.2.1]deca-4,8-dien-3-(exo)ol 6 involving Ireland ester Claisen rearrangement and intramolecular diazo ketone cyclopropanation reactions as key steps.
References
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Journal ArticleDOI
The ester enolate Claisen rearrangement. Stereochemical control through stereoselective enolate formation
Journal ArticleDOI
Synthesis of Polyquinane Natural Products: An Update.
Journal ArticleDOI
Intramolecular cyclization of unsaturated diazoketones
Gilbert Stork,J. Ficini +1 more
Book ChapterDOI
7.2 – Claisen Rearrangements
TL;DR: In this paper, a survey of variants of the Claisen rearrangement that are of general use in stereoselective organic synthesis is presented, highlighting the influence of steric and electronic parameters on transition state geometries.