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Journal ArticleDOI

A titanium salicylate, Na4[Ti(C7H4O3)3]2·11H2O

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TLDR
The tetra-sodium tetra-(salicylato-titanate(IV) undeca-hydrate, Na4[Ti(C7H4O3)3]2·11H2O, crystallizes with two titanium salicylate complex ions, four sodium ions and 11 water molcules in the asymmetric unit.
Abstract
The title compound, tetra­sodium bis­[tris­(salicylato­titanate(IV)] undeca­hydrate, Na4[Ti(C7H4O3)3]2·11H2O, crystallizes with two titanium salicylate complex ions, four sodium ions and 11 water mol­ecules in the asymmetric unit. One water O atom is disordered over two positions, having 0.74 (5) and 0.26 (5) occupancy. Both Ti atoms and three sodium ions adopt a distorted octa­hedral coordination by O atoms. The fourth sodium ion has a distorted trigonal–bipyramidal coordination by oxygen, sharing one edge with a sodium coordination octa­hedron.

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Fueling a Hot Debate on the Application of TiO2 Nanoparticles in Sunscreen.

TL;DR: By closely examining the biological use of TiO2 and the influence of biomolecules on its stability and solubility, the reactivity of the material is reassessed in the presence and absence of UV energy.
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Exploring titanium(IV) chemical proximity to iron(III) to elucidate a function for Ti(IV) in the human body

TL;DR: Based on its chemical similarities with Fe, the biological coordination chemistry of Fe(III) and Ti(IV) is compared and it is hypothesized that Ti( IV) can bind to similar intracellular biomolecules and inhibit Fe bioavailability.
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Exploring Titanium(IV) Complexes as Potential Antimicrobial Compounds

TL;DR: Eight Ti(IV) complexes and some of their corresponding ligands were screened by the Community for Open Antimicrobial Drug Discovery for antimicrobial activity and only one compound exhibited promising inhibitory activity against the Gram-positive bacteria methicillin-resistant Staphylococcus aureus and minimal toxicity against human cells.
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