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Journal ArticleDOI

Acid catalysis of the Claisen rearrangement. 2. Formation of the benzofurobenzopyran and benzofuro[3,2-b]benzofuran skeletons from 1,4-bis(aryloxy)-2-butynes

Dallas K. Bates, +1 more
- 01 Sep 1978 - 
- Vol. 43, Iss: 20, pp 3856-3861
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This article is published in Journal of Organic Chemistry.The article was published on 1978-09-01. It has received 27 citations till now. The article focuses on the topics: Claisen rearrangement & Benzofuran.

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Catalysis by ionic liquid. A green protocol for the stereoselective debromination of vicinal-dibromides by [pmIm]BF4 under microwave irradiation.

TL;DR: An easily accessible ionic liquid, 1-methyl-3-pentylimidazolium fluoroborate, [pmIm]BF4, has been demonstrated to be an efficient catalyst as well as reaction medium for the stereoselective debromination of a variety of structurally diverse vicinal-dibromides to the corresponding (E)-alkenes in high yields under microwave irradiation.
Journal ArticleDOI

Thiophenol-catalyzed Claisen rearrangement and radical cyclization: formation of furo- and pyrano-coumarin derivatives

TL;DR: In this article, the synthesis of dihydrofurocoumarins and dihydropyranocoumarin in excellent yields from 4-prop-2-ynyloxy coumarin via a thiol mediated radical reaction is described.
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