Journal ArticleDOI
Adsorption of anions on smooth platinum electrodes
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TLDR
In this paper, the effect of anions on the adsorption of hydrogen, oxygen and methanol on smooth platinum electrodes has been investigated, and the results show that anions affect the energy distribution of adsorbed hydrogen.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 1970-08-01. It has received 173 citations till now. The article focuses on the topics: Adsorption & Iodide.read more
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Work function, electronegativity, and electrochemical behaviour of metals
TL;DR: In this article, it was shown that the best relationship between the two above quantities is expressed by the equations: E z =−4.61 −0.40 α, where α=(2.10−x M )/0.6 is defined as the degree of orientation of water at the interface.
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Electrochemical oxide film formation at noble metals as a surface-chemical process
TL;DR: In this article, the formation of the oxide films can be examined in detail by recording the distinguishable stages in the film's electrochemical reduction in linear-sweep voltammetry which is sensitive down to OH O fractional coverages as low as 0.5% and over time-scales down to 50μs in experiments on time-evolution and transformation of oxide films.
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Impedance of rough capacitive electrodes
TL;DR: In this article, the authors show that capacitance dispersion due to irregular geometry appears at much higher frequencies than is usual in electrochemical methodologies and demonstrate that the capacitance on rough electrodes is due to adsorption effects.
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The oxygen reduction reaction on a Pt/carbon fuel cell catalyst in the presence of chloride anions
TL;DR: In this paper, the oxygen reduction reaction on a typical carbon supported Pt fuel cell catalyst in the presence of different anions was studied and it was shown that the reduction reaction activity decreases in the order ClO 4− HSO 4− Cl −, consistent with the increasing adsorption bond strength of the anions.
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Book
Modern Aspects of Electrochemistry
TL;DR: In this paper, the authors focus on topics at the forefront of electrochemical research, such as splitting water by electrolysis, splitting water with visible light, and the recent development of lithium batteries.
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Advances in Electrochemistry and Electrochemical Engineering
P. Delahay,Ashok K. Vijh +1 more