Journal ArticleDOI
Advances in electrochemical cofactor regeneration: enzymatic and non-enzymatic approaches
Reads0
Chats0
TLDR
In this article, the authors summarize non-enzymatic and enzymatic electrochemical approaches for cofactor regeneration, then discuss recent developments to solve major issues such as Rh-catalyst mediated enzyme mutual inactivation, electron-transfer rates, catalyst sustainability, product selectivity and simplifying product purification.About:
This article is published in Current Opinion in Biotechnology.The article was published on 2022-02-01. It has received 21 citations till now. The article focuses on the topics: Cofactor & Formate dehydrogenase.read more
Citations
More filters
Journal ArticleDOI
Hierarchically porous metal organic framework immobilized formate dehydrogenase for enzyme electrocatalytic CO2 reduction
Lin Yan,Guanhua Liu,Jian-Qiang Liu,Jing Bai,Yaoxuan Li,Huaxun Chen,Liya Zhou,Jing Gao,Yanjun Jiang +8 more
TL;DR: In this article , a hierarchical porous structure (HP-UiO-66-NH2) containing both micropores and mesopores was firstly converted into hierarchically porous structure to simultaneously enhance the enrichment of CO2 and the immobilization of formate dehydrogenase by optimizing the pore structure.
Journal ArticleDOI
Connecting primitive phase separation to biotechnology, synthetic biology, and engineering
TL;DR: In this paper, a review of liquid-liquid phase separation (LLPS) applied to primitive compartment research is presented, and some examples of LLPS applied to biomolecule purification, drug delivery, artificial cell construction, waste and pollution management, and flavor encapsulation.
Journal ArticleDOI
Fine-Tuning the Electrocatalytic Regeneration of NADH Cofactor Using [Rh(Cp*)(bpy)Cl]+-Functionalized Metal-Organic Framework Films.
TL;DR: In this paper , an electrochemical system for NADH cofactor regeneration, based on highly ordered three-dimensional (3D) metal-organic framework (NU-1000) films, is proposed.
Journal ArticleDOI
Covalent Immobilization of Dehydrogenases on Carbon Felt for Reusable Anodes with Effective Electrochemical Cofactor Regeneration
Giuseppe Pietricola,Lesly Chamorro,Micaela Castellino,Diego Maureira,Tonia Tommasi,Simelys Hernández,Lorena Wilson,Debora Fino,Carminna Ottone +8 more
TL;DR: In this article , the regeneration process of nicotinamide adenine dinucleotide in its oxidized form (NAD+), on a carbon felt surface, has been deeply studied with tests performed at different electrical potentials.
Journal ArticleDOI
Electrochemical Recycling of Adenosine Triphosphate in Biocatalytic Reaction Cascades.
Serge Michel Ruccolo,Gilmar A. Brito,Melodie Christensen,Tetsuji Itoh,Keith Anthony Mattern,Kevin Stone,Neil A. Strotman,Alexandra C. Sun +7 more
TL;DR: In this paper , a simplified cellular respiration mimic was used to turn over enzymes for ATP generation in a simplified respiration mimicking system, which is simple, robust, and scalable, as well as broadly applicable to complex enzymatic processes.
References
More filters
Journal ArticleDOI
Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility
TL;DR: The synthesis of epitaxially grown, wurtzite CdSe/CdS core/shell nanocrystals is reported in this paper, where shells of up to three monolayers in thickness were grown on cores ranging in diameter from 23 to 39.
Journal ArticleDOI
Nanoengineering of particle surfaces.
TL;DR: In this article, the authors present the state-of-the-art in strategies for engineering particle surfaces, such as the layer-by-layer deposition process, which allows fine control over shell thickness and composition.
Journal ArticleDOI
Engineering the third wave of biocatalysis
Uwe T. Bornscheuer,Gjalt W. Huisman,Romas J. Kazlauskas,Romas J. Kazlauskas,Stefan Lutz,Jeffrey C. Moore,Karen Robins +6 more
TL;DR: Applications of protein-engineered biocatalysts ranging from commodity chemicals to advanced pharmaceutical intermediates that use enzyme catalysis as a key step are discussed.
Journal ArticleDOI
Natural engineering principles of electron tunnelling in biological oxidation-reduction.
TL;DR: The 14 Å or less spacing of redox centres provides highly robust engineering for electron transfer, and may reflect selection against designs that have proved more vulnerable to mutations during the course of evolution.
Journal ArticleDOI
Organometallic chemistry, biology and medicine: ruthenium arene anticancer complexes
TL;DR: Initial studies on amino acids and nucleotides suggest that kinetic and thermodynamic control over a wide spectrum of reactions of Ru(II) arene complexes with biomolecules can be achieved.
Related Papers (5)
Electrochemical Regeneration of Oxidoreductases for Cell-free Biocatalytic Redox Reactions
Frank Hollmann,Andreas Schmid +1 more