Advances in the Use of Synthons in Organic Chemistry
01 Jan 1994-Synthesis (© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.)-Vol. 1994, Iss: 09, pp 1005-1005
About: This article is published in Synthesis.The article was published on 1994-01-01 and is currently open access. It has received 40 citations till now. The article focuses on the topics: Bioorganic chemistry.
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TL;DR: 2. R-Heteroatom-Substituted C−X Bond Activation and Cross-Coupling Reactions 3197 1. Kumada−Corriu Reaction 2. Stille Reaction 3197 3. Reductive Carbonylation 3199 IV. Chelation Ass Activation of a Proximal C− X Bond 3199
Abstract: 2. Formation of Aldehydes 3191 3. Formation of Ketones 3194 4. Formation of Silyl Enol Ethers 3194 C. Reductive Heck Reactions 3194 D. Miscellaneous Reactions 3196 III. R-Heteroatom-Substituted C−X Bond Activation 3197 A. Cross-Coupling Reactions 3197 1. Kumada−Corriu Reaction 3197 2. Stille Reaction 3197 3. Manganese-Catalyzed Reactions 3198 B. Carbonylation 3198 C. Reductive Carbonylation 3199 IV. Chelation Assisted Activation of a Proximal C−X Bond 3199
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TL;DR: In this article, an overview of the chemistry of enaminones and related compounds containing the structural unit N-CaC-Z (Za COR, CO2R, CN, NO2, S O 2Ar, etc.).
Abstract: Efforts in our laboratories to devise a general approach to the synthesis of alkaloids focus on the versatile reactivity of enaminones and related compounds containing the structural unit N-CaC-Z (Za COR, CO2R, CN, NO2 ,S O 2Ar, etc.). This lecture presents an overview of our research with these useful building blocks. Themes to be elaborated include chemo- selectivity and diastereoselectivity in reactions of enaminones, and the challenge of controlling absolute stereochemistry.
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