All-lignocellulosic fiberboard from corn biomass and cellulose nanofibers
TL;DR: In this paper, a corn stalk biomass was used to produce high yield thermomechanical pulp (TMP) that was converted into binderless fiberboards and cellulose nanofibers (CNF) were also added as reinforcing agent.
About: This article is published in Industrial Crops and Products.The article was published on 2015-12-15. It has received 63 citations till now. The article focuses on the topics: Fiberboard & Cellulose fiber.
Citations
More filters
TL;DR: Mycelium composites are an emerging class of cheap and environmentally sustainable materials experiencing increasing research interest and commercialisation in the EU and USA for construction applications as mentioned in this paper, such as insulation, door cores, panelling, flooring, cabinetry and other furnishings.
185 citations
TL;DR: In this paper, various extraction techniques of CNF from different plant and bacterial sources are discussed critically with special emphasis on CNF based composites with a focus on cellulose nanofibers.
Abstract: Cellulose is a natural biopolymer that is abundantly available in plant cell walls and is secreted in its pure forms by many bacteria. Due to their unique features cellulose materials are considered as efficient replacements for conventional polymers. Cellulose nanofibers (CNF) have attracted wide interest due to their nano size, ease of preparation, low cost, tuneable surface properties and enhanced mechanical properties. However, the efficiency of CNF depends on the extraction method employed from its source and their features vary from source to source. Hence, there is a need to understand the specificity of CNF extraction from its source in order to obtain highly efficient CNF with maximum potential. CNF has been extracted from plant sources using physical, chemical and enzymatic methods. Although plant derived CNF possess excellent features, the involvement of chemicals and complexity in extraction process limits their usage. Bacterial CNF overcome this limitation through its extracellular secretion which makes extraction easy. CNF is also extracted from various marine filamentous algae. The percentage of CNF obtained from algal sources is less compared to plants and bacterial sources. CNF finds wide variety of applications such as drug carriers, tissue regenerating scaffolds, water purifying membranes, electrodes, supercapacitors, fluorescent probes and flexible electronics. In this review, various extraction techniques of CNF from different plant and bacterial sources are discussed critically with special emphasis on CNF based composites.
132 citations
TL;DR: Novel hybrid panel composites based on wood, fungal mycelium, and cellulose nanofibrils (CNF) resulted in enhanced physical and mechanical properties compared to the ones made by physically mixing wood, mycelia, and CNF.
Abstract: Novel hybrid panel composites based on wood, fungal mycelium, and cellulose nanofibrils (CNF) were developed and investigated in the present study. In one set of experiments, mycelium was grown on softwood particles to produce mycelium-modified wood which was then hybridized with various levels of CNF as binder. The other set of experiments were conducted on unmodified wood particles mixed with CNF and pure mycelium tissue. It was found that the composites made of mycelium-modified wood and CNF resulted in enhanced physical and mechanical properties compared to the ones made by physically mixing wood, mycelium, and CNF. Scanning electron microscopy (SEM) images showed that mycelium modification covered wood particles with a network of fungal hyphae whereas CNF formed a uniform mycelial film over wood particles. Mycelium modification had a significant effect on reducing water absorption and thickness swelling of the hybrid composites and CNF increased the modulus of rupture and modulus of elasticity, optimally at 2.5% addition. We also present results and analysis pertaining to the development of unique lightweight composite systems with physical and mechanical properties optimized at 5% CNF addition with potential to be used in packaging and furniture applications.
78 citations
TL;DR: In this article, a review of the self-bonding mechanism in binderless fiberboard with a focus on agriculture residues based raw materials is presented, where the physical, mechanical, and thermal properties of the fiberboard are discussed.
66 citations
TL;DR: In this article, the effect of drying on the strength development and adhesion between cellulose nanofibrils and wood particles was investigated, and the effects of surface roughness on the wood-CNF bonding strength was evaluated through lap shear testing and scanning electron microscopy.
Abstract: Cellulose nanofibrils (CNF) were investigated as a binder in the formulation of particleboard (PB) panels. The panels were produced in four different groups of target densities with varying amounts of CNF binder. The produced panels were then tested to determine the modulus of rupture (MOR), modulus of elasticity (MOE), internal bond (IB), water absorption (WA), and thickness swelling (TS) properties. Density gradients through the thickness of the panels were evaluated using an X-ray density profiler. The effect of drying on the strength development and adhesion between CNF and wood particles (WP) was investigated, and the effect of surface roughness on the wood-CNF bonding strength was evaluated through lap shear testing and scanning electron microscopy. It was found that at lower panel densities, the produced samples met the minimum standard values recommended for particleboard panels. Medium-density panels met the standard levels for IB, but they did not reach the recommended values for MOR and MOE. The possible bonding mechanism and panel formation process are discussed in light of microscopic observations and the results of lap shear tests were presented.
61 citations
Additional excerpts
...Some recent study has been done to use 2,2,6,6-tetramethylpiperidine-l-oxyl (TEMPO) mediated CNF as a reinforcing agent in the manufacture of fiberboards from corn thermomechanical fibers (Theng et al. 2015)....
[...]
References
More filters
TL;DR: This Review assembles the current knowledge on the isolation of microfibrillated cellulose from wood and its application in nanocomposites; the preparation of nanocrystalline cellulose and its use as a reinforcing agent; and the biofabrication of bacterial nanocellulose, as well as its evaluation as a biomaterial for medical implants.
Abstract: Cellulose fibrils with widths in the nanometer range are nature-based materials with unique and potentially useful features. Most importantly, these novel nanocelluloses open up the strongly expanding fields of sustainable materials and nanocomposites, as well as medical and life-science devices, to the natural polymer cellulose. The nanodimensions of the structural elements result in a high surface area and hence the powerful interaction of these celluloses with surrounding species, such as water, organic and polymeric compounds, nanoparticles, and living cells. This Review assembles the current knowledge on the isolation of microfibrillated cellulose from wood and its application in nanocomposites; the preparation of nanocrystalline cellulose and its use as a reinforcing agent; and the biofabrication of bacterial nanocellulose, as well as its evaluation as a biomaterial for medical implants.
3,452 citations
TL;DR: The new cellulose-based nanofibers formed by size reduction process of native cellulose fibers by TEMPO-mediated oxidation have potential application as environmentally friendly and new bio- based nanomaterials in high-tech fields.
Abstract: Native wood celluloses can be converted to individual nanofibers 3–4 nm wide that are at least several microns in length, i.e. with aspect ratios >100, by TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-mediated oxidation and successive mild disintegration in water. Preparation methods and fundamental characteristics of TEMPO-oxidized cellulose nanofibers (TOCN) are reviewed in this paper. Significant amounts of C6 carboxylate groups are selectively formed on each cellulose microfibril surface by TEMPO-mediated oxidation without any changes to the original crystallinity (∼74%) or crystal width of wood celluloses. Electrostatic repulsion and/or osmotic effects working between anionically-charged cellulose microfibrils, the ζ-potentials of which are approximately −75 mV in water, cause the formation of completely individualized TOCN dispersed in water by gentle mechanical disintegration treatment of TEMPO-oxidized wood cellulose fibers. Self-standing TOCN films are transparent and flexible, with high tensile strengths of 200–300 MPa and elastic moduli of 6–7 GPa. Moreover, TOCN-coated poly(lactic acid) films have extremely low oxygen permeability. The new cellulose-based nanofibers formed by size reduction process of native cellulose fibers by TEMPO-mediated oxidation have potential application as environmentally friendly and new bio-based nanomaterials in high-tech fields.
2,301 citations
TL;DR: Never-Dried and once-dried hardwood celluloses were oxidized by a 2,2,6,6-tetramethylpiperidine-1-oxyl radical (TEMPO)-mediated system, and highly crystalline and individualized cellulose nanofibers, dispersed in water, were prepared by mechanical treatment of the oxidized celluloses/water slurries.
2,017 citations
TL;DR: Wood nanofibrils are used to prepare porous cellulose nanopaper of remarkably high toughness and the large strain-to-failure means that mechanisms, such as interfibril slippage, also contributes to inelastic deformation in addition to deformation of the nan ofibrils themselves.
1,187 citations
01 Jan 1946
904 citations