Journal ArticleDOI
Alternating copolymerisations of dioxaphospholane and dioxaphosphorinane with γ-butyrolactone and ethylene oxide
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TLDR
In this paper, a copolymer containing phosphorus was prepared from 2-phenyl-1,3,2-dioxaphospholane and 4-oxo-5,6-benzo with ethylene oxide and γ-butyrolactone.About:
This article is published in European Polymer Journal.The article was published on 1982-01-01. It has received 3 citations till now. The article focuses on the topics: Ethylene oxide.read more
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Why δ-Valerolactone Polymerizes and γ-Butyrolactone Does Not
TL;DR: The overall results indicate that the lack of polymerizability of gamma-butyrolactone should be attributed to the low strain of the ring, which shows much less geometric distortion in the ester group than delta-valerolactone, and the notable stability of the coiled conformations found in model compounds of poly-4-hydroxybutyrate.
Journal ArticleDOI
Spontaneous zwitterionic copolymerisation: An undervalued and efficacious technique for the synthesis of functional degradable oligomers and polymers
TL;DR: The spontaneous zwitterionic copolymerisation (SZWIP) of compatible nucleophilic and electrophilic monomers is a relatively unknown and unexplored method for the synthesis of (predominantly alternating) degradable co- and terpolymers as mentioned in this paper.
Journal ArticleDOI
Cycloexpansion Reactions in Benzo[e]-1,3,2-diheterophosphorin-4-ones and 4-Oxo-1,3,2-dioxaphospholanes
Vladimir F. Mironov,Liliya M. Burnaeva,G. A. Ivkova,L. M. Abdrakhmanova,Mudaris N. Dimukhametov,I. V. Konovalova +5 more
TL;DR: In this article, a review of the reactions of 2-R-benzo[d]-1,3,2-dioxaphosphorin-4-ones with unsaturated compounds is presented.
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Journal ArticleDOI
No Catalyst Copolymerization by Spontaneous Initiation Mechanism
TL;DR: In this article, a new type of copolymerization, which requires no added initiator, is presented, and a survey of elemental reactions of selected combinations of Copolymerisation is given.
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1,3-Addition-Type Ring-Opening Polymerization of Cyclic Phosphonites
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No Catalyst Copolymerization by Spontaneous Initiation. A New Method of Preparation of Alternating Copolymers
TL;DR: A new type of copolymerization is presented which proceeds without any added catalyst as mentioned in this paper, where a monomer of nucleophilic reactivity (MN) is mixed with the second monomer having electrophilic reactivities (ME) to produce a zwitterion +MN-ME-(1), which is responsible for initiation as well as propagation.