Journal ArticleDOI
An electron spectroscopic study of the adsorption of nitrogen on a Ni/TiO2 catalyst prepared in situ in the spectrometer: evidence for dissociative adsorption in the strong-metal-support-interaction (SMSI) state
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In this paper, it was shown that nitrogen is dissociatively adsorbed on an annealed Ni/TiO2 surface just as on a Ti-Ni alloy surface.Abstract:
Nitrogen is dissociatively adsorbed on an annealed Ni/TiO2 surface just as on a Ti–Ni alloy surface while it is molecularly adsorbed on a Ni/Al2O3 surface.read more
References
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Journal ArticleDOI
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Journal ArticleDOI
Strong interactions in supported-metal catalysts.
TL;DR: Spectroscopic measurements indicate that an electron is transferred from the cation (such as Ti(3+) or Nb(4+)) to the metal particle, which leads to profound changes in the catalytic and chemisorption properties and the morphology of the metal particles.
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Electronic structure of Ni and Pd alloys. I. X-ray photoelectron spectroscopy of the valence bands
TL;DR: In this article, X-ray photoelectron (XPS) spectra of the valence bands of approximately 60 Ni and Pd alloys and intermetallic compounds with 20 different elements are presented.
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A search for precursor states to molecular nitrogen chemisorption on Ni(100), Re(0001) and W(100) surfaces at ~20 K
TL;DR: In this article, the authors studied adsorption and condensation of molecular nitrogen on Ni(100), Re(0001) and W(100) surfaces by XPS at surface temperatures ⩾ 20 K in order to search for a precursor state to the linearly bonded chemisorbed state (γ-state).
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A combined XPS-UPS-EELS study of nitrogen adsorbed on clean and barium-promoted iron surfaces: The nature of the precursor to dissociation
TL;DR: For N2 on a clean Fe surface, the adsorbed precursor in a parallel orientation becomes predominant around 110 K, while at lower temperatures it coexists with a weakly adorbed species as mentioned in this paper.