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Journal ArticleDOI

An improved scale of solvent nucleophilicity based on the solvolysis of the S-methyldibenzothiophenium ion

01 Mar 1991-Journal of Organic Chemistry (American Chemical Society)-Vol. 56, Iss: 5, pp 1845-1850
About: This article is published in Journal of Organic Chemistry.The article was published on 1991-03-01. It has received 178 citations till now. The article focuses on the topics: Scale (ratio) & Solvolysis.
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Journal ArticleDOI
Teruo Umemoto1

480 citations

Journal ArticleDOI
TL;DR: In this paper, it is shown how the correlation (Eqn (1)) log k20°C = s(E + N) where s and N are nucleophile-specific parameters and E is an electrophile-specific parameter.

276 citations