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Atomic layer deposition processes for non-volatile memory devices

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TLDR
In this paper, a memory device is provided which includes a floating gate polysilicon layer disposed over source/drain regions of a substrate, a silicon oxynitride layer over an inter-poly dielectric stack disposed over a silicon oxide layer, and a control gate poly silicon layer over the second aluminum oxide layer.
Abstract
Embodiments of the invention provide memory devices and methods for forming memory devices. In one embodiment, a memory device is provided which includes a floating gate polysilicon layer disposed over source/drain regions of a substrate, a silicon oxynitride layer disposed over the floating gate polysilicon layer, a first aluminum oxide layer disposed over the silicon oxynitride layer, a hafnium silicon oxynitride layer disposed over the first aluminum oxide layer, a second aluminum oxide layer disposed over the hafnium silicon oxynitride layer, and a control gate polysilicon layer disposed over the second aluminum oxide layer. In another embodiment, a memory device is provided which includes a control gate polysilicon layer disposed over an inter-poly dielectric stack disposed over a silicon oxide layer disposed over the floating gate polysilicon layer. The inter-poly dielectric stack contains two silicon oxynitride layers separated by a silicon nitride layer.

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References
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Sequential chemical vapor deposition

TL;DR: In this article, the authors proposed a method for sequential chemical vapor deposition by employing a reactor operated at low pressure, a pump to remove excess reactants, and a line to introduce gas into the reactor through a valve.
Journal ArticleDOI

Surface Chemistry for Atomic Layer Growth

TL;DR: In this article, the basic concepts of atomic layer growth using molecular precursors and binary reaction sequence chemistry are reviewed and the characteristics of film deposition using ALP are explored using recent examples for Al2O3 ALP.
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Atomic layer deposition with nitrate containing precursors

TL;DR: In this paper, metal nitrate-containing precursor compounds are employed in atomic layer deposition processes to form metal-containing films, eg metal, metal oxide, and metal nitride, which films exhibit an atomically abrupt interface and an excellent uniformity.
Patent

Radical-assisted sequential CVD

TL;DR: In this article, a new method for CVD deposition on a substrate is taught wherein radical species are used in alternate steps to depositions from a molecular precursor to treat the material deposited from the molecular precursor and to prepare the substrate surface with a reactive chemical in preparation for the next molecular precursor step.
Journal ArticleDOI

Atomic Layer Deposition of Oxide Thin Films with Metal Alkoxides as Oxygen Sources

TL;DR: This finding adds to the other benefits of the ALD method, especially the atomic-level thickness control and excellent uniformity, and takes a major step toward the scientifically challenging and technologically important task of replacing silica as the gate dielectric in the future generations of metal oxide semiconductor field effect transistors.
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