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Book ChapterDOI

Band Gap Engineering of CdTe Quantum Dots by Hg Alloying in Infrared Region

TL;DR: In this paper, the diameter of the synthesized quantum dots is 3.8 ± 0.5 nm, as estimated from high resolution transmission electron micrographs, and the mercury molar fraction modified band gap engineering is demonstrated with band gap changing from 2.5 eV for CdTe quantum dots to 1.25 eV.
Abstract: We synthesized Hg alloyed CdTe quantum dots (Cd1−xHgxTe) using hydrothermal route. N-acetyl-cysteine is used as the capping agent for water dispersed Cd1−xHgxTe (x = 0, 0.05, 0.1 and 0.5) quantum dots. The diameter of the synthesized quantum dots is 3.8 ± 0.5 nm, as estimated from high resolution transmission electron micrographs. The mercury molar fraction modified band gap engineering is demonstrated with band gap changing from 2.5 eV for CdTe quantum dots to 1.25 eV for Cd0.5Hg0.5Te.
References
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Journal ArticleDOI
TL;DR: The origins, challenges and solutions of NIH Image and ImageJ software are discussed, and how their history can serve to advise and inform other software projects.
Abstract: For the past 25 years NIH Image and ImageJ software have been pioneers as open tools for the analysis of scientific images. We discuss the origins, challenges and solutions of these two programs, and how their history can serve to advise and inform other software projects.

44,587 citations

Journal ArticleDOI
16 Feb 1996-Science
TL;DR: In this article, the authors focus on the properties of quantum dots and their ability to join the dots into complex assemblies creates many opportunities for scientific discovery, such as the ability of joining the dots to complex assemblies.
Abstract: Current research into semiconductor clusters is focused on the properties of quantum dots-fragments of semiconductor consisting of hundreds to many thousands of atoms-with the bulk bonding geometry and with surface states eliminated by enclosure in a material that has a larger band gap. Quantum dots exhibit strongly size-dependent optical and electrical properties. The ability to join the dots into complex assemblies creates many opportunities for scientific discovery.

10,737 citations

Journal ArticleDOI
TL;DR: In this article, three QD solar cell configurations are described: (1) photoelectrodes comprising QD arrays, (2) QD-sensitized nanocrystalline TiO 2, and (3) QDs dispersed in a blend of electron- and hole-conducting polymers.
Abstract: Quantum dot (QD) solar cells have the potential to increase the maximum attainable thermodynamic conversion efficiency of solar photon conversion up to about 66% by utilizing hot photogenerated carriers to produce higher photovoltages or higher photocurrents. The former effect is based on miniband transport and collection of hot carriers in QD array photoelectrodes before they relax to the band edges through phonon emission. The latter effect is based on utilizing hot carriers in QD solar cells to generate and collect additional electron–hole pairs through enhanced impact ionization processes. Three QD solar cell configurations are described: (1) photoelectrodes comprising QD arrays, (2) QD-sensitized nanocrystalline TiO 2 , and (3) QDs dispersed in a blend of electron- and hole-conducting polymers. These high-efficiency configurations require slow hot carrier cooling times, and we discuss initial results on slowed hot electron cooling in InP QDs.

2,405 citations

Journal ArticleDOI
TL;DR: In this paper, thin films containing HgTe quantum dots with diameters of around 10 nm exhibit a photoresponse in the mid-infrared that extends to wavelengths as long as 5 µm.
Abstract: Researchers show that thin films containing HgTe quantum dots with diameters of around 10 nm exhibit a photoresponse in the mid-infrared that extends to wavelengths as long as 5 µm. Such films could become the basis of a new form of low-cost mid-infrared photodetector.

376 citations

Journal ArticleDOI
Yongqiang Dong1, Geli Li1, Nana Zhou1, Ruixue Wang1, Yuwu Chi1, Guonan Chen1 
TL;DR: The result agreed well with that by the DPD colorimetric method, suggesting the potential application of this new, green, sensitive, and facile sensing system in drinking water quality monitoring.
Abstract: Free chlorine was found to be able to destroy the passivated surface of the graphene quantum dots (GQDs) obtained by pyrolyzing citric acid, resulting in significant quenching of their fluorescence (FL) signal. After optimizing some experimental conditions (including response time, concentration of GQDs, and pH value of solution), a green and facile sensing system has been developed for the detection of free residual chlorine in water based on FL quenching of GQDs. The sensing system exhibits many advantages, such as short response time, excellent selectivity, wide linear response range, and high sensitivity. The linear response range of free chlorine (R2 = 0.992) was from 0.05 to 10 μM. The detection limit (S/N = 3) was as low as 0.05 μM, which is much lower than that of the most widely used N-N-diethyl-p-phenylenediamine (DPD) colorimetric method. This sensing system was finally used to detect free residual chlorine in local tap water samples. The result agreed well with that by the DPD colorimetric met...

366 citations