Barium Permangante a Useful Oxidant for the Selective Deoximation of Benzylic Oximes to their Corresponding Carbonyl Compounds
TL;DR: Benzylic oximes are oxidized selectively with barium permanganate in refluxing acetonitrile and produce their corresponding carbonyl compounds in good yields as discussed by the authors.
About: This article is published in Synthetic Communications.The article was published on 1989-12-01. It has received 20 citations till now. The article focuses on the topics: Barium permanganate & Barium.
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TL;DR: The 3-Carboxypyridinium chlorochromate (CPCC) reagent is an inexpensive, easily prepared and stable reagent that can be used to convert oximes, phenylhydrazones, p-nitrophenylhydrasones, semicarbazones and azines as discussed by the authors.
54 citations
TL;DR: In this article, an efficient and convenient conversion of oximes, phenylhydrazones, p-nitrophenyl hydrogen and semicarbazones to the corresponding carbonyl compounds with n-butyltriphenylphosphonium peroxodisulfate is reported.
Abstract: An efficient and convenient conversion of oximes, phenylhydrazones, p-nitrophenylhydrazones and semicarbazones to the corresponding carbonyl compounds with n-butyltriphenylphosphonium peroxodisulfate is reported.
37 citations
TL;DR: Benzylic and allylic oximes are selectively oxidized with zinc bismuthate in refluxing toluene or the mixture of acetonitrile-toluene to afford the corresponding carbonyl compounds as mentioned in this paper.
32 citations
TL;DR: In this paper, a method for the oxidative cleavage of oximes to their parent aldehydes and ketones with ammonium chlorochromate adsorbed on alumina is described.
25 citations
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TL;DR: In this article, the preparation of 2,2-bipyridylchromium peroxide, pyridinechromium permoxide, and chromium peroxy etherate is described.
81 citations
TL;DR: Bispyridinesilver permanganate is an easily prepared crystalline relatively stable compounds, soluble in organic solvents; its uses as an oxidizing agent of organic compounds in benzene are described as mentioned in this paper.
73 citations