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Journal ArticleDOI

Biochar as a sorbent for contaminant management in soil and water: a review.

TL;DR: Due to complexity of soil-water system in nature, the effectiveness of biochars on remediation of various organic/inorganic contaminants is still uncertain.
About: This article is published in Chemosphere.The article was published on 2014-03-01. It has received 3163 citations till now. The article focuses on the topics: Biochar & Slash-and-char.
Citations
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Journal ArticleDOI
TL;DR: A review of recent applications of biochars, produced from biomass pyrolysis (slow and fast), in water and wastewater treatment, and a few recommendations for further research have been made in the area of biochar development for application to water filtration.

1,738 citations

Journal ArticleDOI
TL;DR: In this paper, a general summary of the properties of pyrolytic products and their analysis methods is given, as well as a review of the parameters that affect the process and a summary of current state of the art.
Abstract: Pyrolysis is one of the thermochemical technologies for converting biomass into energy and chemical products consisting of liquid bio-oil, solid biochar, and pyrolytic gas. Depending on the heating rate and residence time, biomass pyrolysis can be divided into three main categories slow (conventional), fast and flash pyrolysis mainly aiming at maximising either the bio-oil or biochar yields. Synthesis gas or hydrogen-rich gas can also be the target of biomass pyrolysis. Maximised gas rates can be achieved through the catalytic pyrolysis process, which is now increasingly being developed. Biomass pyrolysis generally follows a three-step mechanism comprising of dehydration, primary and secondary reactions. Dehydrogenation, depolymerisation, and fragmentation are the main competitive reactions during the primary decomposition of biomass. A number of parameters affect the biomass pyrolysis process, yields and properties of products. These include the biomass type, biomass pretreatment (physical, chemical, and biological), reaction atmosphere, temperature, heating rate and vapour residence time. This manuscript gives a general summary of the properties of the pyrolytic products and their analysis methods. Also provided are a review of the parameters that affect biomass pyrolysis and a summary of the state of industrial pyrolysis technologies.

1,379 citations

Journal ArticleDOI
TL;DR: An overview of biochar production technologies, biochar properties, and recent advances in the removal of heavy metals, organic pollutants and other inorganic pollutants using biochar is provided.

1,301 citations


Cites background or result from "Biochar as a sorbent for contaminan..."

  • ...Ahmad et al. (2013a) found that the presence of more carbonized matters in the biochars produced at high pyrolytic temperatures caused greater adsorption of trichloroethylene (TCE)....

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  • ...The change of biochar pH is consistent with the Boehm titration results, which indicated that total acidity in the biochars decreased, while total basicity increased remarkably with increasing pyrolytic temperature (Ahmad et al., 2013a)....

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  • ...While, nearly 15–25% of biochar still remained even temperature up to 700 C (Ahmad et al., 2012, 2013a; Oh et al., 2012; Chen et al., 2012b; Qian and Chen, 2013), which confirmed the thermal stability of biochar as an adsorbent....

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  • ...Similar conclusions of greater adsorption capacity with higher pyrolytic temperature were also drawn by Zhou et al. (2010) and Ahmad et al. (2013a)....

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  • ...However, very little review article describe the use of biochar for the removal of pollutants in water (Ahmad et al., 2013b)....

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Journal ArticleDOI
TL;DR: Adsorption technologies are a low-cost alternative, easily used in developing countries where there is a dearth of advanced technologies, skilled personnel, and available capital, and adsorption appears to be the most broadly feasible pharmaceutical removal method.
Abstract: In the last few decades, pharmaceuticals, credited with saving millions of lives, have emerged as a new class of environmental contaminant. These compounds can have both chronic and acute harmful effects on natural flora and fauna. The presence of pharmaceutical contaminants in ground waters, surface waters (lakes, rivers, and streams), sea water, wastewater treatment plants (influents and effluents), soils, and sludges has been well doccumented. A range of methods including oxidation, photolysis, UV-degradation, nanofiltration, reverse osmosis, and adsorption has been used for their remediation from aqueous systems. Many methods have been commercially limited by toxic sludge generation, incomplete removal, high capital and operating costs, and the need for skilled operating and maintenance personnel. Adsorption technologies are a low-cost alternative, easily used in developing countries where there is a dearth of advanced technologies, skilled personnel, and available capital, and adsorption appears to be the most broadly feasible pharmaceutical removal method. Adsorption remediation methods are easily integrated with wastewater treatment plants (WWTPs). Herein, we have reviewed the literature (1990-2018) illustrating the rising environmental pharmaceutical contamination concerns as well as remediation efforts emphasizing adsorption.

1,170 citations

Journal ArticleDOI
TL;DR: This review summarizes the characteristics of biochar (e.g., surface area, porosity, pH, surface charge, functional groups, and mineral components) and main mechanisms governing sorption of As, Cr, Cd, Pb, and Hg by biochar and includes competitive sorption mechanisms of co-existing metals.

1,091 citations


Cites background from "Biochar as a sorbent for contaminan..."

  • ...Oxygen-containing compounds including byproducts catechol, substituted catechol, unsaturated anhydrosugars, and diols generally are effective in reducing CrVI to CrIII (Mohan et al., 2011; Ahmad et al., 2014)....

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  • ...Much research has explored its ability for heavy metal removal from water (Ahmad et al., 2014; Mohan et al., 2014)....

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  • ...Based on literatures, five mechanisms governing metal sorption from water by biochar have been proposed (Ahmad et al., 2014; Mohan et al., 2014; Nartey and Zhao, 2014; Qian et al., 2015; Tan et al., 2015; Xie et al., 2015; Inyanga et al., 2016)....

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  • ...Oxygen-containing compounds including byproducts catechol, substituted catechol, unsaturated anhydrosugars, and diols generally are effective in reducing CrVI to CrIII (Mohan et al., 2011; Ahmad et al., 2014)....

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  • ...…biochar production technologies and metal removal performance (thermodynamics, kinetics, isotherms, capacity, and mechanisms) from water using biochar (Ahmad et al., 2014; Mohan et al., 2014; Nartey and Zhao, 2014; Qian et al., 2015; Tan et al., 2015; Xie et al., 2015; Inyanga et al., 2016)....

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References
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Journal ArticleDOI
TL;DR: A review of the recent developments in the wood pyrolysis and reports the characteristics of the resulting bio-oils, which are the main products of fast wood pyrotechnics, can be found in this paper.
Abstract: Fast pyrolysis utilizes biomass to produce a product that is used both as an energy source and a feedstock for chemical production. Considerable efforts have been made to convert wood biomass to liquid fuels and chemicals since the oil crisis in mid-1970s. This review focuses on the recent developments in the wood pyrolysis and reports the characteristics of the resulting bio-oils, which are the main products of fast wood pyrolysis. Virtually any form of biomass can be considered for fast pyrolysis. Most work has been performed on wood, because of its consistency and comparability between tests. However, nearly 100 types of biomass have been tested, ranging from agricultural wastes such as straw, olive pits, and nut shells to energy crops such as miscanthus and sorghum. Forestry wastes such as bark and thinnings and other solid wastes, including sewage sludge and leather wastes, have also been studied. In this review, the main (although not exclusive) emphasis has been given to wood. The literature on woo...

4,988 citations


"Biochar as a sorbent for contaminan..." refers background or methods in this paper

  • ...Pyrolysis is generally divided into fast, intermediate, and slow depending on the residence time and temperature (Table 1; Mohan et al., 2006)....

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  • ...However, bioenergy production is dependent on the pyrolysis conditions, in which the slow pyrolysis results in a lower yield of liquid fuel and more biochar, whereas the fast pyrolysis generates more liquid fuel (bio-oil) with relatively less biochar (Mohan et al., 2006)....

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  • ...Fast pyrolysis with a very short residence time (<2 s) is often used to produce bio-oil from biomass yielding about 75% bio-oil (Mohan et al., 2006)....

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  • ...The resulting gas mixture is known as synthetic gas or syngas (Mohan et al., 2006)....

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  • ...Slow and intermediate pyrolysis processes with a residence time of few minutes to several hours or even days are generally favored for biochar 2009), Mohan et al. (2006), and Sohi et al. (2009)]....

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Journal ArticleDOI
TL;DR: A review of the literature reveals a significant number of early studies on biochar-type materials as soil amendments either for managing pathogens, as inoculant carriers or for manipulative experiments to sorb signaling compounds or toxins as mentioned in this paper.
Abstract: Soil amendment with biochar is evaluated globally as a means to improve soil fertility and to mitigate climate change. However, the effects of biochar on soil biota have received much less attention than its effects on soil chemical properties. A review of the literature reveals a significant number of early studies on biochar-type materials as soil amendments either for managing pathogens, as inoculant carriers or for manipulative experiments to sorb signaling compounds or toxins. However, no studies exist in the soil biologyliterature that recognize the observed largevariations ofbiochar physico-chemical properties. This shortcoming has hampered insight into mechanisms by which biochar influences soil microorganisms, fauna and plant roots. Additional factors limiting meaningful interpretation of many datasets are the clearly demonstrated sorption properties that interfere with standard extraction procedures for soil microbial biomass or enzyme assays, and the confounding effects of varying amounts of minerals. In most studies, microbial biomass has been found to increase as a result of biochar additions, with significant changes in microbial community composition and enzyme activities that may explain biogeochemical effects of biochar on element cycles, plant pathogens, and crop growth. Yet, very little is known about the mechanisms through which biochar affects microbial abundance and community composition. The effects of biochar on soil fauna are even less understood than its effects on microorganisms, apart from several notable studies on earthworms. It is clear, however, that sorption phenomena, pH and physical properties of biochars such as pore structure, surface area and mineral matter play important roles in determining how different biochars affect soil biota. Observations on microbial dynamics lead to the conclusion of a possible improved resource use due to co-location of various resources in and around biochars. Sorption and therebyinactivation of growth-inhibiting substances likelyplaysa rolefor increased abundance of soil biota. No evidence exists so far for direct negative effects of biochars on plant roots. Occasionally observed decreases in abundance of mycorrhizal fungi are likely caused by concomitant increases in nutrient availability,reducing theneedfor symbionts.Inthe shortterm,therelease ofavarietyoforganic molecules from fresh biochar may in some cases be responsible for increases or decreases in abundance and activity of soil biota. A road map for future biochar research must include a systematic appreciation of different biochar-types and basic manipulative experiments that unambiguously identify the interactions between biochar and soil biota.

3,612 citations


"Biochar as a sorbent for contaminan..." refers background in this paper

  • ...Increased microbial population and microbial activity in soils amended with biochar have also been observed (Verheijen et al., 2010; Lehmann et al., 2011)....

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  • ...Significant changes in soil microbial communities and enzyme activities influence biogeochemical processes in soils (Lehmann et al., 2011; Awad et al., 2012)....

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Journal ArticleDOI
01 Jan 1994-Carbon
TL;DR: In this paper, a review of the surface chemistry of carbon blacks and other activated carbons is given, focusing on surface oxides with emphasis on the chemical methods used in the assessment and identification of surface functional groups.

2,705 citations


"Biochar as a sorbent for contaminan..." refers background in this paper

  • ...The increase in proton supply for Cr(VI) reduction may be attributed to the presence of several O-containing acidic (carbonyl, lactonic, carboxylic, hydroxyl, and phenol) and basic (chromene, ketone, and pyrone) functional groups (Goldberg, 1985; Boehm, 1994)....

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Journal ArticleDOI
TL;DR: In this paper, the authors reviewed the available information about the physical and chemical properties of charcoal as affected by different combustion procedures, and the effects of its application in agricultural fields on nutrient retention and crop production.
Abstract: Rapid turnover of organic matter leads to a low efficiency of organic fertilizers applied to increase and sequester C in soils of the humid tropics. Charcoal was reported to be responsible for high soil organic matter contents and soil fertility of anthropogenic soils (Terra Preta) found in central Amazonia. Therefore, we reviewed the available information about the physical and chemical properties of charcoal as affected by different combustion procedures, and the effects of its application in agricultural fields on nutrient retention and crop production. Higher nutrient retention and nutrient availability were found after charcoal additions to soil, related to higher exchange capacity, surface area and direct nutrient additions. Higher charring temperatures generally improved exchange properties and surface area of the charcoal. Additionally, charcoal is relatively recalcitrant and can therefore be used as a long-term sink for atmospheric CO2. Several aspects of a charcoal management system remain unclear, such as the role of microorganisms in oxidizing charcoal surfaces and releasing nutrients and the possibilities to improve charcoal properties during production under field conditions. Several research needs were identified, such as field testing of charcoal production in tropical agroecosystems, the investigation of surface properties of the carbonized materials in the soil environment, and the evaluation of the agronomic and economic effectiveness of soil management with charcoal.

2,514 citations


"Biochar as a sorbent for contaminan..." refers background in this paper

  • ...Significant increases in seed germination, plant growth, and crop yields have been reported in the soils amended with biochars (Glaser et al., 2002)....

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  • ...About 18% increase in the water holding capacity of soil containing biochar was reported (Glaser et al., 2002)....

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Journal ArticleDOI
TL;DR: A molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures suggests the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states.
Abstract: Char black carbon (BC), the solid residue of incomplete combustion, is continuously being added to soils and sediments due to natural vegetation fires, anthropogenic pollution, and new strategies for carbon sequestration (“biochar”). Here we present a molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. Brunauer−Emmett−Teller (BET)−N2 surface area (SA), X-ray diffraction (XRD), synchrotron-based near-edge X-ray absorption fine structure (NEXAFS), and Fourier transform infrared (FT-IR) spectroscopy are used to show how two plant materials (wood and grass) undergo analogous but quantitatively different physical−chemical transitions as charring temperature increases from 100 to 700 °C. These changes suggest the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states: (i) in transition chars, the crystalline character of the precursor ma...

2,283 citations


"Biochar as a sorbent for contaminan..." refers background in this paper

  • ...Aromatic p-systems in highly polar biochars, produced at 400 C, are rich in electron-withdrawing functional groups (Keiluweit et al., 2010)....

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  • ...A comprehensive comparison was made by Keiluweit et al. (2010) among different biochars derived from grass and wood biomass based on pyrolysis temperature....

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  • ...At P700 C, 90% C is produced in biochars from different feedstocks (Chen et al., 2008; Keiluweit et al., 2010; Lian et al., 2011; Uchimiya et al., 2011a), which is attributed to the graphitization of C into well-organized layers....

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  • ...…Feed lot 350 2.5 51.1 47.9 23.5 28.7 9.1 53.32 4.05 15.70 3.64 1.3 – Cantrell et al. (2012) Feed lot 700 8.3 32.2 19.8 36.3 44.0 10.3 52.41 0.91 7.20 1.70 145.2 – Cantrell et al. (2012) Fescue straw 100 – 99.9 69.6 23.5 6.9 – 48.60 7.25 44.10 0.64 1.8 – Keiluweit et al. (2010) Fescue straw…...

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  • ...…al. (2010) Pine shaving 200 – 95.9 77.1 21.4 1.5 – 50.90 6.95 42.20 0.04 2.3 – Keiluweit et al. (2010) Pine shaving 300 – 62.2 70.3 28.2 1.5 – 54.80 6.50 38.70 0.05 3.0 – Keiluweit et al. (2010) Pine shaving 400 – 35.3 36.4 62.2 1.1 – 74.10 4.95 20.90 0.06 28.7 – Keiluweit et al. (2010) Pine…...

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