Biocomposites reinforced with natural fibers: 2000–2010
TL;DR: A comprehensive review of literature on bio-fiber reinforced composites is presented in this paper, where the overall characteristics of reinforcing fibers used in biocomposites, including source, type, structure, composition, as well as mechanical properties, are reviewed.
About: This article is published in Progress in Polymer Science.The article was published on 2012-11-01. It has received 3074 citations till now. The article focuses on the topics: Biocomposite & Transfer molding.
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TL;DR: Lignin is one of the three major components found in the cell walls of natural lignocellulosic materials and is widely available as a major byproduct of a number of industries involved in retrieving the polysaccharide components of plants for industrial applications, such as in paper making, ethanol production from biomass, etc.
Abstract: Rising environmental concerns and depletion of petro-chemical resources has resulted in an increased interest in biorenewable polymer-based environmentally friendly materials. Among biorenewable polymers, lignin is the second most abundant and fascinating natural polymer next to cellulose. Lignin is one of the three major components found in the cell walls of natural lignocellulosic materials. Lignin is widely available as a major byproduct of a number of industries involved in retrieving the polysaccharide components of plants for industrial applications, such as in paper making, ethanol production from biomass, etc. The impressive properties of lignin, such as its high abundance, low weight, environmentally friendliness and its antioxidant, antimicrobial, and biodegradable nature, along with its CO2 neutrality and reinforcing capability, make it an ideal candidate for the development of novel polymer composite materials. Considerable efforts are now being made to effectively utilize waste lignin as one ...
1,065 citations
TL;DR: A comprehensive review of the most appropriate and widely used natural fiber reinforced polymer composites (NFPCs) and their applications is presented in this paper. But, the results of the review are limited due to the high water absorption, inferior fire resistance, and lower mechanical properties of NFPCs.
Abstract: Natural fibers are getting attention from researchers and academician to utilize in polymer composites due to their ecofriendly nature and sustainability. The aim of this review article is to provide a comprehensive review of the foremost appropriate as well as widely used natural fiber reinforced polymer composites (NFPCs) and their applications. In addition, it presents summary of various surface treatments applied to natural fibers and their effect on NFPCs properties. The properties of NFPCs vary with fiber type and fiber source as well as fiber structure. The effects of various chemical treatments on the mechanical and thermal properties of natural fibers reinforcements thermosetting and thermoplastics composites were studied. A number of drawbacks of NFPCs like higher water absorption, inferior fire resistance, and lower mechanical properties limited its applications. Impacts of chemical treatment on the water absorption, tribology, viscoelastic behavior, relaxation behavior, energy absorption flames retardancy, and biodegradability properties of NFPCs were also highlighted. The applications of NFPCs in automobile and construction industry and other applications are demonstrated. It concluded that chemical treatment of the natural fiber improved adhesion between the fiber surface and the polymer matrix which ultimately enhanced physicomechanical and thermochemical properties of the NFPCs.
1,022 citations
Cites background from "Biocomposites reinforced with natur..."
...This structure gives to thermoset polymer good properties such as high flexibility for tailoring desired ultimate properties, great strength, and modulus [3, 4]....
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...At 65% humidity at 21C, the equilibrium moisture content of some natural fiber can be observed in Table 4 [4]....
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...The plants, which produce cellulose fibers can be classified into bast fibers (jute, flax, ramie, hemp, and kenaf), seed fibers (cotton, coir, and kapok), leaf fibers (sisal, pineapple, and abaca), grass and reed fibers (rice, corn, and wheat), and core fibers (hemp, kenaf, and jute) as well as all other kinds (wood and roots) [4]....
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...Table 1: Natural fibers in the world and their world production [4]....
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...Table 2: Chemical composition of some common natural fibers [4]....
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TL;DR: In this paper, a brief outline of work that covers in the area of biocomposites, major class of biodegradable polymers, natural fibres, as well as their manufacturing techniques and properties has been highlighted.
Abstract: The growing ecological and environmental consciousness has driven efforts for development of new innovative materials for various end-use applications. Polymers synthesized from natural resources, have gained considerable research interest in the recent years. This review paper is intended to provide a brief outline of work that covers in the area of biocomposites, major class of biodegradable polymers, natural fibres, as well as their manufacturing techniques and properties has been highlighted. Various surface modification methods were incorporated to improve the fibre–matrix adhesion resulting in the enhancement of mechanical properties of the biocomposites. Moreover, an economical impact and future direction of these materials has been critically reviewed. This review concludes that the biocomposites form one of the emerging areas in polymer science that gain attention for use in various applications ranging from automobile to the building industries.
894 citations
TL;DR: The prime aim of this review article is to demonstrate the recent development and emerging applications of natural cellulose fibers and their polymer materials.
775 citations
TL;DR: It is evident from the literature survey presented herein that modified cellulose-based adsorbents exhibit good potential for the removal of various aquatic pollutants, however, still there is a need to find out the practical utility of these adsorbent on a commercial scale, leading to the improvement of pollution control.
747 citations
Additional excerpts
...4 glycosidic linkages (Faruk et al., 2012; Henriksson and Berglund, 2007; O'Connell et al., 2008) (Fig....
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References
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TL;DR: In this paper, Brown coir fibres were treated by NaOH solution with concentrations from 2% to 10% separately, and the tensile strength of the samples was shown.
266 citations
TL;DR: In this article, the degradation behavior of flax fibres and their polymer composites is explored by monitoring the moisture absorption and swelling, and measuring the residual mechanical properties of the flax/polypropylene composites at different moisture levels.
Abstract: The environmental degradation behaviour of flax fibres and their polymer composites are explored. New upgraded Duralin flax fibres, which have been treated by a novel treatment process for improved moisture and rot sensitivity were studied. Environmental studies showed that these upgraded Duralin flax fibres absorb less moisture than untreated Green flax fibres, whereas the mechanical properties of the treated fibres were retained, if not improved. The effect of this novel flax fibre treatment on the environmental behaviour of natural-fibre-mat-reinforced thermoplastics (NMTs) is investigated by monitoring the moisture absorption and swelling, and measuring the residual mechanical properties of the flax/polypropylene composites at different moisture levels. The moisture absorption and swelling of the upgraded flax fibre composites is approximately 30% lower than that of composites based on Green flax fibres.
265 citations
TL;DR: In this paper, the effects of a silane coupling agent on curing characteristics and mechanical properties of bamboo fiber filled natural rubber composites were studied, and the results showed that the composites improved tensile strength, tear strength, hardness and tensile modulus with the addition of Si69.
264 citations
"Biocomposites reinforced with natur..." refers background in this paper
...The mechanical and thermal properties of bamboo fiber reinforced epoxy composites [137], the effects of fiber loading, coupling and bonding agents on the mechanical properties of bamboo fiber/natural rubber composites [138,139], the isothermal crystallization kinetics of modified bamboo cellulose/PCL composites [140], the influence of environmental aging on the mechanical properties of bamboo/glass fiber reinforced PP hybrid composites [141], and the effect of ceramic fillers on mechanical properties of bamboo fiber/epoxy composites [142] were evaluated....
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TL;DR: In this paper, the authors used the Young's modulus of natural fibres for changes in moisture content and density that occur as a result of processing and found that the Halpin-Tsai equation predicted the experimental data most accurately for the NFRT created for this study.
Abstract: Natural fibre reinforced thermoplastics (NFRT) are increasingly used in a variety of commercial applications, but there has been little theoretical modeling of structure/property relationships in these materials. In this study, micromechanical models available in the short fibre composites literature were used to predict the stiffness of some commercially important natural fibre composite formulations. Also included are equations that correct the Young’s modulus of natural fibres for changes in moisture content and density that occur as a result of processing. Hemp fibres, hardwood fibres, rice hulls, and E-glass fibres were blended into high-density polyethylene in mass fractions of 10–60-wt%. The Young’s modulus of these composites was compared to theoretical values generated by the rule of mixtures, Halpin–Tsai, Nairn’s generalized shear-lag analysis and Mendels et al. stress transfer (micromechanical) models. Based on a sum of errors squared criterion, the Halpin–Tsai equation was found to predict the experimental data most accurately for the NFRT created for this study.
263 citations
"Biocomposites reinforced with natur..." refers methods in this paper
...Similar investigations (PE as matrix) were carried out using soya powder [244], curaua [245], rape straw [246,247], hemp [248], rice straw [249], bagasse [250] rice hull fibers [251] and LDPE as matrixes with wheat straw [252], abaca, bagasse and rice straw fibers [253]....
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TL;DR: The results indicate that wheat straw fibers can be used as potential reinforcing materials for making thermoplastic composites.
263 citations
"Biocomposites reinforced with natur..." refers background in this paper
...The potential of wheat straw fibers to be used as reinorcing additives for PP prepared with the influence of ifferent processes (mechanical and chemical processes) as investigated [262]....
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