Biocomposites reinforced with natural fibers: 2000–2010
TL;DR: A comprehensive review of literature on bio-fiber reinforced composites is presented in this paper, where the overall characteristics of reinforcing fibers used in biocomposites, including source, type, structure, composition, as well as mechanical properties, are reviewed.
About: This article is published in Progress in Polymer Science.The article was published on 2012-11-01. It has received 3074 citations till now. The article focuses on the topics: Biocomposite & Transfer molding.
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TL;DR: Lignin is one of the three major components found in the cell walls of natural lignocellulosic materials and is widely available as a major byproduct of a number of industries involved in retrieving the polysaccharide components of plants for industrial applications, such as in paper making, ethanol production from biomass, etc.
Abstract: Rising environmental concerns and depletion of petro-chemical resources has resulted in an increased interest in biorenewable polymer-based environmentally friendly materials. Among biorenewable polymers, lignin is the second most abundant and fascinating natural polymer next to cellulose. Lignin is one of the three major components found in the cell walls of natural lignocellulosic materials. Lignin is widely available as a major byproduct of a number of industries involved in retrieving the polysaccharide components of plants for industrial applications, such as in paper making, ethanol production from biomass, etc. The impressive properties of lignin, such as its high abundance, low weight, environmentally friendliness and its antioxidant, antimicrobial, and biodegradable nature, along with its CO2 neutrality and reinforcing capability, make it an ideal candidate for the development of novel polymer composite materials. Considerable efforts are now being made to effectively utilize waste lignin as one ...
1,065 citations
TL;DR: A comprehensive review of the most appropriate and widely used natural fiber reinforced polymer composites (NFPCs) and their applications is presented in this paper. But, the results of the review are limited due to the high water absorption, inferior fire resistance, and lower mechanical properties of NFPCs.
Abstract: Natural fibers are getting attention from researchers and academician to utilize in polymer composites due to their ecofriendly nature and sustainability. The aim of this review article is to provide a comprehensive review of the foremost appropriate as well as widely used natural fiber reinforced polymer composites (NFPCs) and their applications. In addition, it presents summary of various surface treatments applied to natural fibers and their effect on NFPCs properties. The properties of NFPCs vary with fiber type and fiber source as well as fiber structure. The effects of various chemical treatments on the mechanical and thermal properties of natural fibers reinforcements thermosetting and thermoplastics composites were studied. A number of drawbacks of NFPCs like higher water absorption, inferior fire resistance, and lower mechanical properties limited its applications. Impacts of chemical treatment on the water absorption, tribology, viscoelastic behavior, relaxation behavior, energy absorption flames retardancy, and biodegradability properties of NFPCs were also highlighted. The applications of NFPCs in automobile and construction industry and other applications are demonstrated. It concluded that chemical treatment of the natural fiber improved adhesion between the fiber surface and the polymer matrix which ultimately enhanced physicomechanical and thermochemical properties of the NFPCs.
1,022 citations
Cites background from "Biocomposites reinforced with natur..."
...This structure gives to thermoset polymer good properties such as high flexibility for tailoring desired ultimate properties, great strength, and modulus [3, 4]....
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...At 65% humidity at 21C, the equilibrium moisture content of some natural fiber can be observed in Table 4 [4]....
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...The plants, which produce cellulose fibers can be classified into bast fibers (jute, flax, ramie, hemp, and kenaf), seed fibers (cotton, coir, and kapok), leaf fibers (sisal, pineapple, and abaca), grass and reed fibers (rice, corn, and wheat), and core fibers (hemp, kenaf, and jute) as well as all other kinds (wood and roots) [4]....
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...Table 1: Natural fibers in the world and their world production [4]....
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...Table 2: Chemical composition of some common natural fibers [4]....
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TL;DR: In this paper, a brief outline of work that covers in the area of biocomposites, major class of biodegradable polymers, natural fibres, as well as their manufacturing techniques and properties has been highlighted.
Abstract: The growing ecological and environmental consciousness has driven efforts for development of new innovative materials for various end-use applications. Polymers synthesized from natural resources, have gained considerable research interest in the recent years. This review paper is intended to provide a brief outline of work that covers in the area of biocomposites, major class of biodegradable polymers, natural fibres, as well as their manufacturing techniques and properties has been highlighted. Various surface modification methods were incorporated to improve the fibre–matrix adhesion resulting in the enhancement of mechanical properties of the biocomposites. Moreover, an economical impact and future direction of these materials has been critically reviewed. This review concludes that the biocomposites form one of the emerging areas in polymer science that gain attention for use in various applications ranging from automobile to the building industries.
894 citations
TL;DR: The prime aim of this review article is to demonstrate the recent development and emerging applications of natural cellulose fibers and their polymer materials.
775 citations
TL;DR: It is evident from the literature survey presented herein that modified cellulose-based adsorbents exhibit good potential for the removal of various aquatic pollutants, however, still there is a need to find out the practical utility of these adsorbent on a commercial scale, leading to the improvement of pollution control.
747 citations
Additional excerpts
...4 glycosidic linkages (Faruk et al., 2012; Henriksson and Berglund, 2007; O'Connell et al., 2008) (Fig....
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References
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TL;DR: In this article, the fabrication process of long-fibre reinforced unidirectional thermoplastic composites made using jute yarns was investigated, and the results indicated that the molding condition at 175°C and 2.7MPa pressure was more suitable to obtain optimized properties.
Abstract: This paper primarily investigates the fabrication process of long-fibre reinforced unidirectional thermoplastic composites made using jute yarns (both untreated and treated). Tubular braiding technique was used to produce an intermediate material called “microbraid yarn” (MBY) with jute yarn as the straightly inserted axial reinforcement fibre and polymer matrix fibre being braided around the reinforcing jute yarns. Microbraid yarns were then wound in a parallel configuration onto a metallic frame and compression molded to fabricate unidirectional composite specimens. In this study, two types of polymeric materials (biodegradable poly(lactic) acid and non-biodegradable homo-polypropylene) were used as matrix fibres. Basic static mechanical properties were evaluated from tensile and 3 point bending tests. Test results were analyzed to investigate the effects of molding temperature and pressure on the mechanical and interfacial behaviour. For the unidirectional jute fibre/poly(lactic) acid (PLA) composites, the results indicated that the molding condition at 175 °C and 2.7 MPa pressure was more suitable to obtain optimized properties. Improved wettability due to proper matrix fusion facilitated thorough impregnation, which contributed positively to the fibre/matrix interfacial interactions leading to effective stress transfer from matrix to fibre and improved reinforcing effects of jute yarns. For the jute/PP unidirectional composites, specimens with only 20% of jute fibre content have shown remarkable improvement in tensile and bending properties when compared to those of the virgin PP specimens. The improvements in the mechanical properties are broadly related to various factors, such as the wettability of resin melts into fibre bundles, interfacial adhesion, orientation and uniform distribution of matrix-fibres and the lack of fibre attrition and attenuation during tubular braiding process.
154 citations
TL;DR: In this paper, the authors deal with the calculation of the elastic properties of cellulose-based natural fibers by using two different types of idealization and assumptions, one model bases on antisymmertrical laminated structure, while the second one bases on a thick laminated composite tube model, taking into account the elliptic geometry, the hollow based structure of the cross section of the fiber cell.
Abstract: This article deals with the calculation of the elastic properties of cellulose based natural fibers by using two different types of idealization and assumptions. One model (model A) bases on antisymmertrical laminated structure, while the second one (model B) bases on a thick laminated composite tube model. Model B is able to take into account the elliptic geometry, the hollow based structure of the cross section of the fiber cell. The calculated relationships between spiral angle and modulus in fiber axis by model A fits successful experimental data for holocellulose fibers which were published elsewhere. In general, modulus in fiber axis decreases with increasing spiral angle as well as the degree of anisotropy, while shear modulus reaches a maximum for a spiral angle of 45°. Fiber cell modulus increases linear with increasing cellulose content for both, the calculated (model A) and measured values. The correlation between experimental data and calculation ones was not as high as in the case of modulus versus spiral angle. The discrepancy between model A and a more real cross section is calculated (model B) with roughly 30%.
154 citations
"Biocomposites reinforced with natur..." refers background in this paper
...4) assuming that the fibers (holocellulose fibers) were lignin-free with a cellulose content of 65 wt% (which is typical cellulose content for natural fibers [186])....
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TL;DR: In this article, the compression and injection molding processes were performed in order to evaluate the better mixer method for fiber (sugarcane bagasse, bagasse cellulose and benzylated bagasse) and matrix (polypropylene).
Abstract: The compression and injection molding processes were performed in order to evaluate the better mixer method for fiber (sugarcane bagasse, bagasse cellulose and benzylated bagasse) and matrix (polypropylene). The samples (composites and polypropylene plates) were cut and submitted to mechanical tests in order to measure flexural and tensile properties. The morphological and microstructural analyses of fracture surface and specimens from composites can be easily evaluated by microscopic techniques. The fracture surface was evaluated by SEM and selected specimens from composites were analyzed by reflected light in OM. The better tested method for composites obtainment was the injection molding under vacuum process, by which composites were obtained with homogeneous distribution of fibers and without blisters. The mechanical properties show that the composites did not have good adhesion between fiber and matrix; on the other hand, the fiber insertion improved the flexural modulus and the material rigidity.
154 citations
TL;DR: In this article, a pre-impregnation technique has been introduced for the injection molding of sisal fiber reinforced polypropylene (PP/SF) composites, which can be injection moulded with relatively lower barrel temperature, and therefore significant thermal degradation of the sisal fibres could be avoided.
153 citations
"Biocomposites reinforced with natur..." refers background in this paper
...Injection molded jute [405] and sisal [406] fiber reinforced PP composites were also investigated regarding their thermal, hydrothermal and, dynamic mechanical behavior....
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TL;DR: Banana fiber (BaF)-filled composites based on high density polyethylene (HDPE)/Nylon-6 blends were prepared via a two-step extrusion method and it was found that the presence of SEBS-g-MA had a positive influence on reinforcing effect of the Nylon- 6 component in the composites.
152 citations
Additional excerpts
...Abaca fiber reinforced composites based on DPE/Nylon-6 blends were prepared [224]....
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