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Bioethylene Production from Ethanol: A Review and Techno-economical Evaluation

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TLDR
In this article, an economic analysis of a bioethylene plant was performed using Aspen® plus and Aspen Process Economic Analyzer, where different qualities of ethanol were considered.
Abstract
Manufacturing of bioethylene via dehydration of bioethanol is an alternative to the fossil-based ethylene production and decreases the environmental consequences for this chemical commodity. A few industrial plants that utilize 1st generation bioethanol for the bioethylene production already exist, although not functioning without subsidiaries. However, there is still no process producing ethylene from 2nd generation bioethanol. This study is divided into two parts. Different ethanol and ethylene production methods, the process specifications and current technologies are briefly discussed in the first part. In the second part, a techno-economic analysis of a bioethylene plant was performed using Aspen® plus and Aspen Process Economic Analyzer, where different qualities of ethanol were considered. The results show that impurities in the ethanol feed have no significant effect on the quality of the produced polymer-grade bioethylene. The capacity of the ethylene storage tank significantly affects the capital costs of the process.

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Catalytic Conversion of Carbohydrates to Initial Platform Chemicals: Chemistry and Sustainability

TL;DR: Recent advances and developments in catalytic transformations of the carbohydrate content of lignocellulosic biomass to IPCs (i.e., ethanol, 3-hydroxypropionic acid, isoprene, succinic and levulinic acids, furfural, and 5-hydroxymethylfurfural) are overviewed.
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CO2-fixation into cyclic and polymeric carbonates: Principles and applications

TL;DR: In this paper, a review of the advancements made within this field is critically discussed with special attention to the potential of these two classes of compounds as green chemical products: cyclic and polymeric carbonates.
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A review on commercial-scale high-value products that can be produced alongside cellulosic ethanol.

TL;DR: This review examines chemicals and materials with a Technology Readiness Level (TRL) of at least 8, which have reached a commercial scale and could be shortly or immediately integrated into a cellulosic ethanol process.
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The Recent Developments in Biobased Polymers toward General and Engineering Applications: Polymers that are Upgraded from Biodegradable Polymers, Analogous to Petroleum-Derived Polymers, and Newly Developed

TL;DR: In this review, biobased polymers are categorized as those that are: upgrades from biodegradable polylactides (PLA), polyhydroxyalkanoates (PHAs), and others; analogous to petroleum-derived polymers such as bio-poly(ethylene terephthalate) (bio-PET); and new biobases such as poly( methylene 2,5-furandicarboxylate (PEF).
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A quest for polycarbonates provided via sustainable epoxide/CO2 copolymerization processes

TL;DR: In this article, the authors highlight advances in copolymerization of carbon dioxide and epoxides (oxiranes) to produce polycarbonates, focusing on starting materials that have been generated from renewable feedstocks including straight-chain alkylene oxides, cyclohexadiene oxide, and limonene oxide.
References
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Journal ArticleDOI

Hydrolysis of lignocellulosic materials for ethanol production: a review.

TL;DR: Simultaneous saccharification and fermentation effectively removes glucose, which is an inhibitor to cellulase activity, thus increasing the yield and rate of cellulose hydrolysis, thereby increasing the cost of ethanol production from lignocellulosic materials.
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Ethylene biosynthesis and its regulation in higher plants

TL;DR: The pathways of Ethylene Biosynthesis, Regulation in Ripening Fruits and Senescing Flowers and Regulation by Light and Carbon Dioxide are traced.
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Production of first and second generation biofuels: A comprehensive review

TL;DR: In this paper, a review of cost effective technologies and the processes to convert biomass into useful liquid bio-fuels and bioproducts, with particular focus on some biorefinery concepts based on different feedstocks aiming at the integral utilization of these feedstocks for the production of value added chemicals.
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Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturing

TL;DR: It is concluded that greater stewardship, data, and—possibly—regulation are needed to ensure the sustainable future of shale-gas extraction and to improve public confidence in its use.
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Production of bioethanol from lignocellulosic materials via the biochemical pathway: a review.

TL;DR: The main problem with bioethanol production is the availability of raw materials for the production as mentioned in this paper, which can highly affect the production costs of the bio-ethanol, as the price of the raw materials is highly volatile.
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