Journal ArticleDOI
Biomimetic Total Synthesis of Gambogin and Rate Acceleration of Pericyclic Reactions in Aqueous Media
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This article is published in Angewandte Chemie.The article was published on 2005-01-21. It has received 84 citations till now. The article focuses on the topics: Pericyclic reaction & Claisen rearrangement.read more
Citations
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Cascade reactions in total synthesis.
TL;DR: The power of cascade reactions in total synthesis is illustrated in the construction of complex molecules and underscore their future potential in chemical synthesis.
Journal ArticleDOI
Organic Synthesis “On Water”
Arani Chanda,Valery V. Fokin +1 more
TL;DR: The currently burgeoning field of organic synthesis in aqueous media encompasses a large family of reactions, and water is still not commonly used as a sole solvent for organic synthesis, at least in part because most organic compounds do not dissolve in water to a significant extent.
Journal ArticleDOI
Organic chemistry in water
TL;DR: Water has emerged as a versatile solvent for organic chemistry in recent years and gives completely new reactivity, including pericyclic reactions, reactions of carbanion equivalent, and reactions of carbocation equivalent.
Journal ArticleDOI
Water: Nature’s Reaction Enforcer—Comparative Effects for Organic Synthesis “In-Water” and “On-Water”
TL;DR: This work presents a meta-analysis of cycloaddition, which aims to determine the carrier and removal status of H2O through a number of mechanisms, including “catalyzed” and “pericyclic” reactions.
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Green chemistry oriented organic synthesis in water
Marc‐Olivier Simon,Chao-Jun Li +1 more
TL;DR: This tutorial review briefly discusses organic synthesis in water with a Green Chemistry perspective.
References
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Journal ArticleDOI
The Diels--Alder reaction in total synthesis.
TL;DR: The Diels-Alder reaction has both enabled and shaped the art and science of total synthesis over the last few decades to an extent which has yet to be eclipsed by any other transformation in the current synthetic repertoire as mentioned in this paper.
Journal ArticleDOI
Hydrophobic acceleration of Diels-Alder reactions
Darryl Rideout,Ronald Breslow +1 more
Related Papers (5)
“Biomimetic” Cascade Reactions in Organic Synthesis: Construction of 4-Oxatricyclo[4.3.1.0]decan-2-one Systems and Total Synthesis of 1-O-Methylforbesione via Tandem Claisen Rearrangement/Diels–Alder Reactions
Kyriacos C. Nicolaou,Jim Li +1 more