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Book ChapterDOI

Biopolymer Composites With High Dielectric Performance: Interface Engineering

TL;DR: In this article, the preparation and dielectric behavior of various biopolymer composites is presented, including metal nanoparticles and carbon-based nanofillers such as carbon nanotubes, graphene, etc.
Abstract: In recent years, there is a growing interest in studying the dielectric behavior of biopolymer composites due to their potential application as a dielectric material in various electronic devices such as microchips, transformers, and circuit boards. Conducting electroactive polymer composites have also been investigated for various potential applications which include biological, biomedical, flexible electrodes, display devices, biosensors, and cells for tissue engineering. In this chapter, the preparation and dielectric behavior of various biopolymer composites is presented. These biopolymer composites generally consist of nanoscale metal nanoparticles and carbon-based nanofillers such as carbon nanotubes, graphene, graphene oxide (GO), etc., dispersed into the polymer matrix. The physical and chemical properties of these fillers and their interactions with polymers have a significant effect on the microstructure and the final properties of nanocomposites. The biopolymer composites with excellent dielectric properties show great promise as an energy storage dielectric layer in high-performance capacitor applications such as embedded capacitors. This chapter highlights some of the examples of such biopolymer composites; their processing and dielectric behavior will be discussed in detail.
Citations
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Journal Article
TL;DR: In this article, Boron nitride nanotubes (BNNT)/polyvinyl alcohol (PVA) composite fibers were fabricated via electrospinning so that all BNNTs became aligned in the fiber casting direction.
Abstract: Boron nitride nanotube (BNNT)/polyvinyl alcohol (PVA) composite fibers (<5 vol % BNNTs) were fabricated via electrospinning so that all BNNTs became aligned in the fiber casting direction. A several-fibers-thick ensemble of parallel-arranged contacting fibers made a single polymer sheet. Numerous sheets were then stacked in different ways with respect to the BNNT orientation (all fibers in adjacent sheets were either parallel or alternately rotated 90°) to make multilayer films that were finally hot-pressed. Various BNNT textures were reflected by the corresponding differences in the measured thermal conductivities of the resultant films due to anisotropy of thermal transport in the nanotubes. The highest values (0.54 W/mK) were obtained along the long axes of aligned BNNTs. Somewhat lower values (0.38 W/mK) were documented in films with alternately stacked fibers/tubes. The theoretical thermal conductivity values were estimated using the Nielsen’s model. These show good match with the experimental data. ...

162 citations

Journal ArticleDOI
TL;DR: In this paper, the potential and market stability of gelatin has been discussed and its recent studies are summarised in this paper, focusing on assessing the general utilities of the various sources of collagen as gelatin derivatives.

120 citations

Journal ArticleDOI
TL;DR: In this article, the authors summarized the recent progress in polymer electrolytes for flexible ZIBs, especially hydrogel electrolytes, including their synthesis and characterization, and provided an insight from lab research to commercialization, relevant challenges, device configurations, and life cycle analysis.
Abstract: Owing to the development of aqueous rechargeable zinc-ion batteries (ZIBs), flexible ZIBs are deemed as potential candidates to power wearable electronics. ZIBs with solid-state polymer electrolytes can not only maintain additional load-bearing properties, but exhibit enhanced electrochemical properties by preventing dendrite formation and inhibiting cathode dissolution. Substantial efforts have been applied to polymer electrolytes by developing solid polymer electrolytes, hydrogel polymer electrolytes, and hybrid polymer electrolytes; however, the research of polymer electrolytes for ZIBs is still immature. Herein, the recent progress in polymer electrolytes is summarized by category for flexible ZIBs, especially hydrogel electrolytes, including their synthesis and characterization. Aiming to provide an insight from lab research to commercialization, the relevant challenges, device configurations, and life cycle analysis are consolidated. As flexible batteries, the majority of polymer electrolytes exploited so far only emphasizes the electrochemical performance but the mechanical behavior and interactions with the electrode materials have hardly been considered. Hence, strategies of combining softness and strength and the integration with electrodes are discussed for flexible ZIBs. A ranking index, combining both electrochemical and mechanical properties, is introduced. Future research directions are also covered to guide research toward the commercialization of flexible ZIBs.

119 citations

Journal ArticleDOI
TL;DR: A systematic review methodology based on the application of this novel technology in the field of drug delivery along with the manufacturing of polypills with varied release profiles and geometries is carried out.

72 citations

References
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Journal ArticleDOI
01 Nov 2007-Carbon
TL;DR: In this article, the effect of dispersion and interfacial interaction on the morphological, rheological, and electrical properties of the composite was evaluated using a twin-screw extruder.

254 citations

Journal ArticleDOI
TL;DR: In this article, a morphological study of the bioblends was carried out by means of WAXS and SEM showing immiscible behavior, revealing high degree of interaction of the nanoclays with the aPLA.
Abstract: Biodegradable blends of amorphous poly(lactic acid) (aPLA) and polycaprolactone (PCL) and nanocomposites of these blends were developed by melt blending. A morphological study of the bioblends was carried out by means of WAXS and SEM showing immiscible behavior. The nanocomposites were also characterized morphologically by WAXS, TEM and SEM, revealing high degree of interaction of the nanoclays with the aPLA. Mechanical, thermal and gas barrier properties of the different blends and nanocomposites were studied and the effect of blending and clay addition on the above-mentioned properties was evaluated.

249 citations

Journal ArticleDOI
TL;DR: Chemically synthesized polypyrrole particles showed good biocompatibility in mice and are attractive candidates for biomedical applications in‐vivo.
Abstract: The objectives of this study were the chemical synthesis of polypyrrole particles, the investigation and estimation of the impact of polypyrrole particle concentration, and the evaluation of the effect of duration of treatment on immune-related haematological parameters and peritoneum cells in mice. The results showed that chemically prepared polypyrrole particles did not have any detectable cytotoxic effect on mouse peritoneum cells. Polypyrrole particles did not induce any allergic response, nor did they affect spleen, kidney or liver indexes. Moreover, no effect of polypyrrole particles on immune-related haematological parameters was observed. No inflammation was detected in the peritoneum of mice after a 6-week period of treatment with polypyrrole particles. In conclusion, chemically synthesized polypyrrole particles showed good biocompatibility in mice and are attractive candidates for biomedical applications in-vivo.

245 citations

Journal ArticleDOI
TL;DR: In this paper, a plausible mechanism for the formation of the nanocomposites (NCs) is presented, in which two different types of dopants, organic acids (camphorsulfonic acid (CSA) and p-toluenesulfonic acids (TSA)) and inorganic acid (hydrochloric acid) are used as a micellar template, whereas micelle formation is absent in the case of HCl.

242 citations

Journal ArticleDOI
TL;DR: The study confirmed that polyaniline has not induced any sensitization and skin irritation either and cytotoxicity, which was higher for polyAniline hydrochloride compared to polyanILine base and was observed on both cell lines, was caused rather by the reaction by-products and residues than by polyanile itself.

237 citations