Biosynthesis of silver Nanoparticles using Coriandrum Sativum leaf extract and their application in nonlinear optics

TLDR: In this paper, a simple and eco-friendly biosynthesis of silver nanoparticles using Coriandrum sativum leaf extract as reducing agent was presented, where the aqueous silver ions when exposed to leaf extract were reduced and resulted in the average size of 26 nm, which was characterized by UV-Visible, X-ray diffraction, Fourier transform infra-red spectroscopy (FT-IR), and transmission electron microscopy (TEM) techniques.

Abstract: We present a simple and eco-friendly biosynthesis of silver nanoparticles using Coriandrum sativum leaf extract as reducing agent. The aqueous silver ions when exposed to leaf extract were reduced and resulted in silver nanoparticles whose average size is 26 nm. The silver nanoparticles were characterized by UV-Visible, X-ray diffraction (XRD), Fourier transform infra-red spectroscopy (FT-IR) and transmission electron microscopy (TEM) techniques. Nonlinear optical properties of silver nanoparticles were studied using Z-scan technique with 6 ns pulse duration at 532 nm. The nonlinear refractive index and third-order susceptibility 3 were measured to be ∼ 6 0×10−13 cm2/W and 1 38×10−9 esu, respectively. Silver nanoparticles were found to exhibit strong reverse saturable absorption (RSA). RSA was identified as the main mechanism responsible for optical limiting.