Carbon Nanotubes--the Route Toward Applications
02 Aug 2002-Science (American Association for the Advancement of Science)-Vol. 297, Iss: 5582, pp 787-792
TL;DR: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects.
Abstract: Many potential applications have been proposed for carbon nanotubes, including conductive and high-strength composites; energy storage and energy conversion devices; sensors; field emission displays and radiation sources; hydrogen storage media; and nanometer-sized semiconductor devices, probes, and interconnects. Some of these applications are now realized in products. Others are demonstrated in early to advanced devices, and one, hydrogen storage, is clouded by controversy. Nanotube cost, polydispersity in nanotube type, and limitations in processing and assembly methods are important barriers for some applications of single-walled nanotubes.
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TL;DR: In this paper, single-wall carbon nanotube field effect transistors (CNFETs) operating at gate and drain voltages below 1V were investigated and it was shown that CNFET operation is controlled by Schottky barriers (SBs) in the source and drain region instead of by the nanotubes itself.
Abstract: Presents experimental results on single-wall carbon nanotube field-effect transistors (CNFETs) operating at gate and drain voltages below 1V. Taking into account the extremely small diameter of the semiconducting tubes used as active components, electrical characteristics are comparable with state-of-the-art metal oxide semiconductor field-effect transistors (MOSFETs). While output as well as subthreshold characteristics resemble those of conventional MOSFETs, we find that CNFET operation is actually controlled by Schottky barriers (SBs) in the source and drain region instead of by the nanotube itself. Due to the small size of the contact region between the electrode and the nanotube, these barriers can be extremely thin, enabling good performance of SB-CNFETs.
375 citations
Cites background from "Carbon Nanotubes--the Route Toward ..."
...Since the discovery of carbon nanotubes (CNTs) by Iijima in 1991 [1], significant progress has been achieved for both understanding the fundamental properties and exploring possible engineering applications [2]....
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TL;DR: This nanowire-embedded cloth can efficiently warm human bodies and save hundreds of watts per person as compared to traditional indoor heaters.
Abstract: Heating consumes large amount of energy and is a primary source of greenhouse gas emission. Although energy-efficient buildings are developing quickly based on improving insulation and design, a large portion of energy continues to be wasted on heating empty space and nonhuman objects. Here, we demonstrate a system of personal thermal management using metallic nanowire-embedded cloth that can reduce this waste. The metallic nanowires form a conductive network that not only is highly thermal insulating because it reflects human body infrared radiation but also allows Joule heating to complement the passive insulation. The breathability and durability of the original cloth is not sacrificed because of the nanowires’ porous structure. This nanowire cloth can efficiently warm human bodies and save hundreds of watts per person as compared to traditional indoor heaters.
375 citations
TL;DR: In this article, the interfacial shear strength of carbon nanotube (CNT) coated carbon fibers in epoxy was studied using the single-fiber composite fragmentation test.
375 citations
Cites background from "Carbon Nanotubes--the Route Toward ..."
...Tensile tests revealed that CVD processing significantly reduces the ultimate tensile strength of the fiber by an average of 37% in the case of the radially aligned MWCNTs and by 30% in the case of randomly oriented MWCNTs. Similarly, a slight reduction in the average tensile modulus of the fiber by 9% and 13% was observed in the radially aligned and randomly oriented MWCNT coated fibers, respectively....
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...The CVD process was adjusted to produce two CNT morphologies for the study: radially aligned and randomly oriented....
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...This study focuses on the effect of CVD applied CNTs on the mechanical properties of carbon fiber-reinforced epoxy composites....
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...These results are then compared to those of untreated sized and unsized T650 carbon fibers in an effort to determine to what degree the fiber mechanical properties are degraded due to thermal CVD growth of CNTs. Additionally, the effect of the presence as well as the orientation of CNTs on the interfacial shear strength of CNT coated carbon fibers is studied using the single-fiber fragmentation test....
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...Two CVD treatments were used; one produced MWCNTs which were radially aligned with respect to the fiber surface, and another which produced randomly oriented MWCNTs with respect to the fiber surface....
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TL;DR: In this article, a method of producing metallic single-wall carbon nanotubes by treatment of carbon-nanotube producing catalysts to obtain the desired catalyst particle size was presented.
Abstract: The present disclosure is directed to a method of producing metallic single-wall carbon nanotubes by treatment of carbon nanotube producing catalysts to obtain the desired catalyst particle size to produce predominantly metallic single wall carbon nanotubes. The treatment of the carbon nanotube producing catalyst particles involves contacting the catalyst particles with a mixture of an inert gas, like He, a reductant, such as H 2 , and an adsorbate, like water, at an elevated temperature range, for example, at 500° C. to 860° C., for a sufficient time to obtain the catalyst particle size. In some of the present methods, the preferential growth of nanotubes with metallic conductivity of up to 91% has been demonstrated.
373 citations
TL;DR: In this paper, different nanoparticles, such as fumed silica and carbon black, were used to optimise the epoxy matrix system of a glass-fibre-reinforced composite.
373 citations
References
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TL;DR: The nanotubes sensors exhibit a fast response and a substantially higher sensitivity than that of existing solid-state sensors at room temperature and the mechanisms of molecular sensing with nanotube molecular wires are investigated.
Abstract: Chemical sensors based on individual single-walled carbon nanotubes (SWNTs) are demonstrated. Upon exposure to gaseous molecules such as NO 2 or NH 3 , the electrical resistance of a semiconducting SWNT is found to dramatically increase or decrease. This serves as the basis for nanotube molecular sensors. The nanotube sensors exhibit a fast response and a substantially higher sensitivity than that of existing solid-state sensors at room temperature. Sensor reversibility is achieved by slow recovery under ambient conditions or by heating to high temperatures. The interactions between molecular species and SWNTs and the mechanisms of molecular sensing with nanotube molecular wires are investigated.
5,908 citations
TL;DR: In this paper, the fabrication of a three-terminal switching device at the level of a single molecule represents an important step towards molecular electronics and has attracted much interest, particularly because it could lead to new miniaturization strategies in the electronics and computer industry.
Abstract: The use of individual molecules as functional electronic devices was first proposed in the 1970s (ref 1) Since then, molecular electronics2,3 has attracted much interest, particularly because it could lead to conceptually new miniaturization strategies in the electronics and computer industry The realization of single-molecule devices has remained challenging, largely owing to difficulties in achieving electrical contact to individual molecules Recent advances in nanotechnology, however, have resulted in electrical measurements on single molecules4,5,6,7 Here we report the fabrication of a field-effect transistor—a three-terminal switching device—that consists of one semiconducting8,9,10 single-wall carbon nanotube11,12 connected to two metal electrodes By applying a voltage to a gate electrode, the nanotube can be switched from a conducting to an insulating state We have previously reported5 similar behaviour for a metallic single-wall carbon nanotube operated at extremely low temperatures The present device, in contrast, operates at room temperature, thereby meeting an important requirement for potential practical applications Electrical measurements on the nanotube transistor indicate that its operation characteristics can be qualitatively described by the semiclassical band-bending models currently used for traditional semiconductor devices The fabrication of the three-terminal switching device at the level of a single molecule represents an important step towards molecular electronics
5,258 citations
TL;DR: X-ray diffraction and electron microscopy showed that fullerene single-wall nanotubes (SWNTs) are nearly uniform in diameter and that they self-organize into “ropes,” which consist of 100 to 500 SWNTs in a two-dimensional triangular lattice with a lattice constant of 17 angstroms.
Abstract: The major part of this chapter has already appeared in [1], but because of the length restrictions (in Science), the discussion on why we think this form is given in only brief detail. This chapter goes into more depth to try to answer the questions of why the fullerenes form themselves. This is another example of the very special behavior of carbon. From a chemist’s standpoint, it is carbon’s ability to form multiple bonds that allows it to make these low dimensional forms rather than to produce tetrahedral forms. Carbon can readily accomplish this and it is in the mathematics and physics of the way this universe was put together, that carbon is given this property. One of the consequences of this property is that, if left to its own devices as carbon condenses from the vapor and if the temperature range is just right, above 1000°C, but lower than 1400°C, there is an efficient self-assembly process whose endpoint is C60.
5,215 citations
TL;DR: In this paper, the Young's modulus, strength, and toughness of nanostructures are evaluated using an atomic force microscopy (AFM) approach. And the results showed that the strength of the SiC NRs were substantially greater than those found previously for larger SiC structures, and they approach theoretical values.
Abstract: The Young's modulus, strength, and toughness of nanostructures are important to proposed applications ranging from nanocomposites to probe microscopy, yet there is little direct knowledge of these key mechanical properties. Atomic force microscopy was used to determine the mechanical properties of individual, structurally isolated silicon carbide (SiC) nanorods (NRs) and multiwall carbon nanotubes (MWNTs) that were pinned at one end to molybdenum disulfide surfaces. The bending force was measured versus displacement along the unpinned lengths. The MWNTs were about two times as stiff as the SiC NRs. Continued bending of the SiC NRs ultimately led to fracture, whereas the MWNTs exhibited an interesting elastic buckling process. The strengths of the SiC NRs were substantially greater than those found previously for larger SiC structures, and they approach theoretical values. Because of buckling, the ultimate strengths of the stiffer MWNTs were less than those of the SiC NRs, although the MWNTs represent a uniquely tough, energy-absorbing material.
4,627 citations
TL;DR: The thermal conductivity and thermoelectric power of a single carbon nanotube were measured using a microfabricated suspended device and shows linear temperature dependence with a value of 80 microV/K at room temperature.
Abstract: The thermal conductivity and thermoelectric power of a single carbon nanotube were measured using a microfabricated suspended device. The observed thermal conductivity is more than 3000 W/K m at room temperature, which is 2 orders of magnitude higher than the estimation from previous experiments that used macroscopic mat samples. The temperature dependence of the thermal conductivity of nanotubes exhibits a peak at 320 K due to the onset of umklapp phonon scattering. The measured thermoelectric power shows linear temperature dependence with a value of 80 microV/K at room temperature.
3,166 citations