Journal ArticleDOI
Catalysis of aerobic olefin oxidation by a ruthenium perhaloporphyrin complex
Reads0
Chats0
TLDR
The perhalogenated porphyrin ruthenium complex (TFPPCl 8 )Ru(CO) as discussed by the authors catalyzes aerobic oxidation of olefins at room temperature.About:
This article is published in Inorganica Chimica Acta.The article was published on 1998-04-02. It has received 29 citations till now. The article focuses on the topics: Ruthenium & Autoxidation.read more
Citations
More filters
Journal ArticleDOI
Ru-based oxidation catalysis.
TL;DR: This tutorial review aims to provide investigators with a general picture of the chemical and structural origins of the excellent performance of many ruthenium catalysts and to promote further advancement that, it is envisaged, will soon benefit society at large.
Book ChapterDOI
Models and Mechanisms of Cytochrome P450 Action
TL;DR: The reactions catalyzed by the cytochrome P450 family of enzymes have challenged and intrigued chemists for more than two decades and the essential features have been agreed upon now for some time.
Journal ArticleDOI
Reactivity and mechanisms of metalloporphyrin‐ catalyzed oxidations
TL;DR: A combination of experimental and computational methods has begun to provide an understanding of the structure and reactivity of these oxometalloporphyrin complexes and the mechanisms of oxygen transfer reactions they catalyze as discussed by the authors.
Journal ArticleDOI
Iron perchlorophthalocyanine and tetrasulfophthalocyanine catalyzed oxidation of cyclohexane using hydrogen peroxide, chloroperoxybenzoic acid and tert-butylhydroperoxide as oxidants
TL;DR: In this paper, the authors employed polychlorophthalocyanine (Cl 16 PcFe II ) and tetrasulfophthalocyanin (Fe II TSPc] 4− ) complexes of iron as catalysts for the oxidation of cyclohexane using tert -butyl hydroperoxide (TBHP), m -chloroperoxybenzoic acid (m -CPBA) and hydrogen peroxide as oxidants.
References
More filters
Book
Cytochrome P-450: Structure, Mechanism, and Biochemistry
Ortiz de Montellano,R Paul +1 more
TL;DR: The Cytochrome P450 and the Metabolism and Bioactivation of Arachidonic Acid and Eicosanoids in Plants and the Diversity and Importance of Microbial Cytochromes P450 are studied.
Book
Metalloporphyrins in catalytic oxidations
TL;DR: Theoretical studies of Oxometalloporphyrin and their reactions with organic substrates of Cytochrome P450 model systems are described in this article.However, these studies focus on the reaction of Oxochromium, Iron and Manganese Tetraphenylporphyrin with Alkenes.
Journal ArticleDOI
Aerobic epoxidation of olefins with ruthenium porphyrin catalysts
John T. Groves,Robert E. Quinn +1 more
TL;DR: Le dioxo(tetramesitylporphyrinato) ruthenium(VI) catalyse l'epoxydation des olefines (cyclooctene, cis-and trans-β-methylstyrene, norbornene) a temperature and pression ambiantes
Journal ArticleDOI
Mechanism of catalytic oxygenation of alkanes by halogenated iron porphyrins
TL;DR: These and related reactivity studies suggest that catalysis of alkane oxygenation by Fe(TFPPBr8)Cl occurs through a radical-chain mechanism in which the radicals are generated by oxidation and reduction of alkyl hydroperoxides.
BookDOI
Active oxygen in chemistry
TL;DR: In this article, an overview of the energetics and reactivity of oxygen is presented, including superoxide and hydroxyl radical chemistry in aqueous solution, as well as reactions of singlet dioxygen.
Related Papers (5)
Aerobic epoxidation of olefins with ruthenium porphyrin catalysts
John T. Groves,Robert E. Quinn +1 more