Journal ArticleDOI
Catalytic asymmetric Friedel-Crafts alkylation reactions--copper showed the way.
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TLDR
Alkylation with Activated Alkenes and Carbonyl Compounds in Copper Complexes and Other Metal Complexes: The Incubation Period 2904-2904 3.2.1.Abstract:
2. The Incubation Period 2904 3. Alkylation with Activated Alkenes 2905 3.1. Copper Complexes 2905 3.2. Other Metal Complexes 2907 3.3. Organocatalysis 2907 4. Alkylation with Carbonyl Compounds 2908 4.1. Copper Complexes 2908 4.2. Other Metal Complexes 2909 4.3. Organocatalysis 2910 5. Alkylation with Imines 2911 5.1. Copper Complexes 2911 5.2. Organocatalysis 2912 6. Miscellaneous 2913 7. Conclusion and Perspectives 2914 8. Acknowledgments 2914 9. Note Added in Proof 2914 10. References 2914read more
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Transition-Metal-Catalyzed C–H Alkylation Using Alkenes
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References
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Journal ArticleDOI
Chiral bis(oxazoline) copper(II) complexes: versatile catalysts for enantioselective cycloaddition, Aldol, Michael, and carbonyl ene reactions.
TL;DR: X-ray crystallography of the chiral complexes reveals a propensity for the formation of distorted square planar or square pyramidal geometries in catalyzed processes that exhibit excellent temperature-selectivity profiles.
Journal ArticleDOI
Schiff base catalysts for the asymmetric strecker reaction identified and optimized from parallel synthetic libraries
Journal ArticleDOI
C2-Symmetric Chiral Bis(Oxazoline) Ligands in Asymmetric Catalysis
Journal ArticleDOI
Enantioselective organo-cascade catalysis.
TL;DR: These new cascade catalysis protocols allow the invention of enantioselective transformations that were previously unknown, including the asymmetric catalytic addition of the elements of HF across a trisubstituted olefin.
Journal ArticleDOI
New Catalytic Approaches in the Stereoselective Friedel–Crafts Alkylation Reaction
TL;DR: Recent developments in the design and use of catalytic and stereoselective strategies for the alkylation of aromatic systems and synthesis of a wide range of polyfunctionalized enantiomerically enriched compounds are reviewed.
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