Journal ArticleDOI
Catalytic degradation of chemical warfare agents and their simulants by metal-organic frameworks
Yangyang Liu,Yangyang Liu,Ashlee J. Howarth,Nicholaas A. Vermeulen,Su-Young Moon,Joseph T. Hupp,Omar K. Farha,Omar K. Farha +7 more
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In this article, the authors summarize recent advances in the development of metal-organic frameworks (MOF) catalysts for the hydrolysis of nerve agents as well as the oxidation of sulfur mustard.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2017-09-01. It has received 240 citations till now. The article focuses on the topics: Chemical Warfare Agents & Sulfur mustard.read more
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Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents
N. Scott Bobbitt,Matthew L. Mendonca,Ashlee J. Howarth,Timur Islamoglu,Joseph T. Hupp,Omar K. Farha,Omar K. Farha,Randall Q. Snurr +7 more
TL;DR: This paper reviews recent experimental and computational work pertaining to the capture of several industrially-relevant toxic chemicals, including NH3, SO2, NO2, H2S, and some volatile organic compounds, with particular emphasis on the challenging issue of designing materials that selectively adsorb these chemicals in the presence of water.
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MOF-Polymer Hybrid Materials: From Simple Composites to Tailored Architectures.
Mark Kalaj,Kyle C. Bentz,Sergio Ayala,Joseph M. Palomba,Kyle S Barcus,Yuji Katayama,Yuji Katayama,Seth M. Cohen +7 more
TL;DR: This Review highlights the development and recent advances in the synthesis of MOF-polymer mixed-matrix membranes (MMMs) and applications of these MMMs in gas and liquid separations and purifications, including aqueous applications such as dye removal, toxic heavy metal sequestration, and desalination.
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Metal-organic frameworks for highly efficient heterogeneous Fenton-like catalysis
Min Cheng,Cui Lai,Yang Liu,Guangming Zeng,Danlian Huang,Chen Zhang,Lei Qin,Liang Hu,Chengyun Zhou,Weiping Xiong +9 more
TL;DR: The use of metal-organic frameworks (MOFs) or MOF composites as catalysts for Fenton-like catalysis has received increasing attention due to their permanent porosity and tunable open metal centers as mentioned in this paper.
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Metal-Organic Frameworks against Toxic Chemicals
Timur Islamoglu,Zhijie Chen,Megan C. Wasson,Cassandra T. Buru,Kent O. Kirlikovali,Unjila Afrin,Mohammad Rasel Mian,Omar K. Farha +7 more
TL;DR: This review will focus on recent advancements in MOF-based adsorbent design for protection against chemical warfare agents and toxic industrial chemicals such as H2S, NH3, SO2, CO, NO2, and NO.
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Stable Metal–Organic Frameworks with Group 4 Metals: Current Status and Trends
TL;DR: The unique properties of MIV-MOFs are discussed, including their high chemical stability and strong tolerance toward defects, and the perspective of new opportunities in synthesis and defect engineering is concluded.
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The Chemistry and Applications of Metal-Organic Frameworks
Hiroyasu Furukawa,Hiroyasu Furukawa,Kyle E. Cordova,Kyle E. Cordova,Michael O'Keeffe,Michael O'Keeffe,Omar M. Yaghi,Omar M. Yaghi,Omar M. Yaghi +8 more
TL;DR: Metal-organic frameworks are porous materials that have potential for applications such as gas storage and separation, as well as catalysis, and methods are being developed for making nanocrystals and supercrystals of MOFs for their incorporation into devices.
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Selective gas adsorption and separation in metal–organic frameworks
TL;DR: This critical review starts with a brief introduction to gas separation and purification based on selective adsorption, followed by a review of gas selective adsorbents in rigid and flexible MOFs, and primary relationships between adsorptive properties and framework features are analyzed.
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Metal–organic framework materials as catalysts
JeongYong Lee,Omar K. Farha,John M. Roberts,Karl A. Scheidt,SonBinh T. Nguyen,Joseph T. Hupp +5 more
TL;DR: A critical review of the emerging field of MOF-based catalysis is presented and examples of catalysis by homogeneous catalysts incorporated as framework struts or cavity modifiers are presented.
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Metal–Organic Framework Materials as Chemical Sensors
Lauren E. Kreno,Kirsty Leong,Omar K. Farha,Mark D. Allendorf,Richard P. Van Duyne,Joseph T. Hupp +5 more
TL;DR: The potential to computationally predict, with good accuracy, affinities of guests for host frameworks points to the prospect of routinely predesigning frameworks to deliver desired properties.
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