Book ChapterDOI
Chapter 3 - The Oxide Chemistry of Molybdenum
A.M. Chippindale,A.K. Cheetham +1 more
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 19 citations till now. The article focuses on the topics: Molybdenum & Oxide.read more
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POLYMERIC GASEOUS SPECIES IN THE SUBLIMATION OF MOLYBDENUM TRIOXIDE. Period covered: To June 30, 1956. Technical Report No. 2 on THERMODYNAMICS OF REFRACTORY MATERIALS AS DETERMINED WITH A MASS SPECTROMETER
TL;DR: In this article, a mass spectometric analysis of the vapor in thermodynamic equilibrium with powdered molybdenum trioxide, as sampled from a Knudsen effusion cell, has shown that the vapor phase consists of Mo3O9, Mo4O12 and Mo5O15 molecules.
Journal ArticleDOI
Influence of 2-Aminopyridine on the Formation of Molybdates under Hydrothermal Conditions
K. Pavani,Arunachalam Ramanan +1 more
TL;DR: In this article, the role of 2-aminopyridine (2ampy) in the formation of the different solids under hydrothermal conditions is discussed, and the structures of these materials were established by single-crystal and powder X-ray diffraction techniques.
Journal ArticleDOI
Chemical etching of molybdenum trioxide : a new tailor-made synthesis of moo3 catalysts
TL;DR: In this article, a chemical etching method has been developed for restructuring these thermally processed catalysts using a 0.1 M NaOH etchant, where the surface steps, ledges, and terraces are created.
Journal ArticleDOI
Tuning the interlayer of transition metal oxides for electrochemical energy storage
TL;DR: In this article, a review of the benefits and methods for interlayer modification of layered transition metal oxides, which include the presence of structural water, solvent cointercalation and exchange, cation exchange, polymers, and small molecules, exfoliation, and exfoliated heterostructures, is presented.
Journal ArticleDOI
A chemists view: Metal oxides with adaptive structures for thermoelectric applications
Gregor Kieslich,Giacomo Cerretti,Igor Veremchuk,Raphaël P. Hermann,Martin Panthöfer,Juri Grin,Wolfgang Tremel +6 more
TL;DR: In this article, the structural aspects of the crystallographic shear planes and the resulting thermoelectric properties of transition metal oxides with adaptive structures have been investigated with respect to their thermal properties.
References
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Journal ArticleDOI
Les bronzes oxygénés
TL;DR: Several transition-metal oxides with formula MxTOm exhibit a wide phase field and high electrical conductivity as mentioned in this paper, and are known as tungsten bronzes, in which the donor m cations occupy tunnels of square, pentagonal, or hexagonal crosssection within a WO3 network of corner-shared octahedra.
Journal ArticleDOI
β-MoO3 produced from a novel freeze drying route
TL;DR: In this paper, the alpha-prime structure of ReO{sub 3] was observed to have two distinct orientations of a short mo-O distance, suggestive of the type of molybdenyl bond observed in both the alpha and the beta-prime forms.
Journal ArticleDOI
Topotactic dehydration of molybdenum trioxide-hydrates
TL;DR: In this article, it was shown that thermal dehydration of molybdenum trioxide-dihydrate proceeds in two steps, both of which are strongly topotactic.
Journal ArticleDOI
Structure and bonding in Li2MoO3 and Li2−xMoO3 (0 ≤ x ≤ 1.7)
TL;DR: Li2MoO3 has a disordered α-NaFeO2 structure (R 3 m; a = 2.884 A, c = 14.834 A) with the molybdenum present as Mo3O13 clusters.
Journal ArticleDOI
The synthesis and structure of tetrasodium tetramethoxyoctamolybdate-methanol complex (Na4[Mo8O24(OCH3)4].8MeOH): a novel isopolymolybdate that decomposes with the loss of formaldehyde
E. M. Mccarron,R. L. Harlow +1 more
TL;DR: Cristallisation dans le groupe P2 1 /c avec a=11,213, b= 11,693 and c=17,622 A, β=94,49°, Z=2.03.