Journal ArticleDOI
Charge-transfer interaction between quinone and aromatics
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This article is published in Transactions of The Faraday Society.The article was published on 1961-01-01. It has received 13 citations till now. The article focuses on the topics: Quinone.read more
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Journal ArticleDOI
Kinetics of addition of tetracyanoethylene to anthracene and bicyclo[2,2,1]heptadiene
P. Brown,R.C. Cookson +1 more
TL;DR: The enthalpy of activation for Diels-Alder addition of tetracyanoethylene to anthracene ranges from only 4·2(5) Kcal mole − in chloroform to 12·3 Kcal Mole −1 in o -xylene as mentioned in this paper.
Journal ArticleDOI
Dipolar addition versus oxygen transfer in the reaction of tetracyanoethylene oxide with unsaturated hydrocarbons
P. Brown,R.C. Cookson +1 more
TL;DR: In this paper, an isotope effect on the carbon linked to the oxygen atom of 9-deuterioanthracene and tetracyanoethylene oxide has been investigated.
Journal ArticleDOI
Intramolecular charge-transfer interaction in N-[ω-(p-nitrophenyl)alkyl]arylamines
Michinori Ōki,Kiyoshi Mutai +1 more
TL;DR: In this article, the occurence of an intramolecular charge transfer interaction has been confirmed by solvent effects and the change of π-base strength in a series of compounds, p-O2NC6H4(CH2)nNHAr, where Ar groups are phenyl, 2,4-dimethylphenyl, mesityl, panisyl, α-naphthyl, and β-nophthyl groups.
Journal ArticleDOI
Amine charge transfer complexes of perfluoroalkanes and an application to poly(tetrafluoroethylene) surface functionalization
TL;DR: The electron affinities of the perfluorocarbons studied in this article were estimated from the data (eg, perfluorsodecalin, 13 eV) photolysis of the CT complexes with n -BuNH 2 leads to CF bond breaking but although the reaction was not synthetically useful, it can be used as a method for obtaining robust photomodified surfaces of poly(tetrafluoroethylene) (PTFE) where water contact angles fall from 108 ° to
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Resolution of insitu Interaction Energies between Molecules and the Reaction Center QA Site: Implications for Electron Transfer Function
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Photocyclizations involving quinone-olefin charge-transfer exciplexes
Interplay of substituent conformation and electron affinity in quinone models of quinone reductases
Howard Robinson,S. D. Kahn +1 more