Journal ArticleDOI
Chemical Redox Agents for Organometallic Chemistry
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1. Advantages and disadvantages of Chemical Redox Agents, 2. Reversible vs Irreversible ET Reagents, 3. Categorization of Reagent Strength.Abstract:
1. Advantages of Chemical Redox Agents 878 2. Disadvantages of Chemical Redox Agents 879 C. Potentials in Nonaqueous Solvents 879 D. Reversible vs Irreversible ET Reagents 879 E. Categorization of Reagent Strength 881 II. Oxidants 881 A. Inorganic 881 1. Metal and Metal Complex Oxidants 881 2. Main Group Oxidants 887 B. Organic 891 1. Radical Cations 891 2. Carbocations 893 3. Cyanocarbons and Related Electron-Rich Compounds 894read more
Citations
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Structural variation in copper(I) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, tau4.
TL;DR: A new geometric parameter for four-coordinate compounds, tau(4), is proposed as an improved, simple metric for quantitatively evaluating the geometry of four- coordinate complexes and compounds.
Journal ArticleDOI
A Practical Beginner’s Guide to Cyclic Voltammetry
Noémie Elgrishi,Kelley J. Rountree,Brian D. McCarthy,Eric S. Rountree,Thomas T. Eisenhart,Jillian L. Dempsey +5 more
TL;DR: In this article, a short introduction to cyclic voltammetry is provided to help the reader with data acquisition and interpretation, and common pitfalls are provided, and the reader is encouraged to apply what is learned in short, simple training modules provided in the Supporting Information.
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Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications
TL;DR: Narrow bandgap conjugated polymers in combination with fullerene acceptors, as well as the values used for the absolute potentials of standard electrodes, can complicate the comparison of materials properties and determination of structure/property relationships.
Journal ArticleDOI
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications
TL;DR: This issue discusses proton-coupled electron transfer or PCET processes, which are central to a great many chemical and biochemical processes, from biological catalysis and energy transduction, to bulk industrial chemical processes, to new approaches to solar energy conversion.
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Conversion constants for redox potentials measured versus different reference electrodes in acetonitrile solutions at 25°C
TL;DR: In this paper, a critical review of conversion constants amongst various reference electrodes reported in the literature reveals that in most cases the comparisons of redox potential values are far from accurate, and therefore, caution should be exercised when one is comparing the redox properties of complexes measured in CH 3 CN solutions versus different reference electrodes.
References
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Book
Comprehensive inorganic chemistry
TL;DR: In this article, the transition elements involving metal-metal bonds are defined and an introductory essay is given, along with a discussion of homogeneous catalysis and transition metal chemistry, B L Shaw & N I Tucker.