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Chemical technology and analysis of oils, fats, and waxes

TL;DR: Lewkowitsch as discussed by the authors reviewed the appearance of the fourth edition some four years ago (NATURE, August 19, 1909) and would have preferred to wait a little longer before bringing out the present edition, but the exhaustion of the previous issue precluded further delay.
Abstract: THE well-known work of the late Dr. Lewkowitsch was reviewed at some length in these columns on the appearance of the fourth edition some four years ago (NATURE, August 19, 1909). In view of the stage of transition through which the subject of fat analysis is now passing, the author would have preferred to wait a little longer before bringing out the present edition, but the exhaustion of the previous issue precluded further delay.Chemical Technology and Analysis of Oils, Fats, and Waxes.By Dr. J. Lewkowitsch. Fifth edition, entirely re-written and enlarged. Vol. i. Pp. xxiii + 668. (London: Macmillan and Co., Ltd.) Price 25s. net.
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Journal ArticleDOI
TL;DR: Experimental and theoretical studies of nonpolar solute partitioning into water are surveyed and it is noted that the hydrophobic effect is not just due to “water ordering” and not merely due to small size effects of water.
Abstract: Oil and water do not mix. The disaffinity of oil for water, with its unusual temperature dependence, is called the hydrophobic effect. It is important to understand the factors underlying the hydrophobic effect because they appear to play key roles in membrane and micelle formation, protein folding, ligand-protein and protein−protein binding, chromatographic retention, possibly nucleic acid interactions, and the partitioning of drugs, metabolites, and toxins throughout the environment and living systems. Here, we survey experimental and theoretical studies of nonpolar solute partitioning into water. We note that the hydrophobic effect is not just due to “water ordering” and not merely due to small size effects of water. The properties vary substantially with temperature and solute shape. Also, we discuss the limitations of using oil/water partitioning as the basis for some thermodynamic models in chemistry and biology.

800 citations

Journal ArticleDOI
TL;DR: In light of the astronauts’ inadequate dietary intake, the use of vitamin and mineral supplements is often debated, but the deficient energy intake of the astronaut is clearly the issue having highest priority.

374 citations

01 Jan 2006
TL;DR: In this article, the authors carried out experimental study, through extraction and characterization of both crude and refined castor oil, using normal hexane was used as solvent for the extraction process, and the oil was refined through degumming, neutralization and bleaching process using local adsorbent (activated clay).
Abstract: This paper carried out experimental study, through extraction and characterization of both crude and refined castor oil. Normal hexane was used as solvent for the extraction process. The oil produced was refined through degumming, neutralization and bleaching process using local adsorbent (activated clay). The characterization analysis revealed that tested parameters, which include specific gravity, refractive index, acid value, saponification value and iodine value for both crude and refined castor oil produced, were within the ASTM standard specifications. In fact the iodine value obtained (84.8) for the refined oil indicates that the oil could certainly be used as lubricant, hydraulic break fluid and protecting coatings. The oil was modified via sulphation method to produce Turkey – red oil that was tested on wooden material, paper and cloth. The test revealed that the Turkey – red oil produced is suitable to be used as a good dying agent and polish.

175 citations

Journal ArticleDOI
TL;DR: A definite plan of campaign was outlined for the investigation of Cases III.
Abstract: CIIEMICAL INNVESTIGATION OF SUBCUTANEOUS TISSUES. A few preliminary determinations only were nmade by McNee in Cases I. and IT. These will be given first. As a result of the experience gained in these two eases, a definite plan of campaign was outlined for the investigation of Cases III. and IV. Case V. recovered spontaneously and no biopsy was made. A. Cases I. a-1(1 II. and Controls. The fat was melted otut of a imiassof subcutaneous fat, and dried. TIhe melting point of this separated fat was taken by the capillary method; and the, iodine value was determined by Hubl's method.

92 citations

Journal ArticleDOI
TL;DR: In this paper, a method for measuring the length of the induction period of marine and other oils and unsaturated fatty acid esters depends upon determining the increases in weight of the oils.
Abstract: A convenient method for measuring the length of the induction period of marine and other oils and unsaturated fatty acid esters depends upon determining the increases in weight. Small amounts of oil with or without additives are held in constant temperature ovens and weighed at regular intervals. Some of the details of technique are described.

88 citations