Journal ArticleDOI
Chemistry and application of 4-oxo-4H-1-benzopyran-3-carboxaldehyde
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TLDR
The chemistry and application of the title aldehyde and some simple derivatives thereof are reviewed in this paper, where the authors propose a simple derivative of the aldehydes, which they call simple aldeheeds.About:
This article is published in Journal of Heterocyclic Chemistry.The article was published on 2008-11-01. It has received 42 citations till now. The article focuses on the topics: Benzopyran.read more
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Recyclizations of 3-formylchromones with binucleophiles
Andrey S. Plaskon,Andrey S. Plaskon,Oleksandr O. Grygorenko,Oleksandr O. Grygorenko,Sergey V. Ryabukhin +4 more
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4-Chloro-3-(trifluoroacetyl)- and 4-chloro-3-(methoxalyl)coumarins as novel and efficient building blocks for the regioselective synthesis of 3,4-fused coumarins
Viktor O. Iaroshenko,Viktor O. Iaroshenko,Friedrich Erben,Satenik Mkrtchyan,Satenik Mkrtchyan,Ani Hakobyan,Ani Hakobyan,Marcelo Vilches-Herrera,Sergii Dudkin,Alina Bunescu,Alexander Villinger,Vyacheslav Ya. Sosnovskikh,Peter Langer +12 more
TL;DR: In this article, the starting materials were prepared by the reaction of 4-hydroxycoumarin with trifluoroacetic anhydride and methyl 2-chloro-2-oxoacetate in the presence of trimethylsilylchloride.
Journal ArticleDOI
Three-component reactions of isocyanoacetates, amines and 3-formylchromones initiated by an unexpected aza-Michael addition.
TL;DR: A new mode of three-component reactions between isocyanoacetates, amines and 3-formylchromones is presented, which enables an efficient synthesis of polysubstituted pyrroles.
Journal ArticleDOI
3-Methoxalylchromone—a novel versatile reagent for the regioselective purine isostere synthesis
Satenik Mkrtchyan,Viktor O. Iaroshenko,Viktor O. Iaroshenko,Sergii Dudkin,Ashot Gevorgyan,Marcelo Vilches-Herrera,Gagik Ghazaryan,Dmitriy M. Volochnyuk,Dmitriy M. Volochnyuk,Dmytro Ostrovskyi,Zeeshan Ahmed,Alexander Villinger,Vyacheslav Ya. Sosnovskikh,Peter Langer +13 more
TL;DR: The first synthesis of 3-methoxalylchromone was described, where the reaction of the latter with electron-rich aminoheterocycles afforded a set of heteroannelated pyridines bearing a CO(2)Me substituent located at the α-position of the pyridine core.
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Synthesis of Chromone-Related Pyrazole Compounds.
TL;DR: This review will cover the literature on the chromone and pyrazole dual chemistry and their outcomes in the 21st century with a focus on the synthesis of chromone-pyrazole dyads.
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Ceric(IV) Ammonium Nitrate: A Novel Reagent for the Synthesis of Homoallyl Alcohols
TL;DR: A rapid and highly efficient method has been developed for the allylation of aldehydes with allyltributylstannane using a catalytic amount of ceric ammonium nitrate in acetonitrile under mild and neutral conditions to afford the corresponding homoallyl alcohols in excellent yields with high chemoselectivity.
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Base catalysed deacylative dimerisation of 3-acetylchromenone: a facile Diels–Alder reaction
TL;DR: This paper showed that the key step in the title reaction id the Diels-Alder addition of 3-acetylchromenone (1) to its acyl-acyl rearranged isomer (9′a) is supported by the formation of 2-salicyloylxanthone (5) from the reaction of (9) with any of the chromenones (1)—(4)
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Synthesis of Biological Active Chromene Benzothiadiazole Derivatives
TL;DR: In this paper, the synthesis of various substituted Chromene-[1, 3]thiazolo [2, 1, 3]- benzothiadiazoles 4a-l by conventional (Method A) and microwave-assisted (Method B) methods achieved reductions in reaction times, higher yields, and a cleaner reaction than the conventional method.
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Benzopyrans - XXXIII. [4+2]Cycloaddition of N,N-dimethylhydrazones and anils of 2-unsubstituted and 2-methyl-4-oxo-4H-1-benzopyran-3-carboxaldehyde with N-phenylmaleimide
TL;DR: The chromone derivatives 1, 2, and 4 give with N -phenylmaleimide the cycloadducts 5, 12, and 13 which are converted by palladised charcoal into 2-azaxanthone 6, xanthones 14 and 15, respectively as mentioned in this paper.
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New Benzo[b]xanthones from Diels-Alder Reactions of Chromone-3-carboxaldehydes with ortho-Benzoquinodimethanes
TL;DR: In this paper, new benzo[b]xanthone derivatives, having substituents in the A and D rings, were prepared from cycloaddition reactions of chromone-3-carboxaldehydes with ortho-benzoquinodimethanes, generated in situ from 1,3-dihydrobenzo[c]thiophene 2,2-dioxide, followed by oxidation of the obtained diastereomeric adducts.