Chemistry of oxo-metal ions-VI 1,10-phenanthrolinium oxopentachloromolybdate(V) and its derivatives
TL;DR: In this article, it has been shown that the oxometal entity MoO 3+ remains intact under various physicochemical methods and the probable constitution of expected cis-trans isomers of MoOCl 3 ·phen has also been discussed.
About: This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1972-10-01. It has received 21 citations till now.
Citations
More filters
••
09 Mar 200778 citations
••
TL;DR: In this article, the synthesis and structure elucidation of the dimeric form of molybdenum oxo-complexes with N-alkylphenothiazines as ligands have been studied.
17 citations
••
TL;DR: In this article, the infrared spectra of the three compounds {VO2F(AA) and {VOF3L2} showed two strong absorptions (in the 800-950 cm−1 region) which are likely to arise from vs and vas(VO2).
10 citations
••
TL;DR: In this paper, a series of mixed chelate complexes of identical composition of the type (NH4)2[UO2(L)2B] and (NH 4]2 [UO 2(L 2B] 2X2] have been thoroughly characterised through elemental analysis, conductance data, X-ray, IR, electronic, NMR spectra as well as thermogravimetric and differential thermal analyses.
9 citations
References
More filters
••
155 citations
••
TL;DR: In this paper, the preparation and chemical properties of molybdenum(V) with 2:2′-dipyridyl are described and possible structures of the complexes are discussed.
57 citations
••
41 citations
••
TL;DR: In this paper, the ultraviolet, visible and infra-red spectra of the compounds Ba(MoO 2 C 2 O 4 ) 2 5H 2 O and K(Mo O 2C 2O 4 )2·5 H 2 O have been measured and their magnetic moments determined, showing that the complex anion is dimeric in the solid and in solution.
38 citations
••
TL;DR: In this article, the reaction of molybdenum (V) oxidetrichloride with aliphatic nitriles (RCN, R = Me, Et, Pr) results in the formation of the complexes, MoOCl 3, 2RCN.
27 citations